ACS Journals Logo
Journal of the American Chemical Society logo

Volume 36
Main Index

Issue 1


Remote Interfacial Electron Transfer from Supramolecular Sensitizers
Roberto Argazzi, Carlo A. Bignozzi, Todd A. Heimer, and Gerald J. Meyer
pp 2 - 3; DOI:
10.1021/ic960717g
PDF
Synthesis and Characterization of (Ph4P)2[Ni2As4S8], (Me4N)2[Mo2O2As2S7], and (Et4N)2[Mo2O2As2Se7]. New One-Dimensional Polymeric Compounds Containing Thio- and Selenoarsenate Ligands
Jun-Hong Chou, Jason A. Hanko, and Mercouri G. Kanatzidis
pp 4 - 9; DOI:
10.1021/ic951665i
PDF
Lanthanide Complexes of the Hexadentate N-Donor Podand Tris[3-(2-pyridyl)pyrazolyl]hydroborate: Solid-State and Solution Properties
Peter L. Jones, Angelo J. Amoroso, John C. Jeffery, Jon A. McCleverty, Elefteria Psillakis, Leigh H. Rees, and Michael D. Ward
pp 10 - 18; DOI:
10.1021/ic960621m
PDF
Bistability and Molecular Switching for Semiquinone and Catechol Complexes of Cobalt. Studies on Redox Isomerism for the Bis(pyridine) Ether Series Co(py2X)(3,6-DBQ)2, X = O, S, Se, and Te
Ok-Sang Jung, Du Hwan Jo, Young-A Lee, Brenda J. Conklin, and Cortlandt G. Pierpont
pp 19 - 24; DOI:
10.1021/ic961214d
PDF
Specific and Nonspecific Solvation Contributions to Intervalence Electron Transfer Transitions and Redox Potentials in Ruthenium Ammine Complexes
Russell S. Drago, David E. Richardson, and James E. George
pp 25 - 32; DOI:
10.1021/ic960066o
PDF
Structural Studies of - and -[Ru(phen)2dppz]2+ Bound to d(GTCGAC)2: Characterization of Enantioselective Intercalation
Cynthia M. Dupureur and and Jacqueline K. Barton
pp 33 - 43; DOI:
10.1021/ic960738a
PDF
Poly(2-pyridyl)phosphines, PPynPh3-n (n = 2, 3), and Their P-Substituted Derivatives as Tripodal Ligands in Molybdenum(0) Carbonyl Complexes
Juan A. Casares, Pablo Espinet, Rosa Hernando, Gonzalo Iturbe, Fernando Villafañe, Dianne D. Ellis, and A. Guy Orpen
pp 44 - 49; DOI:
10.1021/ic960645t
PDF
Synthesis, Characterization, and Magnetic Studies of Two Novel Isostructural Pentanuclear Iron(II) Complexes
Susanna Herold and Stephen J. Lippard
pp 50 - 58; DOI:
10.1021/ic960783i
PDF
A Family of -Amino Acid Salicylaldiminates Incorporating the Binuclear V2O33+ Core: Electrosynthesis, Structure, and Metal Valence
Sujit Mondal, Prasanta Ghosh, and Animesh Chakravorty
pp 59 - 63; DOI:
10.1021/ic960671r
PDF
A Family of Ruthenium Aryls Incorporating an 2-Bonded Nitrite or Nitrate and a Pendant Imine-Phenol Function
Prasanta Ghosh and Animesh Chakravorty
pp 64 - 69; DOI:
10.1021/ic960358p
PDF
Carbon Dioxide Complexation: Infrared Spectroscopy of Iron and Ruthenium 5-Cyclopentadienyl Carbonyl Metallocarboxylates
John R. Pinkes, Christopher J. Masi, Robert Chiulli, Bryan D. Steffey, and Alan R. Cutler
pp 70 - 79; DOI:
10.1021/ic960009v
PDF
W2Cl4(NHR)2(PR'3)2 Molecules. 3. Bidentate Phosphine Complexes of Bis(tert-butylamido)tetrachloroditungsten. Preparation and Structural Characterization of cis,cis-W2Cl4(NHCMe3)2(L-L) (L-L = dmpm, dmpe, dppm, dppe)
F. Albert Cotton, Evgeny V. Dikarev, and Wai-Yeung Wong
pp 80 - 85; DOI:
10.1021/ic960906z
PDF
Anionic Calixarene Complexes of Copper(I) and Silver(I) as Cation Receptors
Wei Xu, Jagadese J. Vittal, and Richard J. Puddephatt
pp 86 - 94; DOI:
10.1021/ic960508w
PDF
Preparation and Reactions of [CpOs(CH3CN)3]+. A Useful Synthetic Intermediate for the Preparation of CpOsL3 Compounds
Daniel A. Freedman, Thomas P. Gill, Amy M. Blough, Robert S. Koefod, and Kent R. Mann
pp 95 - 102; DOI:
10.1021/ic9601504
PDF
Structural Trends in Group 4 Metal Tetraaza Macrocycle Complexes. Molecular Structures of (Me4taen)Zr(OtBu)2 and (Me4taen)Hf(NMe2)2
David G. Black, Richard F. Jordan, and Robin D. Rogers
pp 103 - 108; DOI:
10.1021/ic960823i
PDF
Decanuclear Manganese(III) Complexes with the [Mn10O8]14+ Core: Structural and Magnetochemical Characterization of [Mn10O8(O2CPh)6(chel)8] (chel = pic, dbm)
Hilary J. Eppley, Sheila M. J. Aubin, William E. Streib, John C. Bollinger, David N. Hendrickson, and George Christou
pp 109 - 115; DOI:
10.1021/ic9607548
PDF
First Examples of Carboxyl-Bonded Low-Spin Manganese(III) Complexes
Sanjib Ganguly, Soma Karmakar, and Animesh Chakravorty
pp 116 - 118; DOI:
10.1021/ic960485l
PDF
Formation of Transient Iron(III)-Sulfur(IV) Complexes Revisited. Application of Rapid-Scan Techniques
F. F. Prinsloo, Ch. Brandt, V. Lepentsiotis, J. J. Pienaar, and R. van Eldik
pp 119 - 121; DOI:
10.1021/ic960622e
PDF
Bond Valence Sums in Coordination Chemistry Using Oxidation State Independent R0 Values
Gus J. Palenik
pp 122 - 122; DOI:
10.1021/ic960873n
PDF
Synthesis and Structure of a Trigonal Monopyramidal Vanadium(III) Complex, [(C6F5NCH2CH2)3N]V, and the Vanadium(IV) Product of Its Oxidation, {[(C6F5NCH2CH2)2N(CH2CH2NHC6F5)]V(O)}2
Celine Rosenberger, Richard R. Schrock, and William M. Davis
pp 123 - 125; DOI:
10.1021/ic960889d
PDF
1H NMR Study of Aqueous Molybdomethylarsonates
A. Kobayashi and A. Yagasaki
pp 126 - 128; DOI:
10.1021/ic960852t
PDF
Stability of Group 11 Carbonyl Complexes Cl-M-CO (M = Cu, Ag, Au)
I. Antes, S. Dapprich, G. Frenking, and P.Schwerdtfeger
pp 128 - 128; DOI:
10.1021/ic9612414
PDF

Issue 2


New Routes for Multiple Derivatization of Polyoxometalates. Bis(acetato)dirhodium-11-tungstophosphate, [(PO4)W11O35{Rh2(OAc)2}]5-
Xinyi Wei, Michael H. Dickman, and Michael T. Pope
pp 130 - 131; DOI:
10.1021/ic960991a
PDF
Ferrocene-Substituted Amidinate Derivatives: Syntheses and Crystal Structures of Lithium, Iron(II), and Cobalt(II) Complexes
John R. Hagadorn and John Arnold
pp 132 - 133; DOI:
10.1021/ic961058a
PDF
Structural Demonstration of the Role of Ligand Framework Conformability in Copper(II)/Copper(I) Redox Potentials
Kausik K. Nanda, Anthony W. Addison, Raymond J. Butcher, Michael R. McDevitt, T. Nageswara Rao, and Ekkehard Sinn
pp 134 - 135; DOI:
10.1021/ic961112n
PDF
Electrochemistry, Stability, and Alkene Complexation Chemistry of Copper(I) Triflate in Aqueous Solution. Potential for Use in Electrochemically Modulated Complexation-Based Separation Processes
Takayuki Suzuki, Richard D. Noble, and Carl A. Koval
pp 136 - 140; DOI:
10.1021/ic9608509
PDF
Organometallic Terthiophene Derivatives: Modulation of the Terthiophene Core of 5,5''-Diphenyl-2,2':5'2''-Terthiophene via [CpRu]+ and [Cp*Ru]+ Substituents
David D. Graf and Kent R. Mann
pp 141 - 149; DOI:
10.1021/ic960308k
PDF
Electrochemical Investigation of Ruthenium and Osmium Oligothiophene Complexes: How Does Metal Binding Affect the Oligothiophene -System?
David D. Graf and Kent R. Mann
pp 150 - 157; DOI:
10.1021/ic960309c
PDF
Synthesis and Spectroscopic Characterization of Hexakis(carbonyl)iron(II) Undecafluorodiantimonate(V), [Fe(CO)6][Sb2F11]2
Bianca Bley, Helge Willner, and Friedhelm Aubke
pp 158 - 160; DOI:
10.1021/ic9608105
PDF
Synthesis and Structure Determinations of Complexes Containing a Five-Membered Lactam Structure Based on Organohydrazido(2-) Ligands
Hidetake Seino, Youichi Ishii, and Masanobu Hidai
pp 161 - 171; DOI:
10.1021/ic960778e
PDF
Steric Effects in the Ground and Excited States of Cu(NN)2+ Systems
Michèle K. Eggleston, David R. McMillin, Kristina S. Koenig, and Alexander J. Pallenberg
pp 172 - 176; DOI:
10.1021/ic960698a
PDF
Monomer-Trimer Isomerism in 3-Substituted Pentane-2,4-dione Derivatives of Nickel(II)
A. Döhring, R. Goddard, P. W. Jolly, C. Krüger, and V. R. Polyakov
pp 177 - 183; DOI:
10.1021/ic960441c
PDF
Stepwise Synthesis of the Functionalized Metallatetrahedron Re2(AuPPh3)2(-PCy2)(CO)7X (X = Cl, Br, I)
H.-J. Haupt, M. Schwefer, H. Egold, and U. Flörke
pp 184 - 188; DOI:
10.1021/ic9606690
PDF
Intracrystalline and Electronic Structures of Copper(II) Complexes Stabilized in Two-Dimensional Aluminosilicate
Jin-Ho Choy, Dong-Kuk Kim, Jung-Chul Park, Sung-Nak Choi, and Young-Jin Kim
pp 189 - 195; DOI:
10.1021/ic960631n
PDF
EXAFS Study of Two-Dimensional Organic/Inorganic Hybrid Nanocomposites, Cu2(OH)3(n-CmH2m+1COO) (m = 0, 1, 7, 8, 9): Structural Modification in the Inorganic Layer Induced by the Interlayer Organic Molecule
Wataru Fujita, Kunio Awaga, and Toshihiko Yokoyama
pp 196 - 199; DOI:
10.1021/ic960787n
PDF
Palladium(II) and Platinum(II) Complexes of a Tetraphosphamacrocycle. X-ray Crystal Structures of Phosphorus Analogs of a (Tetramethylcyclam)metal Complex
Tsutomu Mizuta, Akihiro Okano, Tsutomu Sasaki, Hiroshi Nakazawa, and Katsuhiko Miyoshi
pp 200 - 203; DOI:
10.1021/ic960700y
PDF
Synthesis, Structure, and Electrochemistry of an Electron Deficient -Oxo Porphyrin Dimer, [(TPPBr4)Fe]2O
Karl M. Kadish, Marie Autret, Zhongping Ou, Pietro Tagliatesta, Tristano Boschi, and Vincenzo Fares
pp 204 - 207; DOI:
10.1021/ic960040x
PDF
Heterooctanuclear Cluster Complex Formation with Phosphine Participation: Synthesis, Structure, and Magnetic Properties of Co6Ru2(mp)10(PBun3)6 (H2mp = 2-Mercaptophenol, PBun3 = Tri-n-butylphosphine)
Zhong-Ning Chen, Wen-Jie Li, Bei-Sheng Kang, Mao-Chun Hong, Zhong-Yuan Zhou, Thomas C. W. Mak, Zhang Lin, Xiao-Ming Chen, and Han-Qin Liu
pp 208 - 213; DOI:
10.1021/ic960239+
PDF
A Vanadium-Containing Iron-Sulfur Cluster with a V2Fe2S4 Cubane-like Core. Synthesis, Structure, and Characterization of (Et4N)[V2Fe2S4(Me2dtc)5]
Yuheng Deng, Qiutian Liu, Yu Yang, Youtong Wang, Yuanba Cai, Daxu Wu, Changneng Chen, Daizheng Liao, Beisheng Kang, and Jiaxi Lu
pp 214 - 219; DOI:
10.1021/ic9603767
PDF
Crystal Structure and Magnetic Properties of an Infinite Chainlike and a Tetranuclear Bimetallic Copper(II)-Chromium(III) Complex with Bridging Cyanide Ions
De Gang Fu, Jian Chen, Xiang Shi Tan, Li Juan Jiang, Si Wei Zhang, Pei Ju Zheng, and Wen Xia Tang
pp 220 - 225; DOI:
10.1021/ic960481g
PDF
Reaction of BX2-BX2 (X = H or OH) with M(PH3)2 (M = Pd or Pt). A Theoretical Study of the Characteristic Features
Shigeyoshi Sakaki and and Tomoko Kikuno
pp 226 - 229; DOI:
10.1021/ic951504e
PDF
Quadrupole-Dipole Effects in Solid-State Phosphorus-31, CP-MAS NMR Spectra of Tertiary Phosphine Substituted Alkyl- and Acyltetracarbonylmanganese(I) Complexes
Dharamdat Christendat, Ross D. Markwell, Denis F. R. Gilson, Ian S. Butler, and John D. Cotton
pp 230 - 235; DOI:
10.1021/ic960476c
PDF
Tripodal Aminophenolate Ligand Complexes of Aluminum(III), Gallium(III), and Indium(III) in Water
P. Caravan and Chris Orvig
pp 236 - 248; DOI:
10.1021/ic961222u
PDF
Correlation between Ligand Coordination Number and the Shift of the 7F0-5D0 Transition Frequency in Europium(III) Complexes
G. R. Choppin and and Z. M. Wang
pp 249 - 252; DOI:
10.1021/ic9500220
PDF
A Carbidoheptarhenate Complex of Thallium(I)
Udo Brand and John R. Shapley
pp 253 - 255; DOI:
10.1021/ic9609867
PDF
Reactions of Rhenium(V) Oxo and Nitrido Complexes with 1-Phenyl-2-(diphenylphosphino)ethanone (POH). Synthesis and Crystal Structure of ReOCl(PO)2 and ReN(PPh3)(PO)2
Fabienne Connac, Yolande Lucchese, Michèle Dartiguenave, and André L. Beauchamp
pp 256 - 259; DOI:
10.1021/ic9606035
PDF
Synthesis of Fine-Powder Polycrystalline Bi-Se-Te, Bi-Sb-Te, and Bi-Sb-Se-Te Alloys
Joseph J. Ritter and and Pichai Maruthamuthu
pp 260 - 263; DOI:
10.1021/ic960616i
PDF
Unprecedented Influence of Acid Medium in the Synthesis of Mo3M'S4 Cubane-Like Clusters: Preparation of [Mo3PbS4(H2O)9+x]4+
Michael Brorson, Claus J. H. Jacobsen, Hans K. M.Helgesen, and Iver Schmidt
pp 264 - 264; DOI:
10.1021/ic9613321
PDF
Development of a Synthetic Route to Unsymmetrical Triphosphine Ligands and an Investigation of Their Coordination Chemistry with Nickel and Palladium
G. Dyer, J. Roscoe, R. G. Pritchard, and C. A.McAuliffe
pp 264 - 264; DOI:
10.1021/ic961333t
PDF

Issue 3


Characterization of a -2:2-Peroxo Dinuclear Cobalt(II) Complex
Shiro Hikichi, Hidehito Komatsuzaki, Nobumasa Kitajima, Munetaka Akita, Masahiro Mukai, Teizo Kitagawa, and Yoshihiko Moro-oka
pp 266 - 267; DOI:
10.1021/ic950723x
PDF
Tuning of Superexchange Couplings in a Molecule-Based Ferroferrimagnet: (NiIIxMnII1-x)1.5[CrIII(CN)6]
Shin-ichi Ohkoshi, Osamu Sato, Tomokazu Iyoda, Akira Fujishima, and Kazuhito Hashimoto
pp 268 - 269; DOI:
10.1021/ic960978q
PDF
Reversible Nitrogen Atom Transfer between Nitridomanganese(V) and Manganese(III) Schiff-Base Complexes
Christopher J. Chang, Donald W. Low, and Harry B. Gray
pp 270 - 271; DOI:
10.1021/ic961023a
PDF
Synthesis and Characterization of Rhodium(I) Boryl and Rhodium(III) Tris(Boryl) Compounds: Molecular Structures of [(PMe3)4Rh(B(cat))] and fac-[(PMe3)3Rh(B(cat))3] (cat = 1,2-O2C6H4)
Chaoyang Dai, Graham Stringer, Todd B. Marder, Andrew J. Scott, William Clegg, and Nicholas C. Norman
pp 272 - 273; DOI:
10.1021/ic9611047
PDF
Photosubstitution Reactions of trans-Chloro(azine)(1,4,8,11-tetraazacyclotetradecane)ruthenium(II) Complexes
Maristela Silva and and Elia Tfouni
pp 274 - 277; DOI:
10.1021/ic9605581
PDF
Alkoxido, Amido, and Imido Derivatives of Titanium(IV) Tetratolylporphyrin
Steven D. Gray, Joseph L. Thorman, Lisa M. Berreau, and L. Keith Woo
pp 278 - 283; DOI:
10.1021/ic960977y
PDF
Olefin-Amino Acid Complexes of Platinum(II). 2. NMR Study of the Effect of Olefin Structure on the Stability and on the Stereoselectivity of Binding for 2-Coordinated Prochiral Olefins
Luther E. Erickson, Peter Hayes, Joanna J. Hooper, Kevin F. Morris, Sally A. Newbrough, Marjan Van Os, and Petie Slangan
pp 284 - 290; DOI:
10.1021/ic960967x
PDF
A New Class of Biomimetically Relevant "Scorpionate" Ligands. 1. The (2-Hydroxyphenyl)bis(pyrazolyl)methanes: Synthesis and Structural Characterization of Some Cobalt(II) Complexes
Timothy C. Higgs and Carl J. Carrano
pp 291 - 297; DOI:
10.1021/ic9610703
PDF
A New Class of Biomimetically Relevant "Scorpionate" Ligands. 2. The (2-Hydroxyphenyl)bis(pyrazolyl)methanes: Structural Characterization of a Series of Mono-, Di-, and Trinuclear Nickel(II) Complexes
Timothy C. Higgs and Carl J. Carrano
pp 298 - 306; DOI:
10.1021/ic960920b
PDF
The First X-ray Structural Evidence Demonstrating Thiolate Coordination in an Organocobalt B12 Model Complex: Implications for Methionine Synthase
Suzette M. Polson, Lory Hansen, and Luigi G. Marzilli
pp 307 - 313; DOI:
10.1021/ic961019z
PDF
Synthesis and X-ray Structures of Elusive Imine/Oxime-Type Organocobalt B12 Complexes. NMR Study Suggesting Steric Strain within the Axially Ligated Benzimidazole
Suzette M. Polson, Renzo Cini, Claudia Pifferi, and Luigi G. Marzilli
pp 314 - 322; DOI:
10.1021/ic961105z
PDF
Syntheses and X-ray Structures of Mixed-Ligand Salicylaldehyde Complexes of Mn(III), Fe(III), and Cu(II) Ions: Reactivity of the Mn(III) Complex toward Primary Monoamines and Catalytic Epoxidation of Olefins by the Cu(II) Complex
Gopal Das, Rameshwer Shukla, Subrata Mandal, Ramsharan Singh, Parimal K. Bharadwaj, Jaap van Hall, and Kenton H. Whitmire
pp 323 - 329; DOI:
10.1021/ic9510371
PDF
Effect of Hybridization on Structure and Bonding of Cluster Compounds Possessing a Square-Pyramidal Fe3(CO)9E2 Core (E = Element of Group 15 or 16)
Jeffrey R. Eveland, Jean-Yves Saillard, and Kenton H. Whitmire
pp 330 - 334; DOI:
10.1021/ic960243l
PDF
Properties of Pure Nitryl Bromide. Thermal Behavior, UV/Vis and FTIR Spectra, and Photoisomerization to trans-BrONO in an Argon Matrix
Dieter Scheffler, Hinrich Grothe, Helge Willner, Andreas Frenzel, and Cornelius Zetzsch
pp 335 - 338; DOI:
10.1021/ic9606946
PDF
Properties of Fluorocarbonyl Peroxynitrate
Dieter Scheffler, Iris Schaper, Helge Willner, Hans-Georg Mack, and Heinz Oberhammer
pp 339 - 344; DOI:
10.1021/ic960847p
PDF
Syntheses of Cationic Lead(II) and Tin(II) Complexes Containing Tris(pyrazolyl)methane Ligands. Control of Stereochemistry by Variation in Ligand Substitution
Daniel L. Reger, James E. Collins, Arnold L. Rheingold, Louise M. Liable-Sands, and Glenn P. A. Yap
pp 345 - 351; DOI:
10.1021/ic961030z
PDF
Synthesis, Structure, and Properties of BaVO2(AsO4): a New Vanadium Arsenate Containing the V2O42+ Core
Florence Gagnard, Christian Reisner, and Wolfgang Tremel
pp 352 - 355; DOI:
10.1021/ic960498z
PDF
On the Existence in Solution of Doubly Thiolate-Bridged Double Cubanes Containing the Heterometal [MFe3S4] Core (M = Mo, W)
Jiesheng Huang, Christopher Goh, and R. H. Holm
pp 356 - 361; DOI:
10.1021/ic960844c
PDF
Electron Transfer. 133. Copper Catalysis in the Sulfite Reduction of Peroxynitrite
Ahmad M. Al-Ajlouni and Edwin S. Gould
pp 362 - 365; DOI:
10.1021/ic960907r
PDF
Studies on the Reactivity of Tetrafluoro- and Pentafluorophenyl Trimethylsilyl Ether with Pentafluorobenzenes. Chemistry and X-ray Structural Investigations of Polyfluorodiphenyl Ethers
Burkhard Krumm, Ashwani Vij, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 366 - 381; DOI:
10.1021/ic960879c
PDF
Vibrational Study of (5-Cyclopentadienyl)metal Complexes
E. Diana, R. Rossetti, P. L. Stanghellini, and S. F. A. Kettle
pp 382 - 391; DOI:
10.1021/ic960545n
PDF
Silicon-Fluorine and Silicon-Carbon Bond Cleavage in Organofluorosilicates: A Molecular Orbital Study
Xiaobo Ou and Alexander F. Janzen
pp 392 - 395; DOI:
10.1021/ic940888q
PDF
A Theoretical Study of Complexes MHx2- and MCly2- in Crystalline A2MHx and A2MCly Compounds (A = Alkali, Alkaline Earth; M = Ni, Pd, Pt; x = 2, 4, 6; y = 4, 6)
Meng-sheng Liao and and Qian-er Zhang
pp 396 - 405; DOI:
10.1021/ic960369i
PDF
[Fe(OEP)(X)]+ -Cation Radicals: Characterization and Spin-Spin Interactions
Charles E. Schulz, Hungsun Song, Anil Mislankar, Robert D. Orosz, Christopher A. Reed, Peter G. Debrunner, and W. Robert Scheidt
pp 406 - 412; DOI:
10.1021/ic961053d
PDF
Assignment of the Optical Spectra of Metal Phthalocyanine Anions
John Mack and Martin J. Stillman
pp 413 - 425; DOI:
10.1021/ic960737i
PDF
Chiroptical Absorption and Luminescence Spectra of a Dissymmetric Osmium(II)-Polypyridyl Complex Containing an Optically Active Bis(bipyridine)-Type Ligand of Well-Defined Structural Chirality
Kevin E. Gunde, Alberto Credi, Erik Jandrasics, Alex von Zelewsky, and F. S. Richardson
pp 426 - 434; DOI:
10.1021/ic9609012
PDF
Phosphorus-31 Chemical Shift Anisotropies in Solid, Octahedral Chromium(0) Triphenylphosphine Derivatives
Yining Huang, Haewon L. Uhm, Denis F. R. Gilson, and Ian S. Butler
pp 435 - 438; DOI:
10.1021/ic960816u
PDF
Pressure-Induced Luminescence Rigidochromism in the Photophysics of the Cuprous Iodide Cluster Cu4I4py4
Dat Tran, James L. Bourassa, and Peter C. Ford
pp 439 - 442; DOI:
10.1021/ic960959g
PDF
Supramolecular Soft-Soft Interactions of Diiodo(tert-butyl)(isopropyl)phosphonium Cations with 2- to 5-Bridging Iodide Anions. Formation of Chains, Helices, and Columnar Structures
Volkmar Stenzel, Jörg Jeske, Wolf-Walther du Mont, and Peter G. Jones
pp 443 - 448; DOI:
10.1021/ic9603058
PDF
Polymorphism in Coordination Chemistry. Selective Syntheses and ab Initio X-ray Powder Diffraction Characterization of Two New Crystalline Phases of Solid [Pd(dmpz)2(Hdmpz)2]2 (Hdmpz = 3,5-Dimethylpyrazole)
Norberto Masciocchi, G. Attilio Ardizzoia, Girolamo La Monica, Massimo Moret, and Angelo Sironi
pp 449 - 454; DOI:
10.1021/ic960831z
PDF
Spin Crossover in the 2,2'-Bipyrimidine- (bpym-) Bridged Iron(II) Complexes [Fe(L)(NCX)2]2(bpym) (L = 2, 2'-Bithiazoline (bt) and bpym; X = S, Se). X-ray Absorption Spectroscopy, Magnetic Susceptibility, Calorimetric, and Mössbauer Spectroscopy Studies
José Antonio Real, Isabel Castro, Azzedine Bousseksou, Michel Verdaguer, Ramón Burriel, Miguel Castro, Jorge Linares, and François Varret
pp 455 - 464; DOI:
10.1021/ic960509o
PDF
Multiple Bonds Between Main Group Elements and Transition Metals. 151.1 Trioxorhenium(VII) Alkoxide Complexes
Wolfgang A. Herrmann, William A. Wojtczak, Georg R. J. Artus, Fritz E. Kühn, and Mike R. Mattner
pp 465 - 471; DOI:
10.1021/ic951508j
PDF
Oxotungsten(VI) Chemistry of Hydrotris(3,5-dimethylpyrazol-1-yl)borate: Hydroxodioxotungsten(VI), Trioxotungsten(VI), and (-Oxo)bis[dioxotungsten(VI)] Complexes
Aston A. Eagle, Graham N. George, Edward R. T. Tiekink, and Charles G. Young
pp 472 - 479; DOI:
10.1021/ic9609261
PDF
Local Density Functional Theory Analysis of the Structures and Energies of the Isomers of Low-Spin [Ni(cyclam)]2+
Kenneth R. Adam, Ian M. Atkinson, and Leonard F. Lindoy
pp 480 - 481; DOI:
10.1021/ic960864e
PDF
Nitrogen-Phosphorus Multiple Bond Vibrational Assignments in the Infrared and Raman
Neil Burford, Jason A. C. Clyburne, Donna Silvert, Stephanie Warner, W. Alex Whitla, and Katherine Valenta Darvesh
pp 482 - 484; DOI:
10.1021/ic960133e
PDF
A Planar P2N4S2 Ring: Preparation and X-ray Structures of Et4P2N4S2Cl2 and [R4P2N4S2][AlCl4]2 (R = Et, Ph)
Michele Brock, Tristram Chivers, Masood Parvez, and Rainer Vollmerhaus
pp 485 - 489; DOI:
10.1021/ic960567+
PDF
cis-[Pt(NH3)2(9-MeA-N7)(9-EtGH-N7)](PF6)2·1.5H2O (9-MeA = 9-Methyladenine; 9-EtGH = 9-Ethylguanine): A Right-Handed Helicoidal Model Compound for the Intrastrand A,G Cross-Link in Duplex DNA
Guy Schröder, Michal Sabat, Ivan Baxter, Jirí Kozelka, and Bernhard Lippert
pp 490 - 493; DOI:
10.1021/ic9611296
PDF
Aryloxide and Alkoxide Derivatives of Metal Clusters. Syntheses, Structures, and Reactivities of the -Oxo-Bridged Triuthenium Clusters Ru3(CO)8(-2-OC6H4Cl)2 and Ru3(CO)8(-2-OCH2C6H4N)2
Donald J. Darensbourg, Bernardo Fontal, Steve S.Chojnacki, Kevin K. Klausmeyer, and Joseph H.Reibenspies
pp 494 - 494; DOI:
10.1021/ic961354n
PDF

Issue 4


Synthesis and Characterization of Gold(I) Complexes with the Ligand 1,2-Dithiolate-o-carborane. Crystal Structures of [Au2(-S2C2B10H10)(PPh3)2], [Au2(-S2C2B10H10)(-{(PPh2)2(CH=CH)}], and [Au2(-S2C2B10H10)(-{(PPh2)2(C6H4)}]
Olga Crespo, M. Concepción Gimeno, Peter G. Jones, Birte Ahrens, and Antonio Laguna
pp 495 - 500; DOI:
10.1021/ic960822q
PDF
Bulky Amidinate Complexes of Tin(IV). Synthesis and Structure of Sn(RNC(R')NR)2Cl2 (R = Cyclohexyl, R' = H, Me; R = SiMe3, R' = tBu)
Yuanlin Zhou and Darrin S. Richeson
pp 501 - 504; DOI:
10.1021/ic960940d
PDF
Syntheses and Structures of the Tungstoborate Anions
André Tézé, Monique Michelon, and Gilbert Hervé
pp 505 - 509; DOI:
10.1021/ic961051t
PDF
Dicopper Complexes with a Dissymmetric Dicompartmental Schiff Base-Oxime Ligand: Synthesis, Structure, and Magnetic Interactions
Elena V. Rybak-Akimova, Daryle H. Busch, Pawan K. Kahol, Nicholas Pinto, Nathaniel W. Alcock, and Howard J. Clase
pp 510 - 520; DOI:
10.1021/ic9601145
PDF
1,3-Bis(trimethylsilyl)-2-phenyl-1-aza-3-phosphapropenide Anions as Bidentate Ligands for the Alkaline Earth Metals Magnesium, Calcium, Strontium, and Barium
Matthias Westerhausen, Matthias H. Digeser, and Wolfgang Schwarz
pp 521 - 527; DOI:
10.1021/ic960887t
PDF
Linear Free Energy Relationships for Complex Formation Reactions between Carboxylic Acids and Palladium(II). Equilibrium and High-Pressure Kinetics Study
Tiesheng Shi and Lars I. Elding
pp 528 - 536; DOI:
10.1021/ic9613523
PDF
Reversible C60 Binding to Dendrimer-Containing Ir(CO)Cl(PPh2R)2 Complexes
Vincent J. Catalano and Nicholas Parodi
pp 537 - 541; DOI:
10.1021/ic9612764
PDF
EPR Studies of the Mixed-Metal Cubane-Type Complex Having a [Mo3CuS4(H2O)10]4+ Core
Ryo Miyamoto, Satoshi Kawata, Masamoto Iwaizumi, Haruo Akashi, and Takashi Shibahara
pp 542 - 546; DOI:
10.1021/ic950250u
PDF
Reactions of 1,1'-Bis(diphenylphosphino)ferrocene with Boranes, Thiaboranes, and Carboranes
Kelley J. Donaghy, Patrick J. Carroll, and Larry G. Sneddon
pp 547 - 553; DOI:
10.1021/ic9611913
PDF
Substitution on Metallaboranes at Boron. Syntheses of closo-1-X-[2,3,4-(5-C5Me5)3(-H)2Co3B2H], X = Cl and OH, and closo-1,5-Cl2-[2,3,4-(5-C5Me5)3(-H)2Co3B2] from closo-[2,3,4-(5-C5Me5)3(-H)2Co3B2H2]
Kathryn J. Deck, Paula Brenton, and Thomas P. Fehlner
pp 554 - 558; DOI:
10.1021/ic961184e
PDF
W2Cl4(NR2)2(PR'3)2 Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and Characterizations of W2Cl4(NR2)2(PR'3)2 (R = Et, Bu, Hex; R'3 = Me3, Et2H) and an Intermediate Complex W2Cl4(NEt2)2(NHEt2)2
F. Albert Cotton, Evgeny V. Dikarev, N. Nawar, and Wai-Yeung Wong
pp 559 - 566; DOI:
10.1021/ic9610694
PDF
Synthesis, Structure, and Magnetic Properties of New Ru26+ Compounds
F. A. Cotton and and A. Yokochi
pp 567 - 570; DOI:
10.1021/ic960637c
PDF
Metal Substitution in Keggin-Type Tridecameric Aluminum-Oxo-Hydroxy Clusters
Wallace O'Neil Parker, Jr., Roberto Millini, and Imre Kiricsi
pp 571 - 575; DOI:
10.1021/ic960635s
PDF
Structural Dependence of Aromatic Ring Stacking and Related Weak Interactions in Ternary Amino Acid-Copper(II) Complexes and Its Biological Implication
Tamotsu Sugimori, Hideki Masuda, Nayumi Ohata, Kouji Koiwai, Akira Odani, and Osamu Yamauchi
pp 576 - 583; DOI:
10.1021/ic9608556
PDF
Photophysics of Ru(phen)2(PHEHAT)2+: A Novel "Light Switch" for DNA and Photo-oxidant for Mononucleotides
Cécile Moucheron, Andrée Kirsch-De Mesmaeker, and Sylvia Choua
pp 584 - 592; DOI:
10.1021/ic9609315
PDF
F430 Model Chemistry. An Investigation of Nickel Complexes as Catalysts for the Reduction of Alkyl Halides and Methyl Coenzyme-M by Sodium Borohydride
Alan M. Stolzenberg and Zhong Zhang
pp 593 - 600; DOI:
10.1021/ic960768d
PDF
Olefin-Amino Acid Complexes of Platinum(II). 3. NOE Difference and Low-Temperature NMR Determinations of Rotamer Populations of Coordinated Olefins and the Stereoselectivity of Coordination of Prochiral Olefins
Kevin F. Morris, Luther E. Erickson, Biliana V. Panajotova, David W. Jiang, and Fei Ding
pp 601 - 607; DOI:
10.1021/ic9609665
PDF
EPR Spectra, Luminescence Data, and Radiationless Decay Processes of Copper(II) Porphyrins
Kurstan L. Cunningham, Kristina M. McNett, Rodney A. Pierce, Keith A. Davis, Holden H. Harris, David M. Falck, and David R. McMillin
pp 608 - 613; DOI:
10.1021/ic960604x
PDF
Reaction of Phenyl and Methyl Disulfide with ·Cr(CO)3C5Me5 and HCr(CO)3C5Me5. Metal Radical and Metal Hydride Reactivity at the Sulfur-Sulfur Bond. Different Mechanisms for Oxidative Addition of Alkyl and Aryl Disulfides
Telvin D. Ju, Kenneth B. Capps, Russell F. Lang, Gerald C. Roper, and Carl D. Hoff
pp 614 - 621; DOI:
10.1021/ic960294i
PDF
A Facile Trans to Gauche Conversion in Layered Silver Butanethiolate
Hilary G. Fijolek, Jill R. Grohal, Jennifer L. Sample, and Michael J. Natan
pp 622 - 628; DOI:
10.1021/ic961268n
PDF
Design, Synthesis, and X-ray Structural Characterization of New Dinucleating Macrocyclic Ligands and a Novel Phenolate-Bridged Dilanthanum(III) Complex
Zheng Wang, Joseph Reibenspies, and Arthur E. Martell
pp 629 - 636; DOI:
10.1021/ic960665v
PDF
Mononuclear and Binuclear Molybdenum(V) Complexes of the Ligand N,N'-Dimethyl-N,N'-bis(2-mercaptophenyl)ethylenediamine: Geometric Isomers
Keith R. Barnard, Michael Bruck, Susan Huber, Carina Grittini, John H. Enemark, Robert W. Gable, and Anthony G. Wedd
pp 637 - 649; DOI:
10.1021/ic960848h
PDF
Mechanism of Linkage Isomerization in (1-5-Chloropentene)pentacarbonylchromium(0)
Santino Ladogana, Suresh K. Nayak, Jaap P. Smit, and Gerard R. Dobson
pp 650 - 655; DOI:
10.1021/ic960347w
PDF
Solid State and Solution Study of Trinuclear (Ni, Ba, Ni) Complexes: (L12Ni)2Ba(ClO4)2·2H2O (1) and (L22Ni)2Ba(ClO4)2·2H2O (2) (L1 = 3-Methoxysalicylaldiminato and L2 = 3-(2-Methoxyethoxy)salicylaldiminato). Crystal and Molecular Structure of 2
Jean-Pierre Costes, Jean-Pierre Laurent, Philippe Chabert, Gérard Commenges, and Françoise Dahan
pp 656 - 660; DOI:
10.1021/ic960856y
PDF
Synthesis, Structure, Magnetism, and Spectroscopic Properties of Some Mono- and Dinuclear Nickel Complexes Containing Noninnocent Pentane-2,4-dione Bis(S-alkylisothiosemicarbazonate)-Derived Ligands
Vladimir Arion, Karl Wieghardt, Thomas Weyhermueller, Eckhard Bill, Vukadin Leovac, and Anna Rufinska
pp 661 - 669; DOI:
10.1021/ic960802o
PDF
Synthesis, Crystal Structure, and Magnetic Properties of a Ferrimagnetic Layered Compound [NEt4][Mn(5-Cl-salen)]2[Fe(CN)6] (NEt4 = Tetraethylammonium, 5-Cl-salen = N,N'-Ethylenebis((5-chlorosalicylidene)aminato))
Hitoshi Miyasaka, Naohide Matsumoto, Nazzareno Re, Emma Gallo, and Carlo Floriani
pp 670 - 676; DOI:
10.1021/ic9608814
PDF
Alternating Ferromagnetic-Antiferromagnetic Interactions in a Manganese(II)-Azido One-Dimensional Compound: [Mn(bipy)(N3)2]
Roberto Cortés, Marc Drillon, Xavier Solans, Luis Lezama, and Teófilo Rojo
pp 677 - 683; DOI:
10.1021/ic961017e
PDF
Rb2Hg3Te4: A New Layered Compound Synthesized from Solvothermal Reactions
Jing Li, Zhen Chen, Kin-Chung Lam, Suzanne Mulley, and Davide M. Proserpio
pp 684 - 687; DOI:
10.1021/ic960566h
PDF
Reaction of Bis(N,N-dimethylthiocarbamoyl) Sulfide with Copper(II) Halides and the Crystal and Molecular Structures of Halogeno(bis(N,N-dimethylthiocarbamoyl) sulfido)copper(I) Complexes
Luis I. Victoriano, María Teresa Garland, and Andrés Vega
pp 688 - 693; DOI:
10.1021/ic960625r
PDF
Theoretical Study on the Structures of Iminopnictoranes and Their Reactions with Formaldehyde
Jugo Koketsu, Yoshihiko Ninomiya, Yoshizo Suzuki, and Nobuaki Koga
pp 694 - 702; DOI:
10.1021/ic951220u
PDF
Synthesis, Structure, and Properties of Ca16Sb11, a Complex Zintl Phase. Twelve Other Isotypic Compounds Formed by Divalent Metals and Pnictogens
E. Alejandro Leon-Escamilla, Weir-Mirn Hurng, Eric S. Peterson, and John D. Corbett
pp 703 - 710; DOI:
10.1021/ic961035w
PDF
Heterolytic H2 Activation by Dihydrogen Complexes. Effects of the Ligand X in [M(X)H2{Ph2P(CH2)3PPh2}2]n+ (M = Ru, Os; X = CO, Cl, H)
Eliana Rocchini, Antonio Mezzetti, Heinz Rüegger, Urs Burckhardt, Volker Gramlich, Alessandro Del Zotto, Paolo Martinuzzi, and Pierluigi Rigo
pp 711 - 720; DOI:
10.1021/ic9605579
PDF
Near-Infrared Electronic Spectroscopy and Emitting-State Properties of K2PdCl4 and K2PdBr4
Yanick Pelletier and Christian Reber
pp 721 - 728; DOI:
10.1021/ic960388s
PDF
Kinetic and Spectroscopic Studies on -Cyclodextrin Rotaxanes with Pentacyano(cyanopyridinium)ferrate(II) Stoppers
Angela P. Lyon and Donal H. Macartney
pp 729 - 736; DOI:
10.1021/ic961117k
PDF
Preparation and X-ray Crystal Structure of the Polymeric Zirconium(IV) Oxalate Complex [K2{Zr(C2O4)3}·H2C2O4·H2O]n
Ricardo Baggio, Maria Teresa Garland, and Mireille Perec
pp 737 - 739; DOI:
10.1021/ic960987z
PDF
Ab Initio Study of Cyclenphosphorane: The Molecular Structures of Phosphorus(III) and Phosphorus(V) Tautomers
Gyusung Chung, Ohyun Kwon, and Younghi Kwon
pp 740 - 742; DOI:
10.1021/ic9606744
PDF
A Trinuclear Nickel(II) Complex Based on Bridging Oxalate and Cyanide Ligands
Iñaki Muga, Juan M. Gutiérrez-Zorrilla, Antonio Luque, Pascual Román, and Francesc Lloret
pp 743 - 745; DOI:
10.1021/ic960874f
PDF
Use of Perfluorodecalin as a Reaction Medium for the Preparation of Anhydrous Metal Bromides
Thomas G. Hibbert, Dennis G. Tuck, and Kenneth Wade
pp 746 - 746; DOI:
10.1021/ic9611148
PDF
Low-Coordinate Homoleptic Iron(II) Thiolates Revisited
David J. Evans, David L. Hughes, and Jack Silver
pp 747 - 748; DOI:
10.1021/ic960929d
PDF
Autoionization of SmI3 in Tetrahydrofuran. X-ray Crystal Structure of the Ionic Complex [SmI2(THF)5][SmI4(THF)2]
Zuowei Xie, Ka-yue Chiu, Bomu Wu, and Thomas C.W. Mak
pp 748 - 748; DOI:
10.1021/ic961411c
PDF
One-Step Preparation of Dimethyl Sulfide Substituted Icosahedral Boranes: The Crystal and Molecular Structures of 1,7-(SMe2)2B12H10, 1,12-(SMe2)2B12H10, and [SMe3][B12H11(SMe2)]·MeCN
Ewan J. M. Hamilton, Glenn T. Jordan IV, Edward A.Meyers, and Sheldon G. Shore
pp 748 - 748; DOI:
10.1021/ic961472a
PDF

Issue 5


Mark E. Vol'pin 1923-1996 IN MEMORIAM
Y.N. Bubnov
pp 749 - 750; DOI:
10.1021/ic961441f
PDF
Organization of Amino Acids Using a Metallotriazacyclononane Template
Andrew A. Watson, Anthony C. Willis, and David P. Fairlie
pp 752 - 753; DOI:
10.1021/ic960867r
PDF
Theoretical Study of the Dimerization of Multiply-Bonded Aluminum-Nitrogen Compounds
Tracy P. Hamilton and and Adam W. Shaikh
pp 754 - 755; DOI:
10.1021/ic961248l
PDF
Correlation of EPR Parameters with Electronic Structure in the Homologous Series of Low-Symmetry Complexes Tp*MoOX2 (Tp* = Hydrotris(3,5-dimethylpyrazol-1-yl)borate; X = F, Cl, Br)
Norriel S. Nipales and T. David Westmoreland
pp 756 - 757; DOI:
10.1021/ic960913n
PDF
CIDNP in the Photolysis of Coenzyme B12 Model Compounds Suggesting That C-Co Bond Homolysis Occurs from the Singlet State
Alexander I. Kruppa, Marc B. Taraban, Tatyana V. Leshina, Ettaya Natarajan and, and Charles B. Grissom
pp 758 - 759; DOI:
10.1021/ic960562c
PDF
Raman Spectra of M2(OR)6 and M2R6 (M = Mo, W) Compounds: Assignment of the MM Stretching Frequency in M2X6 Dimers
John C. Littrell, Chad E. Talley, Richard F. Dallinger, and Thomas M. Gilbert
pp 760 - 761; DOI:
10.1021/ic9608049
PDF
Electropolymerization of Molecular Assemblies
John A. Moss, Roberto Argazzi, Carlo A. Bignozzi, and Thomas J. Meyer
pp 762 - 763; DOI:
10.1021/ic960902u
PDF
Synthesis and Excited State Raman Spectroscopy of Sterically Crowded Ruthenium(II) Octaethyltetraphenylporphyrin
S. E. Vitols, J. Scott Roman, Daniel E. Ryan, Milton E. Blackwood, Jr., and Thomas G. Spiro
pp 764 - 769; DOI:
10.1021/ic960773h
PDF
Phosphorus Nuclear Magnetic Shielding Anisotropy and Crystal Structure of (1-Hydroxyalkyl)dimethylphosphine Sulfides
Gisbert Grossmann, Kerstin Krüger, Gisela Ohms, Axel Fischer, Peter G. Jones, Jens Goerlich, and Reinhard Schmutzler
pp 770 - 775; DOI:
10.1021/ic960469o
PDF
Thermodynamic Calculations for Reactions Involving Hydrogen Halide Polymers, Ions, and Lewis Acid Adducts. 2. Polychlorohydrogenate(1-) Anions (HnCln+1-), Polychlorohydrogen(I) Cations (Hn+1Cln+), and Hydrogen Chloride Polymers (HCl)n
W. David Chandler, Keith E. Johnson, Bradley D. Fahlman, and John L. E. Campbell
pp 776 - 781; DOI:
10.1021/ic9607999
PDF
Effects of Molecular Electric Potential and Anisotropic Atomic Repulsion in the Dichlorine Dimer and Crystalline Chlorine
Donald E. Williams and Daquan Gao
pp 782 - 788; DOI:
10.1021/ic960592f
PDF
Excited-State Distortions in Bis[hydrotris(3,5-dimethyl-1-pyrazolyl)borato]copper(II) Determined from Resonance Raman Intensities and a Normal Coordinate Analysis
Jeffrey L. Wootton, Jeffrey I. Zink, Guillermo Díaz Fleming, and Marcelo Campos Vallette
pp 789 - 795; DOI:
10.1021/ic961006l
PDF
Structure and Assignment of the Luminescence of a New Mixed-Ligand Copper(I) Polymer
Maher Henary, Jeffrey L. Wootton, Saeed I. Khan, and Jeffrey I. Zink
pp 796 - 801; DOI:
10.1021/ic9610593
PDF
Synthesis of Cage Compounds Containing Boron, Germanium, and Phosphorus Atoms
Tuqiang Chen, Eileen N. Duesler, Robert T. Paine, and H. Nöth
pp 802 - 808; DOI:
10.1021/ic961026n
PDF
Butyllithium Deprotonation vs Alkali Metal Reduction of Cobalt Dicarbollide: A New Synthetic Route to C-Substituted Derivatives
Rebecca Miller Chamberlin, Brian L. Scott, Miryam M. Melo, and Kent D. Abney
pp 809 - 817; DOI:
10.1021/ic960811x
PDF
N-1- and 2-Pyrimidine Linkage Isomers in Complexes of [RuII(hedta)]-
Ya Chen, Fu-Tyan Lin, and Rex E. Shepherd
pp 818 - 826; DOI:
10.1021/ic961048+
PDF
Electrochemically Switched Anion Translocation in a Multicomponent Coordination Compound
Giancarlo De Santis, Luigi Fabbrizzi, Daniela Iacopino, Piersandro Pallavicini, Angelo Perotti, and Antonio Poggi
pp 827 - 832; DOI:
10.1021/ic960892x
PDF
Synthesis, Characterization, and Spectral Properties of New Perpendicularly Linked Osmium(II) Porphyrin Oligomers
Nobuko Kariya, Taira Imamura, and Yoichi Sasaki
pp 833 - 839; DOI:
10.1021/ic960878k
PDF
EPR and 2H NMR Studies on the Oxidation of Nickel(II) Tetraphenylcarbaporphyrin To Form Novel Organometallic Nickel(III) Complexes
Piotr J. Chmielewski and Lechosaw Latos-Grayski
pp 840 - 845; DOI:
10.1021/ic9608760
PDF
Structure and Electrochemical Studies of [(trispicMeen)ClFeIIIOFeIIICl(trispicMeen)]2+. Spectroscopic Characterization of the Mixed-Valence FeIIIOFeII Form. Relevance to the Active Site of Dinuclear Iron-Oxo Proteins
Alexander L. Nivorozhkin, Elodie Anxolabéhère-Mallart, Pierre Mialane, Roman Davydov, Jean Guilhem, Michèle Cesario, Jean-Paul Audière, Jean-Jacques Girerd, Stenbjorn Styring, Lutz Schussler, and Jean-Louis Seris
pp 846 - 853; DOI:
10.1021/ic951084t
PDF
Crystal and Molecular Structures of Asymmetric cis- and trans-Platinum(II/IV) Compounds and Their Reactions with DNA Fragments
Eduard G. Talman, Wolfgang Brüning, Jan Reedijk, Anthony L. Spek, and Nora Veldman
pp 854 - 861; DOI:
10.1021/ic960983u
PDF
Synthesis and Characterization of Poly(alumosiloxane)-Bound (Ether-phosphine)ruthenium(II) Complexes
Ekkehard Lindner, Andreas Jäger, Martin Kemmler, Friedrich Auer, Peter Wegner, Hermann A. Mayer, Andreas Benez, and Erich Plies
pp 862 - 866; DOI:
10.1021/ic960076p
PDF
A New Bridging Ligand for the [Mo2]4+ Dimer: Syntheses and X-ray Crystal Structures of the Redox Pair [Mo2{-2-(NPh)2CNHPh}4]0/+
Philip J. Bailey, Simon F. Bone, Lindsey A. Mitchell, Simon Parsons, Kenneth J. Taylor, and Lesley J. Yellowlees
pp 867 - 871; DOI:
10.1021/ic960712j
PDF
The [Cl2OMo(-OC2H5)2(-HOC2H5)MoOCl2]/PMe3 System: A Chameleon Yielding the X-ray Structures of MoOCl2(PMe3)3, MoOCl3(PMe3)2, Mo4O4Cl4(2-OEt)4(PMe3)2(3-O)2, and MoOCl3(OPMe3)(PMe3)
Christian Limberg, Michael Büchner, Katja Heinze, and Olaf Walter
pp 872 - 879; DOI:
10.1021/ic961046p
PDF
Manganese(II) Hexafluoroarsenate: Unusually High Coordination of Manganese(II) in a Fluorine Environment
Horst Borrmann, Karel Lutar, and Boris emva
pp 880 - 882; DOI:
10.1021/ic960814+
PDF
Sol-Gel Synthesis of Layered Birnessite-Type Manganese Oxides
Stanton Ching, Diana J. Petrovay, Matthew L. Jorgensen, and Steven L. Suib
pp 883 - 890; DOI:
10.1021/ic961088d
PDF
Hydrosilation Reactions Catalyzed by Supported Bimetallic Colloids
Günter Schmid, Heike West, Horst Mehles, and Andreas Lehnert
pp 891 - 895; DOI:
10.1021/ic960762o
PDF
Cleavage of Formamidinate Ligands on a Ta=Ta Double Bond: Formation of HxCNAryl (x = 0 and 1) and Arylimido-Bridged Complexes
F. Albert Cotton, Lee M. Daniels, Carlos A. Murillo, and Xiaoping Wang
pp 896 - 901; DOI:
10.1021/ic9611507
PDF
W2Cl4(NR2)2(PR'3)2 Molecules. 5. Preparation and Characterization of W2Cl4(NEt2)2(L-L) (L-L = dmpm, dmpe, dppe), W2Cl4(NBu2)2(L-L) (L-L = dmpm, dmpe), and W2Cl4(NHex2)2(dmpm). First Complexes with Bridging Diphosphine Ligands in a cis,trans-Stereochemistry
F. Albert Cotton, Evgeny V. Dikarev, and Wai-Yeung Wong
pp 902 - 912; DOI:
10.1021/ic961151z
PDF
Linear-Chain Structures of Platinum(II) Diimine Complexes
William B. Connick, Richard E. Marsh, William P. Schaefer, and Harry B. Gray
pp 913 - 922; DOI:
10.1021/ic961232v
PDF
Coordination Polymers of Co(NCS)2 with Pyrazine and 4,4'-Bipyridine: Syntheses and Structures
Jian Lu, Tasneem Paliwala, Shiao C. Lim, Carolyn Yu, Tianyan Niu, and Allan J. Jacobson
pp 923 - 929; DOI:
10.1021/ic961158g
PDF
Design and Magnetic Properties of a Magnetically Isolated GdIIICuII Pair. Crystal Structures of [Gd(hfa)3Cu(salen)], [Y(hfa)3Cu(salen)], [Gd(hfa)3Cu(salen)(Meim)], and [La(hfa)3(H2O)Cu(salen)] [hfa = Hexafluoroacetylacetonato, salen = N,N'-Ethylenebis(salicylideneaminato), Meim = 1-Methylimidazole]
Isabelle Ramade, Olivier Kahn, Yves Jeannin, and Francis Robert
pp 930 - 936; DOI:
10.1021/ic9607595
PDF
Assignment of Electronic Spectra of the Platinum(III) Dimer Complexes [Pt2(SO4)4(H2O)2]2- and [Pt2(HPO4)4(H2O)2]2-
Robert Stranger, Sandra C. Nissen, Michael T. Mathieson, and Trevor G. Appleton
pp 937 - 939; DOI:
10.1021/ic951614l
PDF
Reaction of 5-(CH3)2S-6-[((CH3)3Si)2C=CH]B10H11 with Cyclopentadienylnickel Carbonyl Dimer
William Quintana
pp 940 - 941; DOI:
10.1021/ic9604369
PDF
Different Products from the Chemical and Electrochemical Reduction of "HgSe2": [K(2.2.2-cryptand)]2[HgSe2] and [PPh4]2[Hg(Se4)2]·en
Chang-Woo Park, Donna M. Smith, Michael A. Pell, and James A. Ibers
pp 942 - 943; DOI:
10.1021/ic960786v
PDF
Syntheses and Characterizations of the New Tetranuclear Rhenium Cluster Compounds Re4(3-Q)4(TeCl2)4Cl8 (Q = S, Se, Te)
Yuri V. Mironov, Thomas E. Albrecht-Schmitt, and James A. Ibers
pp 944 - 946; DOI:
10.1021/ic961011p
PDF
Synthesis, Characterization, and Reactivity toward Nickel(II) of the New Saturated 14-Membered P2S2 Macrocycles cis- and trans-1,8-Diphenyl-1,8-diphospha-4,12-dithia- cyclotetradecane
José Antonio Muñoz, Lluis Escriche, Jaume Casabó, Consuelo Pérez-Jiménez, Raikko Kivekäs, and Reijo Sillanpää
pp 947 - 949; DOI:
10.1021/ic960611l
PDF
Synthesis and X-ray Structure of the Mononuclear Nine-Coordinate Gadolinium(III) Hydrogen Oxydiacetate [Gd(C4H5O5)3]·C4H6O5·H2O
Ricardo Baggio, Maria Teresa Garland, and Mireille Perec
pp 950 - 952; DOI:
10.1021/ic960974l
PDF

Issue 6


Insights on the Excited State Electronic Structures of Ruthenium(II) Polypyridine Complexes Obtained by Step-Scan Fourier Transform Infrared Absorption Difference Time-Resolved Spectroscopy
Pingyun Chen, Kristin M. Omberg, Darius A. Kavaliunas, Joseph A. Treadway, Richard A. Palmer, and Thomas J. Meyer
pp 954 - 955; DOI:
10.1021/ic961328p
PDF
Hydrolysis of Unactivated Esters and Acetonitrile Hydration by a Hydroxo-Dicopper(II) Complex
Steven T. Frey, Narasimha N. Murthy, Susan T. Weintraub, Laurence K. Thompson, and Kenneth D. Karlin
pp 956 - 957; DOI:
10.1021/ic961439o
PDF
A New Generation of Nickel-dmit-Based Molecular Conductors Based on Fully Conjugated Bimetallic Complexes
Anthony E. Pullen, Ruth-Maria Olk, Stephan Zeltner, Eberhard Hoyer, Khalil A. Abboud, and John R. Reynolds
pp 958 - 959; DOI:
10.1021/ic9610389
PDF
Ligand Exchange and Molecular Aggregation of an Ag-Sn Heterobimetallic Complex: First Structural Characterization of an Ag-Sn Bond
Bernd Findeis, Lutz H. Gade, Ian J. Scowen, and Mary McPartlin
pp 960 - 961; DOI:
10.1021/ic9611352
PDF
Optical Properties of [Ru(phen)2dppz]2+ as a Function of Nonaqueous Environment
Rajesh B. Nair, Brian M. Cullum, and Catherine J. Murphy
pp 962 - 965; DOI:
10.1021/ic960862u
PDF
Gold Clustering at the Terminal Functions of Long-Chain Thiols and Amines
José M. López-de-Luzuriaga, Alexander Sladek, Annette Schier, and Hubert Schmidbaur
pp 966 - 968; DOI:
10.1021/ic961254h
PDF
Alkyl Transfer to Metal Thiolates: Kinetics, Active Species Identification, and Relevance to the DNA Methyl Phosphotriester Repair Center of Escherichia coli Ada
Jonathan J. Wilker and Stephen J. Lippard
pp 969 - 978; DOI:
10.1021/ic961082o
PDF
Metalloporphyrin Peroxo Complexes of Iron(III), Manganese(III), and Titanium(IV). Comparative Studies Demonstrating That the Iron(III) Complex Is Extremely Nucleophilic
Marlene F. Sisemore, Matthias Selke, Judith N. Burstyn, and Joan Selverstone Valentine
pp 979 - 984; DOI:
10.1021/ic9612616
PDF
Mössbauer and Magnetization Studies of Heme-Copper-Bridged Assemblies Pertinent to Cytochrome c Oxidase
Karl E. Kauffmann, Christine A. Goddard, Yan Zang, R. H. Holm, and Eckard Münck
pp 985 - 993; DOI:
10.1021/ic960826v
PDF
Reactivity of Cubane-Type [(OC)3MFe3S4(SR)3]3- Clusters (M = Mo, W): Interconversion with Cuboidal [Fe3S4]0 Clusters and Electron Transfer
James W. Raebiger, Charles A. Crawford, Jian Zhou, and R. H. Holm
pp 994 - 1003; DOI:
10.1021/ic961122o
PDF
New Adducts of Dirhodium(II) Formamidinate Complexes with Polycyano Acceptor Molecules. X-ray Crystal Structure of the Tricyanomethanide Complex Rh2(form)4[C(CN)3] (form = N,N'-Di-p-tolylformamidinate)
Sandra Lo Schiavo, Giuseppe Bruno, Piero Zanello, Franco Laschi, and Pasquale Piraino
pp 1004 - 1012; DOI:
10.1021/ic9603868
PDF
Metal Dependence of the Highest Occupied Molecular Orbital in Sterically Hindered Octaethyltetraphenylporphyrins
Sharon A. Sibilia, Songzhou Hu, Christine Piffat, Dan Melamed, and Thomas G. Spiro
pp 1013 - 1019; DOI:
10.1021/ic960774+
PDF
Models for Arginine-Metal Binding. Synthesis of Guanidine and Urea Ligands through Amination and Hydration of a Cyanamide Ligand Bound to Platinum(II), Osmium(III), and Cobalt(III)
David P. Fairlie, W. Gregory Jackson, Brian W. Skelton, Huo Wen, Allan H. White, Wasantha A. Wickramasinghe, Tai Chin Woon, and Henry Taube
pp 1020 - 1028; DOI:
10.1021/ic961138e
PDF
Oxygen versus Nitrogen Bonding of Carboxamides to Pentaammineruthenium(II/III)
David P. Fairlie, Yigal Ilan, and Henry Taube
pp 1029 - 1037; DOI:
10.1021/ic9611406
PDF
Syntheses, X-ray Structures, and Solution Properties of [V4O4{(OCH2)3CCH3}3(OC2H5)3] and [V4O4{(OCH2)3CCH3}2(OCH3)6]: Examples of New Ligand Coordination Modes
Debbie C. Crans, Feilong Jiang, John Chen, Oren P. Anderson, and Mary M. Miller
pp 1038 - 1047; DOI:
10.1021/ic961037g
PDF
Molecular Structure of Trifluorophosphine Tetraborane(8), B4H8PF3, As Determined in the Gas Phase by Electron Diffraction and ab Initio Computations
Paul T. Brain, David W. H. Rankin, Heather E. Robertson, Mark A. Fox, Robert Greatrex, Alireza Nikrahi, and Michael Bühl
pp 1048 - 1054; DOI:
10.1021/ic961032j
PDF
M2L6 Complexes with Triple Mo-Mo and W-W Bonds: Molecular Topology and Inverted Pyramidality Effect
Xiang-Yang Liu and Santiago Alvarez
pp 1055 - 1060; DOI:
10.1021/ic9612358
PDF
Ab Initio and Experimental Studies on the Structure and Relative Stability of the cis-Hydride-2-Dihydrogen Complexes [{P(CH2CH2PPh2)3}M(H)(2-H2)]+ (M = Fe, Ru)
Claudio Bianchini, Dante Masi, Maurizio Peruzzini, Maurizio Casarin, Chiara Maccato, and Gian Andrea Rizzi
pp 1061 - 1069; DOI:
10.1021/ic960736q
PDF
Synthesis of Cage Compounds Containing Boron, Tin, and Phosphorus Atoms
Tuqiang Chen, Eileen N. Duesler, Robert T. Paine, and H. Nöth
pp 1070 - 1075; DOI:
10.1021/ic9612818
PDF
Labile Complexes of the [RuTp(pn)]+ (Tp = Tripyrazolylborate, pn = Ph2PCH2CH2NMe2) Fragment Including the Dinitrogen Ligand
Gregor Trimmel, Christian Slugovc, Petra Wiede, Kurt Mereiter, Valentin N. Sapunov, Roland Schmid, and Karl Kirchner
pp 1076 - 1083; DOI:
10.1021/ic961128d
PDF
Copper(I)-Purine-Phosphine Complexes. Syntheses and Molecular Structures of [Cu2(-HL1)2(-dppm)(1-dppm)2] and {[Cu3(3-Cl)2(-dppm)3][Cu(HL2)2]} (H2L1 = 8-Mercaptotheophylline and H2L2 = 8-Ethyl-3-methylxanthine)
E. Colacio, R. Cuesta, and J. M. Moreno
pp 1084 - 1087; DOI:
10.1021/ic960928l
PDF
Oxomolybdenum(V)/Iron(III) Porphyrinate Complexes: Effect of Axial Ligand Plane Orientation on Complex Stability, Reduction Potential, and NMR and EPR Spectra
Partha Basu, Arnold M. Raitsimring, John H. Enemark, and F. Ann Walker
pp 1088 - 1094; DOI:
10.1021/ic960945a
PDF
A Triad of Variable-Valent Rhenium Aldimine and Amide Systems Interrelated by Successive Oxygen Atom Transfer
Bimal Kumar Dirghangi, Mahua Menon, Amitava Pramanik, and Animesh Chakravorty
pp 1095 - 1101; DOI:
10.1021/ic9611094
PDF
Novel Cyclopentadienyl-Free Organolanthanides: The First Examples of Five-Membered Amidolanthanide Heterocycles
Syed A. A. Shah, Hendrik Dorn, Herbert W. Roesky, Paolo Lubini, and Hans-Georg Schmidt
pp 1102 - 1106; DOI:
10.1021/ic961033b
PDF
Mononuclear Amido and Binuclear Imido Zirconium Complexes Supported by Dibenzotetraaza[14]annulene Ligands. X-ray Structure of [(Me4taa)Zr(-NR)2Zr(NHR)2] (R = But or 2,6-C6H3Me2)
Georgii I. Nikonov, Alexander J. Blake, and Philip Mountford
pp 1107 - 1112; DOI:
10.1021/ic961209+
PDF
Molecular Architecture of Polynuclear Ruthenium Bipyridyl Complexes with Controlled Metal Helicity
Nicholas C. Fletcher, F. Richard Keene, Heiko Viebrock, and Alex von Zelewsky
pp 1113 - 1121; DOI:
10.1021/ic960948n
PDF
ESR Studies of Oxochromium(V) Porphyrin Complexes: Electronic Structure of the CrV=O Moiety
Hiroshi Fujii, Tetsuhiko Yoshimura, and Hitoshi Kamada
pp 1122 - 1127; DOI:
10.1021/ic960722k
PDF
Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) Charge Transfer Salts of Re2(NCS)10n- (n = 2, 3)
Cameron J. Kepert, Mohamedally Kurmoo, and Peter Day
pp 1128 - 1135; DOI:
10.1021/ic960884g
PDF
Nitrogen- vs Carbon-Coordination of the -Cyano-Stabilized Phosphorus Ylide Ph3P=C(H)CN. X-ray Crystal Structure of {Pd(dmba)[P(OMe)3][NC-C(H)=PPh3]}(ClO4)
Larry R. Falvello, Susana Fernández, Rafael Navarro, and Esteban P. Urriolabeitia
pp 1136 - 1142; DOI:
10.1021/ic960904e
PDF
Synthesis and Structure of One-, Two-, and Three-Dimensional Alkaline Earth Metal Gallium Nitrides: Sr3Ga2N4, Ca3Ga2N4, and Sr3Ga3N5
S. J. Clarke and F. J. DiSalvo
pp 1143 - 1148; DOI:
10.1021/ic9612562
PDF
Comparative Analysis of the Conformations of Symmetrically and Asymmetrically Deca- and Undecasubstituted Porphyrins Bearing Meso-Alkyl or -Aryl Groups
Mathias O. Senge, Craig J. Medforth, Timothy P. Forsyth, David A. Lee, Marilyn M. Olmstead, Walter Jentzen, Ravindra K. Pandey, John A. Shelnutt, and Kevin M. Smith
pp 1149 - 1163; DOI:
10.1021/ic961156w
PDF
MCD Spectra for Metal-Centered Transitions in the Hg3(dppm)34+ Cluster Complex
W. Roy Mason
pp 1164 - 1167; DOI:
10.1021/ic9607447
PDF
High Superoxide Dismutase Activity of a Novel, Intramolecularly Imidazolato-Bridged Asymmetric Dicopper(II) Species. Design, Synthesis, Structure, and Magnetism of Copper(II) Complexes with a Mixed Pyrazole-Imidazole Donor Set
Giovanni Tabbì, Willem L. Driessen, Jan Reedijk, Raffaele P. Bonomo, Nora Veldman, and Anthony L. Spek
pp 1168 - 1175; DOI:
10.1021/ic961260d
PDF
Crystal Structure and Absorption Spectroscopy of a Neodymium(III) Complex with Triethylenetetraaminehexaacetic Acid, Na3[Nd(TTHA)]·2.5NaClO4·7.617H2O
Anna Mondry and and Przemysaw Starynowicz
pp 1176 - 1180; DOI:
10.1021/ic9604728
PDF
Synthetic, Spectroscopic, and Electrochemical Studies of the Isomerically-Rich [M(CO)2(P2P')X]+/0 (M = Mn, Re; X = Cl, Br; P2P' = 3-Ph2P(CH2)2P(Ph)(CH2)2PPh2) System: Structural Characterization of a Novel Pair of Diastereoisomers of cis,mer-Re(CO)2(P2P')Cl
Alan M. Bond, Ray Colton, Robert W. Gable, Maureen F. Mackay, and Jacky N. Walter
pp 1181 - 1193; DOI:
10.1021/ic961295d
PDF
Preparation and Characterization of a Homoleptic Vanadium(III) Amide Complex and Its Transformation into Terminal Chalcogenide Derivatives [(3,5-Me2Ph)AdN]3V=E (E = S, Se; Ad = Adamantyl)
Kamalesh B. P. Ruppa, Nathalie Desmangles, Sandro Gambarotta, Glenn Yap, and Arnold L. Rheingold
pp 1194 - 1197; DOI:
10.1021/ic961168h
PDF
Density Functional Calculations of Electronic Structure, Charge Distribution, and Spin Coupling in Manganese-Oxo Dimer Complexes
X. G. Zhao, W. H. Richardson, J.-L. Chen, J. Li, L. Noodleman, H.-L. Tsai, and D. N. Hendrickson
pp 1198 - 1217; DOI:
10.1021/ic9514307
PDF
Syntheses, X-ray Crystal Structures, and Spectroscopic Properties of New Nickel Dithiolenes and Related Compounds
Francesco Bigoli, Paola Deplano, Francesco A. Devillanova, John. R. Ferraro, Vito Lippolis, Peter J. Lukes, Maria Laura Mercuri, Maria Angela Pellinghelli, Emanuele F. Trogu, and Jack M. Williams
pp 1218 - 1226; DOI:
10.1021/ic960930c
PDF
Gutmann Acceptor Properties of LiCl, NaCl, and KCl Buffered Ambient-Temperature Chloroaluminate Ionic Liquids
Robert A. Mantz, Paul C. Trulove, Richard T. Carlin, Terry L. Theim, and Robert A. Osteryoung
pp 1227 - 1232; DOI:
10.1021/ic960994n
PDF
Structure and Magnetic Behavior of a New 1-D Compound with Simultaneous End-On Azido and Carboxylato Bridges. Unexpected Strong Ferromagnetic Coupling for a Cu-N-Cu Bond Angle of 111.9 as a Consequence of Ligand HOMOs Countercomplementarity
Albert Escuer, Ramon Vicente, Franz A. Mautner, and Mohamed A. S. Goher
pp 1233 - 1236; DOI:
10.1021/ic961107j
PDF
Solvent Dependence of the Reaction of (5-C5Me5)Ir(CO)2 with Aryldiazonium Ions. Synthesis and Characterization of Mono- and Diiridium Carbonyl Complexes Including the X-ray Structures of [{(5-C5Me5)Ir(CO)}2(1-1-1,2-2-p-C6H4OMe)][BF4] and [(5-C5Me5)(CO)2Ir-Ir(CO)(Cl)(5-C5Me5)][BF4]
Xiaoqian Yan, Raymond J. Batchelor, Frederick W. B. Einstein, Xiaoheng Zhang, Ruby Nagelkerke, and Derek Sutton
pp 1237 - 1246; DOI:
10.1021/ic960993v
PDF
Synthesis, Crystal Structure, and Second-Order Optical Nonlinearity of Bis(2-chlorobenzaldehyde thiosemicarbazone)cadmium Halides (CdL2X2; X = Br, I)
Yu-peng Tian, Chun-ying Duan, Cun-yuan Zhao, Xiao-zeng You, Thomas C. W. Mak, and Ze-ying Zhang
pp 1247 - 1252; DOI:
10.1021/ic9603870
PDF
Heterometallic Complexes with Selenolate Ligands: Crystal Structures of [(CO)3Mn(-SePh)3Co(-SePh)3Mn(CO)3]-, (CO)4Mn(-SeMe)2Co(CO)(-SeMe)3Mn(CO)3, and [(CO)3Mn(-SePh)3Mn(CO)3]-
Wen-Feng Liaw, Way-Zen Lee, Chun-Yuan Wang, Gene-Hsiang Lee, and Shie-Ming Peng
pp 1253 - 1257; DOI:
10.1021/ic9607797
PDF
Conversion of Hydrosilanes to Silanols and Silyl Esters Catalyzed by [Ph3PCuH]6
Ulrich Schubert and and Catrin Lorenz
pp 1258 - 1259; DOI:
10.1021/ic961134+
PDF
C-S Bond Cleavage Routes to the Titanium-Sulfide Complexes (CpTi)6(3-S)4(3-O)4 and (CpTi)4(3-S)3(2-S)(2-SEt)2 (Cp = -C5H5)
Andrea V. Firth and Douglas W. Stephan
pp 1260 - 1262; DOI:
10.1021/ic961520r
PDF
An Unusual Coordination Mode in a Bis(dialkyldithiocarbamato)zinc(II) Adduct with N,N,N',N'-Tetramethylethylenediamine: X-ray Crystal Structures of 2[MeiPrNCS2]2Zn·Me2N(CH2)2NMe2 and [MeiPrNCS2]2Zn·C5H5N
M. A. Malik, M. Motevalli, P. O'Brien, and J. R. Walsh
pp 1263 - 1264; DOI:
10.1021/ic9609158
PDF
Crystal Structures of the Isomorphous Prototypic Oxo-Centered Trinuclear Complexes [Cr3O(OOCCH3)6(H2O)3]Cl·6H2O and [Fe3O(OOCCH3)6(H2O)3]Cl·6H2O
C. E. Anson, J. P. Bourke, R. D. Cannon, U. A. Jayasooriya, M. Molinier, and A. K. Powell
pp 1265 - 1267; DOI:
10.1021/ic960960f
PDF
Structure and Reactivity of 1-Isothiocyanatosilatrane: The First Silatrane with a Direct Si-NCS Bond
Suraj P. Narula, Ravi Shankar, Manish Kumar, Raj K. Chadha, and Christopher Janaik
pp 1268 - 1273; DOI:
10.1021/ic960695y
PDF
Photoinduced Ligand Redistribution Chemistry of Quadruply Bonded Mo2Cl2(6-mhp)2(PR3)2 Complexes
Ann M. Macintosh and Daniel G. Nocera
pp 1274 - 1274; DOI:
10.1021/ic9700664
PDF

Issue 7


DNA-Photocleavage Activities of Vanadium(V)-Peroxo Complexes
Daniel W. J. Kwong, O. Y. Chan, Ricky N. S. Wong, Siegfried M. Musser, Luis Vaca, and Sunney I. Chan
pp 1276 - 1277; DOI:
10.1021/ic960909b
PDF
Hexa-, Hepta-, and Octacoordinate Boronium Ions:1 BH6+, BH72+, and BH83+
Golam Rasul and George A. Olah
pp 1278 - 1281; DOI:
10.1021/ic960843k
PDF
Stabilization by Hydrogen. Synthetic and Structural Studies of the Zintl Phase Ba5Ga6H2
Robert W. Henning, E. Alejandro Leon-Escamilla, Jing-Tai Zhao, and John D. Corbett
pp 1282 - 1285; DOI:
10.1021/ic9612966
PDF
Heterobimetallic Complexes with Phenylcyclopentadienyl Ligand: Syntheses and Structures of Tricarbonylchromium-6,5-Phenylcyclopentadienyl-Transition Metal Complexes
Changtao Qian, Jianhua Guo, Jie Sun, Jian Chen, and Peiju Zheng
pp 1286 - 1295; DOI:
10.1021/ic951630i
PDF
Aryldiazene, Aryldiazenido, and Hydrazine Complexes of Manganese. Preparation, Characterization, and X-ray Crystal Structures of [Mn(CO)3(4-CH3C6H4N=NH){PPh(OEt)2}2]BF4 and [Mn(CO)3(NH2NH2){PPh(OEt)2}2]BPh4 Derivatives
Gabriele Albertin, Stefano Antoniutti, Alessia Bacchi, Emilio Bordignon, Fabio Busatto, and Giancarlo Pelizzi
pp 1296 - 1305; DOI:
10.1021/ic9608612
PDF
Effect of Pyridyl Donors in the Chelation of Aluminum(III), Gallium(III), and Indium(III)
P. Caravan, Steven J. Rettig, and Chris Orvig
pp 1306 - 1315; DOI:
10.1021/ic961230a
PDF
Cationic Lanthanide Complexes of N,N'-Bis(2-pyridylmethyl)ethylenediamine-N,N'-diacetic Acid (H2bped)
P. Caravan, Parisa Mehrkhodavandi, and Chris Orvig
pp 1316 - 1321; DOI:
10.1021/ic9613016
PDF
Osmium-Promoted Oxidative Dimerization of Aminoarenes to N-Aryl-o-arenoquinone Diimines (L). Synthesis, Structure, Electrochemistry, and Reactivity of OsBr2L2
Kedar Nath Mitra and Sreebrata Goswami
pp 1322 - 1326; DOI:
10.1021/ic960420i
PDF
Syntheses and Structural Characterizations of Ferra- and Cobaltacarborane Complexes Derived from the arachno-6-R-5,6,7-C3B7H12 [R- = NCCH2-, MeOC(O)CH2-, MeC(O)CH2-] Tricarbaborane
Beverly A. Barnum, Patrick J. Carroll, and Larry G. Sneddon
pp 1327 - 1337; DOI:
10.1021/ic961253p
PDF
Disproportionation Kinetics of Hypoiodous Acid As Catalyzed and Suppressed by Acetic Acid-Acetate Buffer
Edward T. Urbansky, Brian T. Cooper, and Dale W. Margerum
pp 1338 - 1344; DOI:
10.1021/ic960745z
PDF
Luminescent Properties of Lanthanide Nitrato Complexes with Substituted Bis(benzimidazolyl)pyridines
Stéphane Petoud, Jean-Claude G. Bünzli, Kurt J. Schenk, and Claude Piguet
pp 1345 - 1353; DOI:
10.1021/ic961305a
PDF
trans-Difluorosilicon(IV) Complexes of Tetra-p-tolylporphyrin and Tetrakis(p-(trifluoromethyl)phenyl)porphyrin: Crystal Structures and Unprecedented Reactivity in Hexacoordinate Difluorosilanes
Kevin M. Kane and, Frederick R. Lemke, and Jeffrey L. Petersen
pp 1354 - 1359; DOI:
10.1021/ic960639x
PDF
Sulfido-Persulfido Equilibria in Sulfur-Rich Metal Clusters: The Case of (C5Me5)3RhRu2S42+
Anne Venturelli, Thomas B. Rauchfuss, and Atul K. Verma
pp 1360 - 1365; DOI:
10.1021/ic9609564
PDF
Polyoxoanion-Supported Organometallic Complexes: Carbonyls of Rhenium(I), Iridium(I), and Rhodium(I) That Are Soluble Analogs of Solid-Oxide-Supported M(CO)n+ and That Exhibit Novel M(CO)n+ Mobility
Toshi Nagata, Matthias Pohl, Heiko Weiner, and Richard G. Finke
pp 1366 - 1377; DOI:
10.1021/ic960910a
PDF
Enhancement of Zero Resistance Temperature above 90 K and Hole Distribution in (Hg0.5Pb0.5)Sr2(Ca0.7Y0.3)Cu2O7- via Chemical Substitution of Ba into Sr Sites
R. S. Liu, J. M. Chen, and D. S. Shy
pp 1378 - 1382; DOI:
10.1021/ic9611249
PDF
Synthesis of Heteronuclear Pt-Tl Complexes with Donor-Acceptor Bonds. X-ray Structures of cis-[Tl(2-OOCCH3)Pt(PPh3)(C6F5)2] and (NBu4)2[{Pt(C6F5)3}2{(2-O,3-O'CCH3)Tl}2]
Rafael Usón, Juan Forniés, Milagros Tomás, Raquel Garde, and Rosa I. Merino
pp 1383 - 1387; DOI:
10.1021/ic960453y
PDF
Formation, Properties, and Characterization of a Fully Reduced FeIIFeII Form of Spinach (and Parsley) [2Fe-2S] Ferredoxin with the Macrocyclic Complex [Cr(15-aneN4)(H2O)2]2+ as Reductant
Sang-Choul Im, Takamitsu Kohzuma, William McFarlane, Jacques Gaillard, and A. Geoffrey Sykes
pp 1388 - 1396; DOI:
10.1021/ic9608253
PDF
Synthesis, Structure, and Reactivity of Ruthenium and Osmium Nitrido Complexes with 1,2-Benzenedithiolate Ligands: N- versus S-Alkylation
Dieter Sellmann, Michael W. Wemple, Wolfgang Donaubauer, and Frank W. Heinemann
pp 1397 - 1402; DOI:
10.1021/ic961240b
PDF
Stoichiometric Interconversion of S-Bridged RhIII2AgI3 Pentanuclear and RhIII4AgI5 Nonanuclear Structures: Synthesis and Structural Characterization of [Ag3{Rh(aet)3}2]3+ and [Ag5{Rh(aet)3}4]5+ (aet = 2-Aminoethanethiolate)
Takumi Konno and and Ken-ichi Okamoto
pp 1403 - 1406; DOI:
10.1021/ic960692l
PDF
Active Site Models for Galactose Oxidase. Electronic Effect of the Thioether Group in the Novel Organic Cofactor
Shinobu Itoh, Shigehisa Takayama, Ryuichi Arakawa, Akihiro Furuta, Mitsuo Komatsu, Akito Ishida, Setsuo Takamuku, and Shunichi Fukuzumi
pp 1407 - 1416; DOI:
10.1021/ic961144a
PDF
Copper Sites in Copper-Exchanged ZSM-5 for CO Activation and Methanol Synthesis: XPS and FTIR Studies
H. Y. Chen, L. Chen, J. Lin, K. L. Tan, and J. Li
pp 1417 - 1423; DOI:
10.1021/ic960122l
PDF
Vanadium Hydrotris(pyrazolyl)borate Complexes of Diphenyl Phosphate. Heterometallic Complexes of the [LV{(PhO)2PO2}3]- Fragment
Norman S. Dean, Ladd M. Mokry, Marcus R. Bond, Madan Mohan, Tom Otieno, C. J. O'Connor, K. Spartalian, and Carl J. Carrano
pp 1424 - 1430; DOI:
10.1021/ic960979i
PDF
Comparison of -Bond Strengths in M-E (M = B, Al, Ga; E = O, N, S) Compounds. Ab Initio Calculation of Rotational Barriers
William H. Fink, Philip P. Power, and Thomas L. Allen
pp 1431 - 1436; DOI:
10.1021/ic961111v
PDF
New Type of Polymeric Indium Tellurides: Low-Temperature Synthesis and Structure Characterization of [M(en)3]In2Te6 (M = Fe, Zn) and - and -[Mo3(en)3(2-Te2)3(3-Te)(3-O)]In2Te6
Jing Li, Zhen Chen, Thomas J. Emge, and Davide M. Proserpio
pp 1437 - 1442; DOI:
10.1021/ic960751v
PDF
Electronic Absorption and MCD Spectra for Pd(AuPPh3)82+, Pt(AuPPh3)82+, and Related Platinum-Centered Gold Cluster Complexes
Michael J. Adrowski and W. Roy Mason
pp 1443 - 1453; DOI:
10.1021/ic9606993
PDF
Complex Formation and Ligand Substitution Reactions of (2-Picolylamine)palladium(II) with Various Biologically Relevant Ligands. Characterization of (2-Picolylamine)(1,1-cyclobutanedicarboxylato)palladium(II)
Tobias Rau, Mohamed Shoukry, and Rudi van Eldik
pp 1454 - 1463; DOI:
10.1021/ic961192v
PDF
Preparation and NMR Spectra of the (Trifluoromethyl)argentates(III) [Ag(CF3)nX4-n]-, with X = CN (n = 1-3), CH3, CCC6H11, Cl, Br (n = 2, 3), and I (n = 3), and of Related Silver(III) Compounds. Structures of [PPh4][trans-Ag(CF3)2(CN)2] and [PPh4][Ag(CF3)3(CH3)]
Reint Eujen, Berthold Hoge, and David J. Brauer
pp 1464 - 1475; DOI:
10.1021/ic9610445
PDF
Reactions of Bis(triphenylphosphonio)isophosphindolide Salts with Mercury(II) Compounds: Coordination Induced Addition and Oxidation Reactions and Synthesis of a Monomeric 1:1 Complex of the Type [R2(R'O)P]HgBr2
Dietrich Gudat, Martin Nieger, and Martin Schrott
pp 1476 - 1481; DOI:
10.1021/ic960883o
PDF
Gas-Phase Characterization of Unhindered Silanimines by Photoelectron Spectroscopy: Experimental and Theoretical Study of the Si=N Double Bond
V. Metail, S. Joanteguy, A. Chrostowska-Senio, G. Pfister-Guillouzo, A. Systermans, and J. L. Ripoll
pp 1482 - 1487; DOI:
10.1021/ic960869b
PDF
In Situ, Time-Resolved X-ray Diffraction Study of the Solid-State Polymerization of Disulfur Dinitride to Poly(sulfur nitride)
H. Müller, S. O. Svensson, J. Birch, and Å. Kvick
pp 1488 - 1494; DOI:
10.1021/ic961141y
PDF
Alkaline Earth Metal and Lanthanide(III) Complexes of Ligands Based upon 1,4,7,10-Tetraazacyclododecane-1,7-bis(acetic acid)
Jurriaan Huskens, Diego A. Torres, Zoltan Kovacs, João P. André, Carlos F. G. C. Geraldes, and A. Dean Sherry
pp 1495 - 1503; DOI:
10.1021/ic961131x
PDF
Association of Oxo-Molybdenum Dithiolene Complexes with a Multiamide Additive and Its Influence on the Ease of O-Atom Transfer
Hiroyuki Oku, Norikazu Ueyama, and Akira Nakamura
pp 1504 - 1516; DOI:
10.1021/ic951277g
PDF
Intervalence Absorption, Ligand Interchange, and Redox Reactivity in Binuclear Cyanopyridine-Bridged Complexes Containing Pentacyanoruthenate(II) and Pentaammineruthenium(II) or -(III)
Alejandra E. Almaraz, Luis A. Gentil, Luis M. Baraldo, and José A. Olabe
pp 1517 - 1519; DOI:
10.1021/ic9606643
PDF
Reduction and Aerobic Oxidation of Hexaketocyclohexane (C6O6) by Reaction with Metallic Copper
Gábor Speier, Edit Speier, Bruce Noll, and Cortlandt G. Pierpont
pp 1520 - 1521; DOI:
10.1021/ic970077x
PDF
Intermolecular Hydrogen Bonding of ReH2(CO)(NO)L2 Hydrides with Perfluoro-tert-butyl Alcohol. Competition between M-H···H-OR and M-NO···H-OR Interactions
Natalia V. Belkova, Elena S. Shubina, Aleksei V. Ionidis, Lina M. Epstein, Heiko Jacobsen, Andreas Messmer, and Heinz Berke
pp 1522 - 1525; DOI:
10.1021/ic9608298
PDF
Hydrogen-Bonded Oximate-Oxime Chelation and Variable Metal Valence. Syntheses and Structures of RuCl2(L)(HL)z (HL = PhC(NOH)NNPh; z = 1-, 0)
Vadivelu Manivannan, Bimal Kumar Dirghangi, Chandan Kumar Pal, and Animesh Chakravorty
pp 1526 - 1528; DOI:
10.1021/ic960964k
PDF

Issue 8


Metamagnetic Behavior of the Novel Bimetallic Ferromagnetic Chain Compound MnNi(NO2)4(en)2 (en = Ethylenediamine)
Olivier Kahn, Evangelos Bakalbassis, Corine Mathonière, Masayuki Hagiwara, Koichi Katsumata, and Lahcène Ouahab
pp 1530 - 1531; DOI:
10.1021/ic9611453
PDF
Application of Capillary Electrophoresis for the Assessment of Enantiomeric Purity of -Diimine Transition Metal Complexes
Chris M. Shelton, Kathryn E. Seaver, John F. Wheeler, and Noel A. P. Kane-Maguire
pp 1532 - 1533; DOI:
10.1021/ic9612055
PDF
Assembly of a Triple-Cage Species Containing B, P, and Si Atoms
Tuqiang Chen, Eileen N. Duesler, Robert T. Paine, and H. Nöth
pp 1534 - 1535; DOI:
10.1021/ic961421d
PDF
Thermodynamic Properties of the Rare Earth Element Vapor Complexes LnAl3Cl12 from Ln = La to Ln = Lu
Zhi-Chang Wang and Lin-Shan Wang
pp 1536 - 1540; DOI:
10.1021/ic960746r
PDF
Density Functional Study of the Primary Photoprocesses of Manganese Pentacarbonyl Chloride (MnCl(CO)5)
Maikel P. Wilms, Evert Jan Baerends, Angela Rosa, and Derk J. Stufkens
pp 1541 - 1551; DOI:
10.1021/ic960688+
PDF
Cobalt as a Probe for Zinc in Metalloenzyme Model Compounds? A Comparison of Spectroscopic Features and Coordination Geometry of Four- and Five-Coordinate Complexes. Crystal and Molecular Structures of [Co(3-TpPh)(2-TpPh)], [(3-TpPh)Zn(anthranilate)], and [(3-TpPh)M(2-acac)] (TpPh = Hydrotris(3-phenylpyrazol-1-yl)borate, acac = Pentane-2,4-dionate, and M = Zn, Co)
Andreas Kremer-Aach, Wolfgang Kläui, Ralf Bell, Angela Strerath, Hartmut Wunderlich, and Dietrich Mootz
pp 1552 - 1563; DOI:
10.1021/ic961434r
PDF
Tetracoordinated Manganese(III) Alkylcorrolates. Spectroscopic Studies and the Crystal and Molecular Structure of (7,13-Dimethyl-2,3,8,12,17,18-hexaethylcorrolato)manganese(III)
Silvia Licoccia, Elisabetta Morgante, Roberto Paolesse, Francesca Polizio, Mathias O. Senge, Eugenio Tondello, and Tristano Boschi
pp 1564 - 1570; DOI:
10.1021/ic960334i
PDF
Incorporation of Group 11 Metal Ions into a Diplatinum Center Leading to Pt2M Heterotrinuclear Complexes Supported by a Tridentate Phosphine Ligand (M = Au, Ag, Cu)
Tomoaki Tanase, Hirotaka Toda, and Yasuhiro Yamamoto
pp 1571 - 1577; DOI:
10.1021/ic960771x
PDF
Template Synthesis and Reactions of Tricarbonylmolybdenum Phosphadithiamacrocycle Complexes
Philip J. Blower, John C. Jeffery, John R. Miller, Spencer N. Salek, Dirk Schmaljohann, Raymond J. Smith, and Michael J. Went
pp 1578 - 1582; DOI:
10.1021/ic961143i
PDF
Metal-Stabilized Rare Tautomers of Nucleobases. 6. Imino Tautomer of Adenine in a Mixed-Nucleobase Complex of Mercury(II)
Félix Zamora, Michele Kunsman, Michal Sabat, and Bernhard Lippert
pp 1583 - 1587; DOI:
10.1021/ic961167p
PDF
Self-Assembly of Homochiral Double Helix and Side-by-Side Helix Conformers of Double-Stranded Disilver(I)- and Digold(I)-Tetra(tertiary phosphine) Helicates
Anthea L. Airey, Gerhard F. Swiegers, Anthony C. Willis, and S. Bruce Wild
pp 1588 - 1597; DOI:
10.1021/ic9610344
PDF
Fluoro[3-hydrotris(3-R-5-methylpyrazol-1-yl)borato]zinc(II): The First TpZnF Complexes, Convenient Precursors to Zinc Hydride Complexes
Wolfgang Kläui, Uwe Schilde, and Michael Schmidt
pp 1598 - 1601; DOI:
10.1021/ic961249d
PDF
Crystal Chemistry of Gallium(I) in Oxides: Ga+-''-Alumina and GaZr2(PO4)3
A. P. Wilkinson
pp 1602 - 1607; DOI:
10.1021/ic961103e
PDF
A One-Dimensional Helical Copper(II) Imino Nitroxide
Hiroki Oshio, Takashi Watanabe, Akihiro Ohto, and Tasuku Ito
pp 1608 - 1610; DOI:
10.1021/ic960938m
PDF
1H and 31P NMR of Pentaammineruthenium(III) Complexes of Exocyclically-Coordinated Adenine and Cytosine Ligands. Evidence for Rotamers with Distinct Acidities
V. M. Rodriguez-Bailey and M. J. Clarke
pp 1611 - 1618; DOI:
10.1021/ic9610142
PDF
Extent of Intramolecular Aromatic-Ring Stacking in Ternary Cu2+ Complexes Formed by 2,2'-Bipyridyl or 1,10-Phenanthroline and Flavin Mononucleotide (FMN2-)
Matthias Bastian and Helmut Sigel
pp 1619 - 1624; DOI:
10.1021/ic961179a
PDF
Perpendicularly Arranged Ruthenium Porphyrin Dimers and Trimers
Kenji Funatsu, Akira Kimura, Taira Imamura, Akio Ichimura, and Yoichi Sasaki
pp 1625 - 1635; DOI:
10.1021/ic961154b
PDF
Dinuclear (d3-d3) Diolate Complexes of Molybdenum and Tungsten. 1. Preparation and Characterization of Complexes Derived from 2,5-Dimethylhexane-2,5-diol
M. H. Chisholm, I. P. Parkin, K. Folting, and E. Lobkovsky
pp 1636 - 1641; DOI:
10.1021/ic961133h
PDF
Dinuclear (d3-d3) Diolate Complexes of Molybdenum and Tungsten. 2.1 Derivatives of 2,2'-Methylenebis(6-tert-butyl-4-methylphenoxide). Direct Observation of the Conversion of Bridged to Chelate Isomers (M = Mo) and Reversible Carbon-Hydrogen Bond Oxidative Addition (M = W)
Malcolm H. Chisholm, Jui-Hsien Huang, John C. Huffman, and Ivan P. Parkin
pp 1642 - 1651; DOI:
10.1021/ic961429n
PDF
Metal-Purine Interactions: Homo- and Heterodinuclear Platinum(II) and/or Palladium(II) Complexes of 8-Thiotheophylline. Crystal Structures of [Pt(-TT)(dppm)]2·2DMSO and [(dppm)Pt(-TT)2Pd(dppm)]·7H2O
Enrique Colacio, Rafael Cuesta, Mustapha Ghazi, M. Angeles Huertas, Jose M. Moreno, and Antonio Navarrete
pp 1652 - 1656; DOI:
10.1021/ic961288p
PDF
Solution and Solid State Properties of [N-(2-Hydroxyethyl)iminodiacetato]vanadium(IV), -(V), and -(IV/V) Complexes
Mohammad Mahroof-Tahir, Anastasios D. Keramidas, Ron B. Goldfarb, Oren P. Anderson, Mary M. Miller, and Debbie C. Crans
pp 1657 - 1668; DOI:
10.1021/ic9610243
PDF
Formation and X-ray Structures of Eight- and Sixteen-Membered Rings (ArC)nN2n(SPh)n [n = 2, Ar = 4-XC6H4 (X = Br, CF3); n = 4, Ar = 4-BrC6H4] and the Electronic Structures of (HC)2N4(SH)2 and (HC)2N4(SH)22-
Tristram Chivers, Masood Parvez, Ignacio Vargas-Baca, Tom Ziegler, and Peter Zoricak
pp 1669 - 1675; DOI:
10.1021/ic961157o
PDF
Binding of meso-Tetrakis(N-methylpyridinium-4-yl)porphyrin to Double Helical RNA and DNA·RNA Hybrids
Tadayuki Uno, Kanya Hamasaki, Masahiko Tanigawa, and Saburo Shimabayashi
pp 1676 - 1683; DOI:
10.1021/ic960824a
PDF
Electronic Structure of the Lowest Excited States of Cr(CO)4(2,2'-bipyridine): A CASSCF/CASPT2 Analysis
Dominique Guillaumont, Chantal Daniel, and Antonín Vlek, Jr.
pp 1684 - 1688; DOI:
10.1021/ic960872v
PDF
Synthesis and Characterization of Cs5Sb8S18(HCO3): A New Layered Phase Containing Interstitial Cations and Anions
George L. Schimek and Joseph W. Kolis
pp 1689 - 1693; DOI:
10.1021/ic960359h
PDF
p-tert-Butylcalix[4]arene Tetrakis(diphenylphosphinite) and Tetrakis(dimethylphosphinite) Acting as Phosphorus Binding Surfaces for Monometallic and Homo- and Heterodimetallic Fragments
Matthias Stolmàr, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli
pp 1694 - 1701; DOI:
10.1021/ic9615382
PDF
Sulfur-Bridged Cubane-Type Molybdenum-Gallium Clusters with Mo3GaS4n+ (n = 5, 6) Cores. X-ray Structures of [Mo3GaS4(H2O)12](CH3C6H4SO3)5·14H2O and [Mo3GaS4(H2O)12](CH3C6H4SO3)6·17H2O
Takashi Shibahara, Syoji Kobayashi, Naoki Tsuji, Genta Sakane, and Minoru Fukuhara
pp 1702 - 1706; DOI:
10.1021/ic960897u
PDF
Tetrabutylammonium Tetracyanocobaltate(II) Dioxygen Carriers
Ingrid K. Meier, Ronald M. Pearlstein, Dorai Ramprasad, and Guido P. Pez
pp 1707 - 1714; DOI:
10.1021/ic9608004
PDF
Hydrolysis of Double-Stranded and Single-Stranded RNA in Hairpin Structures by the Copper(II) Macrocycle Cu([9]aneN3)Cl2
Eric L. Hegg, Kim A. Deal, Laura L. Kiessling, and Judith N. Burstyn
pp 1715 - 1718; DOI:
10.1021/ic960955b
PDF
A Route to exo-Heterodisubstituted and Monosubstituted o-Carborane Derivatives
F. Teixidor, C. Viñas, R. Benakki, R. Kivekäs, and R. Sillanpää
pp 1719 - 1723; DOI:
10.1021/ic9609719
PDF
Synthesis and Crystal Structure of (-Malonanilide-O,O')bis[bis(dibenzoylmethanato)dioxouranium(VI)]: A New Coordination Mode of the Malonamide Ligand
Shanmugaperumal Kannan and and George Ferguson
pp 1724 - 1725; DOI:
10.1021/ic960626j
PDF
Synthesis and Structure of the Thallium(I) Salt of the Tetrakis{3,5-bis(trifluoromethyl)phenyl}borate Anion
Russell P. Hughes and, Danielle C. Lindner, Arnold L. Rheingold, and Glenn P. A. Yap
pp 1726 - 1727; DOI:
10.1021/ic961164c
PDF
Silylphosphide Reagents in Synthetic Routes to Cyclophosphines
Paul F. Brandt, David M. Schubert, and Arlan D. Norman
pp 1728 - 1731; DOI:
10.1021/ic961350i
PDF
Hydroxylation of an Aliphatic C-H Bond in an Imidazole-Ligated (-2:2-Peroxo)dicopper(II) Complex
William E. Allen and Thomas N. Sorrell
pp 1732 - 1734; DOI:
10.1021/ic961187r
PDF

Issue 9


A Novel 3D Three-Connected Cubic Network Containing [Ag6(hmt)6]6+ Hexagonal Units (hmt = Hexamethylenetetramine)
Lucia Carlucci, Gianfranco Ciani, Davide M. Proserpio, and Angelo Sironi
pp 1736 - 1737; DOI:
10.1021/ic970043p
PDF
Tantalum Complexes Bearing 1-, 2-, and "Slipped" 2-Pyrazolato Ligands
Ilia A. Guzei, Glenn P. A. Yap, and Charles H. Winter
pp 1738 - 1739; DOI:
10.1021/ic970185j
PDF
Assembly of Mixed-Metal Cages Using Polyimido Antimony(III) Anions. Syntheses and Structures of [Sb3(NCy)4(HNCy)2]K·2(toluene), [Sb2(NCy)4]2M4 (M = Cu, Ag), and [Sb(NCy)3]2Pb3 (Cy = Cyclohexyl, C6H11)
Michael A. Beswick, Natalie L. Cromhout, Christopher N. Harmer, Michael A. Paver, Paul R. Raithby, Moira-Ann Rennie, Alexander Steiner, and Dominic S. Wright
pp 1740 - 1744; DOI:
10.1021/ic961108b
PDF
Preparation and Characterization of a Diamagnetic and Dinuclear Titanium(III) Formamidinate Complex. Evidence for the Existence of a Ti-Ti Bond?
Shoukang Hao, Khalil Feghali, and Sandro Gambarotta
pp 1745 - 1748; DOI:
10.1021/ic961358s
PDF
The True Structure and Metal-Metal-Bonded Framework of LiMoIIIO2 Determined from Total Neutron Scattering
Simon J. Hibble, Ian D. Fawcett, and Alex C. Hannon
pp 1749 - 1753; DOI:
10.1021/ic961325c
PDF
A Density Functional Study of Metal-Ligand Bonding in [(PR3)2M]+ and [PR3MCl] (M = Ag, Au; R = H, Me) Complexes
Graham A. Bowmaker, Hubert Schmidbaur, Sven Krüger, and Notker Rösch
pp 1754 - 1757; DOI:
10.1021/ic9609766
PDF
1,2-Disilanediyl Bis(triflate), F3CSO3-SiH2SiH2-O3SCF3, as the Key Intermediate for a Facile Preparation of Open-Chain and Cyclic 1,1- and 1,2-Diaminodisilanes
Marcus Söldner, Annette Schier, and Hubert Schmidbaur
pp 1758 - 1763; DOI:
10.1021/ic961416+
PDF
Diastereomeric Control in the Formation of Carbon-Cobalt Bonds in Organocobalt Corrinoids: Reactions of Cobalt(II) Corrinoids with Organic Hydroperoxides
Kenneth L. Brown, Daqing Zhao, Shifa Cheng, and Xiang Zou
pp 1764 - 1771; DOI:
10.1021/ic9614273
PDF
Side Chain Entropy and the Activation of Organocobalamins for Carbon-Cobalt Bond Homolysis: Synthesis, Characterization, and Thermolysis of the Neopentyl Derivative of a Unique Cobalamin Analog Lacking a c Side Chain
Kenneth L. Brown, Shifa Cheng, Jeffrey D. Zubkowski, and Edward J. Valente
pp 1772 - 1781; DOI:
10.1021/ic961378u
PDF
Synthesis and Structural Characterization of Five-, Six-, and Seven-Coordinate Manganese(II) Complexes of the Tripodal Ligand Tris(2-benzimidazolylmethyl)amine
Myoung Soo Lah and and Hyungphil Chun
pp 1782 - 1785; DOI:
10.1021/ic960923o
PDF
Synthesis and Coordination Chemistry of the First Water-Soluble Dithio-Bis(phosphine) Ligands [(HOH2C)2P(CH2)2S-X-S(CH2)2P(CH2OH)2] (X = (CH2)3 or C6H4). X-ray Crystal Structure of [Pd(HOH2C)2P(CH2)2S(CH2)3S(CH2)2P(CH2OH)2](Cl)2
C. Jeffrey Smith, V. Sreenivasa Reddy, Srinivasa R. Karra, Kattesh V. Katti, and Leonard J. Barbour
pp 1786 - 1791; DOI:
10.1021/ic961319g
PDF
Synthesis and Structure of a Novel Lewis Acid-Base Adduct, (H3C)3SiN3·GaCl3, en Route to Cl2GaN3 and Its Derivatives: Inorganic Precursors to Heteroepitaxial GaN
J. Kouvetakis, Jeff McMurran, P. Matsunaga, M. O'Keeffe, and John L. Hubbard
pp 1792 - 1797; DOI:
10.1021/ic961273r
PDF
Molybdenum(VI) Peroxo -Amino Acid Complexes: Synthesis, Spectra, and Properties of MoO(O2)2(-aa)(H2O) for -aa = Glycine, Alanine, Proline, Valine, Leucine, Serine, Asparagine, Glutamine, and Glutamic Acid. X-ray Crystal Structures of the Glycine, Alanine, and Proline Compounds
Cirila Djordjevic, Nikola Vuletic, Bradley A. Jacobs, Myunghi Lee-Renslo, and Ekk Sinn
pp 1798 - 1805; DOI:
10.1021/ic9610997
PDF
cis-Dichloro(,-diamino carboxylate ethyl ester)palladium(II) as Palladium(II) versus Platinum(II) Model Anticancer Drugs: Synthesis, Solution Equilibria of Their Aqua, Hydroxo, and/or Chloro Species, and in Vitro/in Vivo DNA-Binding Properties
M. L. González, J. M. Tercero, A. Matilla, J. Niclós-Gutiérrez, M. T. Fernández, M. C. López, C. Alonso, and S. González
pp 1806 - 1812; DOI:
10.1021/ic961226z
PDF
Synthesis and Crystal Structure Determination of Bifunctional Phosphine-Linked Triplatinum Double-Cluster Complexes
Daniel Imhof, Urs Burckhardt, Klaus-Hermann Dahmen, Felix Joho, and Reinhard Nesper
pp 1813 - 1820; DOI:
10.1021/ic960846x
PDF
Iron-Sulfur Clusters with SiMe2-Bridged Cyclopentadienyl Ligands: [Me2Si(5-C5H4)2]2Fe5S12, [Me2Si(5-C5H4)2]2Fe4S6, and [Me2Si(5-C5H4)2]2Fe4S6(CO)
Wouter van den Berg, Lianne Boot, Helma Joosen, Johannes G. M. van der Linden, Wil P. Bosman, Jan M. M. Smits, René de Gelder, Paul T. Beurskens, Jürgen Heck, and Anton W. Gal
pp 1821 - 1828; DOI:
10.1021/ic960900+
PDF
The [Mn2(2-OHsalpn)2]2-,-,0,+ System: Synthesis, Structure, Spectroscopy, and Magnetism of the First Structurally Characterized Dinuclear Manganese Series Containing Four Distinct Oxidation States
Andrew Gelasco, Martin L. Kirk, Jeff W. Kampf, and Vincent L. Pecoraro
pp 1829 - 1837; DOI:
10.1021/ic970140i
PDF
Copper K-Edge X-ray Absorption Studies of La2-xKxCuO4 Superconductors, Ba4NaCuO4(CO3)2, and NdCu2O4
Sarah L. Stoll, Robert M. Bornick, Angelica M. Stacy, and Paul D. VerNooy
pp 1838 - 1841; DOI:
10.1021/ic960424n
PDF
Transition-Metal Derivatives of a Functionalized Cyclopentadienyl Ligand. 15.> Synthesis and Structures of Amino Cyclopentadienyl Derivatives of Rhodium(I) and Rhodium(III) Including Water-Soluble Compounds
Athanassios I. Philippopoulos and, Nick Hadjiliadis, Claire E. Hart, Bruno Donnadieu, Patrick C. Mc Gowan, and René Poilblanc
pp 1842 - 1849; DOI:
10.1021/ic960395g
PDF
Stereoisomerism and Equilibrium Properties of Oxygen-Carrying Cobalt(II) Complexes of Histamine and Its Derivatives: A New Approach to an Old System
Tamás Gajda, Bernard Henry, and Jean-Jacques Delpuech
pp 1850 - 1859; DOI:
10.1021/ic960832r
PDF
Singlet Oxygen and the Production of Sulfur Oxygenates of Nickel(II) and Palladium(II) Thiolates
Craig A. Grapperhaus, Michael J. Maguire, Thawatchai Tuntulani, and Marcetta Y. Darensbourg
pp 1860 - 1866; DOI:
10.1021/ic970050d
PDF
(Trimethylsilyl)phosphine as a Versatile Reagent for Syntheses of New 4-Sila- and 4-Phosphaphosphorinanes
Michael L. J. Hackney, David M. Schubert, Paul F. Brandt, R. C. Haltiwanger, and Arlan D. Norman
pp 1867 - 1872; DOI:
10.1021/ic961329h
PDF
1H and 31P NMR and EPR of Pentaammineruthenium(III) Complexes of Endocyclically Coordinated Nucleotides, Nucleosides, and Related Heterocyclic Bases. Autoxidation of [(GuoN7)(NH3)5RuIII] (Guo = Guanosine). Crystal Structure of [7MeGuaN9(NH3)5Ru]Cl3·3H2O
V. M. Rodriguez-Bailey, K. J. LaChance-Galang, P. E. Doan, and M. J. Clarke
pp 1873 - 1883; DOI:
10.1021/ic9609416
PDF
Kinetics of Formation of Ca2+ Complexes of Acyclic and Macrocyclic Poly(amino carboxylate) Ligands: Bimolecular Rate Constants for the Fully-Deprotonated Ligands Reveal the Effect of Macrocyclic Ligand Constraints on the Rate-Determining Conversions of Rapidly-Formed Intermediates to the Final Complexes
Shu Ling Wu, Kenneth A. Johnson, and William DeW. Horrocks, Jr.
pp 1884 - 1889; DOI:
10.1021/ic960649y
PDF
Synthesis and Spectroscopic Characterization of Pyrrolidyl and Piperidyl Dithioformate Derivatives of Dimethyltellurium(IV) Compounds. Crystal Structures of Me2Te[S2CN(CH2)3CH2]2, Me2Te[S2CN(CH2)4CH2]2, Me2Te{[S2CN(CH2)3CH2][S2CN(CH2)4CH2]}, Me2TeCl[S2CN(CH2)3CH2], Me2TeBr[S2CN(CH2)3CH2], Me2TeI[S2CN(CH2)3CH2], Me2TeCl[S2CN(CH2)4CH2], and Me2TeI[S2CN(CH2)4CH2]
John E. Drake and Jincai Yang
pp 1890 - 1903; DOI:
10.1021/ic9608455
PDF
Thermochemistry of Oxo Transfer from Coordinated Nitrite in the Dinitro(5,10,15,20-tetrakis(o-pivalamidophenyl)porphinato)iron(III) Anion
Melanie Frangione, Jennifer Port, Murtuza Baldiwala, Andrew Judd, John Galley, Magrey DeVega, Kara Linna, Leigh Caron, Elizabeth Anderson, and John A. Goodwin
pp 1904 - 1911; DOI:
10.1021/ic9608915
PDF
Reactions of {[Pd(-SC6F5)(-dppm)Pd](-SC6F5)}4·2O(C2H5)2. Crystal Structures of the Complexes [(Ph3P)Pd(-SC6F5)(-dppm)Pd(SC6F5)]·1.4CH2Cl2 and [(Ph3P)Pd(-SC6F5)(-dppm)Pd(PPh3)]SO3CF3·2CH2Cl2 and ab Initio MO Calculations on the Model Systems [(H3P)Pd(-H2PCH2PH2)(-SH)Pd(PH3)]+ and [(H3P)Pd(-H2PCH2PH2)Pd(PH3)]2+
Rafael Usón, Juan Forniés, Javier Fernández Sanz, Miguel A. Usón, Isabel Usón, and Santiago Herrero
pp 1912 - 1922; DOI:
10.1021/ic960818e
PDF
Optical Absorption Spectroscopy of the Tetranuclear Compound [Mn{Cu(oxpn)}3](ClO4)2·2H2O (oxpn = N,N'-Bis(3-aminopropyl)oxamide): Complementarity with Magnetic Properties
Olivier Cador, Corine Mathonière, and Olivier Kahn
pp 1923 - 1928; DOI:
10.1021/ic960857q
PDF
Theoretical Evidence for Two New Intermediate Xenon Species: Xenon Azide Fluoride, FXe(N3), and Xenon Isocyanate Fluoride, FXe(NCO)
Axel Schulz and Thomas M. Klapötke
pp 1929 - 1933; DOI:
10.1021/ic9613671
PDF
Structure and Bond Nature of the UF5 Monomer
J. Onoe, H. Nakamatsu, T. Mukoyama, R. Sekine, H. Adachi, and K. Takeuchi
pp 1934 - 1938; DOI:
10.1021/ic961237s
PDF
Versatile Complexation Ability of Very Large Phosphino-Terminated Dendrimers
Michaël Slany, Manuel Bardaji, Anne-Marie Caminade, Bruno Chaudret, and Jean Pierre Majoral
pp 1939 - 1945; DOI:
10.1021/ic961258m
PDF
Absorption and Luminescence Spectroscopy of MnO42--Doped Crystals of BaSO4
Thomas C. Brunold and Hans U. Güdel
pp 1946 - 1954; DOI:
10.1021/ic9611711
PDF
Substitution Reactions of Aluminum Organoamide Complexes [Al(-NR2)nCl3-n]2 (R = Et, iPr; n 3) with LiNR'R'' (R' = R'' = iPr, Et; R' = H, R'' = iPr): Crystal Structure of [Al(-NEt2)(NiPr2)X]2 (X = Cl, H) and AlCl3(NiPrH2)2{Al(NH3)(NH2)[Al(NiPrH)(NiPr)Cl]2}2
Chung-Cheng Chang, Mung-Dar Li, Michael Y. Chiang, Shie-Ming Peng, Yu Wang, and Gene-Hsiang Lee
pp 1955 - 1960; DOI:
10.1021/ic950539b
PDF
Chiral and Achiral Diphosphine Complexes of Ruthenium(II) Incorporating Labile Nitrile Ligands: Synthesis and Solution Chemistry of Mono- and Dinuclear Derivatives of Ru2Cl4(PP)2 (PP = Chelating Diphosphine)
Deryn E. Fogg and Brian R. James
pp 1961 - 1966; DOI:
10.1021/ic960735y
PDF
Synthesis and Cyclic Voltammetry Studies of Copper Complexes of Bromo- and Alkoxyphenyl-Substituted Derivatives of Tris(2-pyridylmethyl)amine: Influence of Cation-Alkoxy Interactions on Copper Redox Potentials
Chang-Lin Chuang, Osvaldo dos Santos, Xiaodong Xu, and James W. Canary
pp 1967 - 1972; DOI:
10.1021/ic960942y
PDF
Formation of the Novel Six-Coordinate Atrane Cation in [FMeSn(HMeNCH2CH2)2N(CH2CH2NMe)]BF4
Winfried Plass, Jiri Pinkas, and John G. Verkade
pp 1973 - 1978; DOI:
10.1021/ic961052l
PDF
Synthesis and X-ray Crystal Structure of (tmp)2Al-Fe(cp)(CO)2: An Alanyl-Containing Iron Complex with a Tricoordinated Aluminum Atom
B. N. Anand, Ingo Krossing, and Heinrich Nöth
pp 1979 - 1981; DOI:
10.1021/ic970110f
PDF
Mononuclear Niobium Imido and Oxo Complexes Supported by N,N'-Bis(trimethylsilyl)benzamidinate Ligands. X-ray Structures of [Nb(NBut){PhC(NSiMe3)2}Cl2(py)] and [Nb(O){(4-C6H4Me)C(NSiMe3)2}2Cl]
Peter J. Stewart, Alexander J. Blake, and Philip Mountford
pp 1982 - 1986; DOI:
10.1021/ic961391e
PDF

Issue 10


A Supramolecular Approach to the Crystallization of Polynuclear Aqua Ions: Structure and Magnetism of an 18-Crown-6 Adduct of Bis(-hydroxo)octaaquadichromium(III) Mesitylene-2-sulfonate Trihydrate
Alexander Drljaca, David C. R. Hockless, Boujemaa Moubaraki, Keith S. Murray, and Leone Spiccia
pp 1988 - 1989; DOI:
10.1021/ic9614125
PDF
Synthesis and X-ray Crystal Structure Determination of the First Potassium Salt of a Primary Phosphane: [KP(H)Mes*]x
Gerd W. Rabe, Glenn P. A. Yap, and Arnold L. Rheingold
pp 1990 - 1991; DOI:
10.1021/ic961420l
PDF
Synthesis and Characterization of Isostructural Metalloporphyrin Chalconitrosyl Complexes Ru(TTP)(NE)Cl (E = O, S) and a Remarkable Thionitrosyl/Nitrite Nitrosyl/Thiazate Transformation
D. Scott Bohle, Chen-Hsiung Hung, Annie K. Powell, Bryan D. Smith, and Sigrid Wocadlo
pp 1992 - 1993; DOI:
10.1021/ic9614576
PDF
Properties of Trifluoroacetyl Peroxynitrate, CF3C(O)OONO2
Rodion Kopitzky, Michaela Beuleke, Gert Balzer, and Helge Willner
pp 1994 - 1997; DOI:
10.1021/ic9612109
PDF
A Loose Cage for Transition Metals
Giancarlo De Santis, Luigi Fabbrizzi, Angelo Perotti, Nicola Sardone, and Angelo Taglietti
pp 1998 - 2003; DOI:
10.1021/ic960933p
PDF
Complexes of the Trioxodinitrate Anion: Synthesis and Characterization of [ZnII(bipy)(H2O)(N2O3)] and [CoII(bipy)2(N2O3)]
Carmen Chuy, Larry R. Falvello, Eduardo Libby, Juan Cristián Santa-María, and Milagros Tomás
pp 2004 - 2009; DOI:
10.1021/ic961194f
PDF
Reactions of Transition Metal Carbonyl Dianions with (Organo)gallium Chlorides: Anionic Gallium Complexes of Chromium, Iron, and Manganese. Structure of [PPN]2{[(CO)4Fe-Ga(CH3)-Fe(CO)4]}
Roland A. Fischer, Markus M. Schulte, Eberhardt Herdtweck, and Mike R. Mattner
pp 2010 - 2017; DOI:
10.1021/ic9606183
PDF
Oligomerization of the PH3CuCCCuPH3 Acetylide toward the Formation of (PH3CuC)n (n = 4, 6, 8) Metal Carbides: A Theoretical Study Based on Density Functional Theory
Paola Belanzoni, Simona Fantacci, Nazzareno Re, Marzio Rosi, Antonio Sgamellotti, and Carlo Floriani
pp 2018 - 2022; DOI:
10.1021/ic960813h
PDF
Molecular Dynamics within Diorganotin Systems: Solution and Solid State Studies of New Mixed Distannoxane Dimers [tBu2(Cl)SnOSn(Cl)R2]2
Dainis Dakternieks, Klaus Jurkschat, Serena van Dreumel, and Edward R. T. Tiekink
pp 2023 - 2029; DOI:
10.1021/ic9611608
PDF
Synthesis, Magnetism, and X-ray Molecular Structure of the Mixed-Valence Vanadium(IV/V)-Oxygen Cluster [VO4(V18O45)]9-
Lorenza Suber, Mario Bonamico, and Vincenzo Fares
pp 2030 - 2033; DOI:
10.1021/ic960706n
PDF
Base Effects on the Formation of Four- and Five-Coordinate Cationic Aluminum Complexes
Jolin A. Jegier and David A. Atwood
pp 2034 - 2039; DOI:
10.1021/ic961455l
PDF
Beryllium Chelation by Dicarboxylic Acids in Aqueous Solution
Michael Schmidt, Andreas Bauer, and Hubert Schmidbaur
pp 2040 - 2043; DOI:
10.1021/ic961410k
PDF
Cyclic Aminophosphites and -phosphoranes Possessing Six- and Higher-Membered Rings: A Comparative Study of Structure and Reactivity
Musa A. Said, Melanie Pülm, R. Herbst-Irmer, and K. C. Kumara Swamy
pp 2044 - 2051; DOI:
10.1021/ic9611958
PDF
Spectroscopic, Magnetic, and Electrochemical Studies of a Dimeric N-Substituted-Sulfanilamide Copper(II) Complex. X-ray and Molecular Structure of the Cu2(sulfathiazolato)4 Complex
Javier Casanova, Gloria Alzuet, Julio Latorre, and Joaquín Borrás
pp 2052 - 2058; DOI:
10.1021/ic960968p
PDF
Conformational and Coordination Equilibria on DOTA Complexes of Lanthanide Metal Ions in Aqueous Solution Studied by 1H-NMR Spectroscopy
Silvio Aime, Mauro Botta, Mauro Fasano, M. Paula M. Marques, Carlos F. G. C. Geraldes, Dirk Pubanz, and André E. Merbach
pp 2059 - 2068; DOI:
10.1021/ic961364o
PDF
Hydrogen Atom Abstraction by Permanganate: Oxidations of Arylalkanes in Organic Solvents
Kimberly A. Gardner, Linda L. Kuehnert, and James M. Mayer
pp 2069 - 2078; DOI:
10.1021/ic961297y
PDF
Methyl Transfer to Mercury Thiolates: Effects of Coordination Number and Ligand Dissociation
Jonathan J. Wilker, Karen E. Wetterhahn, and Stephen J. Lippard
pp 2079 - 2083; DOI:
10.1021/ic961178i
PDF
Ruthenium(VI) Doped into Single Crystals with the BaSO4 and -K2SO4 Structures: Optical Absorption Spectra of RuO42-
Thomas C. Brunold and Hans U. Güdel
pp 2084 - 2091; DOI:
10.1021/ic961314j
PDF
Heterometallic Osmium-Mercury Chain Structures Linking Two {Os3(CO)10(-X)} Subunits (X = Cl, Br, I): Syntheses and Molecular Structures of [{Os3(CO)10(-X)}2(4-Hg)] (X = Cl, I), [{Os3(CO)10(-Cl)}2{-HgOs(CO)4}2], and cis-[Os(CO)4{(-Hg)Os3(CO)10(-Cl)}2]
Yat-Kun Au and Wing-Tak Wong
pp 2092 - 2096; DOI:
10.1021/ic961092p
PDF
Organometallic Selenolates. 5.1 Synthesis and Complexing Properties of 2-Propene- and 2-Methyl-2-propeneselenolato Molybdenum and Tungsten Compounds. Crystal Structures of cp(CO)3WSeCH2C(CH3)=CH2, [cp(CO)2MoSeCH2C(CH3)=CH2]2, [cp(CO)3Mo(-SeCH2C(CH3)=CH2)W(CO)5], [cp(CO)3Mo(-SeCH2C(CH3)=CH2)Mo(CO)5], and [cp(CO)3Mo(-SeCH2CH=CH2)Mo(CO)5]
Peter G. Jones, Jörg Laube, and Carsten Thöne
pp 2097 - 2102; DOI:
10.1021/ic961199c
PDF
Ferrocene-Based Tris(1-pyrazolyl)borates: A New Approach to Heterooligometallic Complexes and Organometallic Polymers Containing Transition Metal Atoms in the Backbone
Fabrizia Fabrizi de Biani, Frieder Jäkle, Michael Spiegler, Matthias Wagner, and Piero Zanello
pp 2103 - 2111; DOI:
10.1021/ic9612360
PDF
Neutral Ferrocenoyl Receptors for the Selective Recognition and Sensing of Anionic Guests
Paul D. Beer, Andrew R. Graydon, Anna O. M. Johnson, and David K. Smith
pp 2112 - 2118; DOI:
10.1021/ic961401b
PDF
The Strong Acidity and the Process for Deprotonation of (6-Toluene)Fe(H)2(SiCl3)2
Zhengui Yao and Kenneth J. Klabunde
pp 2119 - 2123; DOI:
10.1021/ic961073f
PDF
Synthesis, Photophysics, and Electrochemistry of Ruthenium(II) Polypyridine Complexes with Crown Ether Pendants
Vivian Wing-Wah Yam, Vicky Wing-Man Lee, Fu Ke, and Kam-Wing Michael Siu
pp 2124 - 2129; DOI:
10.1021/ic961400j
PDF
Pyrazolylborate-Zinc Complexes of RNA Precursors and Analogues Thereof
Michael Ruf, Karl Weis, and Heinrich Vahrenkamp
pp 2130 - 2137; DOI:
10.1021/ic961379m
PDF
Asymmetric Synthesis of P-Chiral Diphosphines. Steric Effects on the Palladium-Complex-Promoted Asymmetric Diels-Alder Reaction between a Dimethylphenylphosphole and (E/Z)-Methyl-Substituted Diphenylvinylphosphines
Beng-Hwee Aw, T. S. Andy Hor, S. Selvaratnam, K. F. Mok, Andrew J. P. White, David J. Williams, Nicholas H. Rees, William McFarlane, and Pak-Hing Leung
pp 2138 - 2146; DOI:
10.1021/ic961479s
PDF
Trifluoromethyl Hypobromite, CF3OBr
Rolf Minkwitz, Raimund Bröchler, Andreas Kornath, Ralf Ludwig, and Frank Rittner
pp 2147 - 2150; DOI:
10.1021/ic961113f
PDF
Carbene-Pnictinidene Adducts
Anthony J. Arduengo, III, Joseph C. Calabrese, Alan H. Cowley, H. V. Rasika Dias, Jens R. Goerlich, William J. Marshall, and Bernhard Riegel
pp 2151 - 2158; DOI:
10.1021/ic970174q
PDF
Polyoxoanion Coordination Chemistry: Synthesis and Characterization of the Heterometallic, Hexanuclear Clusters [{Zn(bipy)2}2V4O12], [{Zn(phen)2}2V4O12]·H2O, and [{Ni(bipy)2}2Mo4O14]
Yiping Zhang, Pamela J. Zapf, Linda M. Meyer, Robert C. Haushalter, and Jon Zubieta
pp 2159 - 2165; DOI:
10.1021/ic961045x
PDF
Tungstorhenate Heteropolyanions. 2. Synthesis and Characterization of Enneatungstorhenates(V), -(VI), and -(VII)
Fernando Ortéga, Michael T. Pope, and Howard T. Evans, Jr.
pp 2166 - 2169; DOI:
10.1021/ic961142q
PDF
Theoretical and Experimental Studies of Six-Membered Selenium-Sulfur Nitrides SexS4-xN2 (x = 0-4). Preparation of S4N2 and SeS3N2 by the Reaction of Bis[bis(trimethylsilyl)amino]sulfane with Chalcogen Chlorides
Arto Maaninen, Jari Siivari, Reijo J. Suontamo, Jari Konu, Risto S. Laitinen, and Tristram Chivers
pp 2170 - 2177; DOI:
10.1021/ic9613570
PDF
Use of Manganese(II)-Schiff Base Complexes for Carrying Polar Organometallics and Inorganic Ion Pairs
Emma Gallo, Euro Solari, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli
pp 2178 - 2186; DOI:
10.1021/ic9614069
PDF
Hydrothermal Synthesis, Structure, and Magnetic Properties of a Novel Monodimensional Iron Phosphate: [FeF(HPO4)2,N2C3H12,(H2O)x] (x 0.20) (ULM-14)
Myriam Cavellec, Didier Riou, Jean-Marc Grenèche, and Gérard Férey
pp 2187 - 2190; DOI:
10.1021/ic960888l
PDF
Preparation and Characterization of a Diamagnetic Sulfido-Bridged Divanadium Amide Complex
Mark Moore, Khalil Feghali, and Sandro Gambarotta
pp 2191 - 2194; DOI:
10.1021/ic961471i
PDF
Synthesis, Reactivity, and Structure of [H13O6][PtCl5(H4O2)]·2(18-cr-6): A Crown Ether Complex of a Pentachloroaquaplatinic Acid with an [H13O6]+ Cation in a Cage of Three Crown Ether Molecules
Dirk Steinborn, Olaf Gravenhorst, Helmut Hartung, and Ute Baumeister
pp 2195 - 2199; DOI:
10.1021/ic9614780
PDF
Competing Magnetic Exchange Interactions in Tetranuclear d1 Systems: Synthesis, Structure, and Magnetochemistry of a Neutral Vanadium(IV) Complex with a {(VO)4(3-OR)2(2-OR)4}2+ Core
Winfried Plass
pp 2200 - 2205; DOI:
10.1021/ic9613669
PDF
Reduction of Aqueous Na2WO4 by NaBH4 at Ambient Temperatures To Obtain Lower Valent Tungsten Oxides
C. Tsang, S. Y. Lai, and A. Manthiram
pp 2206 - 2210; DOI:
10.1021/ic9610039
PDF
Rhodium(III) and Iridium(III) Solvates of the Form [(5-C5Me5)M(S)3]2+ as Models for the Reactivity of Half-Sandwich Compounds
Antonio Cusanelli, Lynda Nicula-Dadci, Urban Frey, and André E. Merbach
pp 2211 - 2217; DOI:
10.1021/ic961380l
PDF
Synthesis, Characterization, and Reactivity of Group 12 Metal Thiocarboxylates, M(SOCR)2Lut2 [M = Cd, Zn; R = CH3, C(CH3)3; Lut = 3,5-Dimethylpyridine (Lutidine)]
May D. Nyman, Mark J. Hampden-Smith, and Eileen N. Duesler
pp 2218 - 2224; DOI:
10.1021/ic960784a
PDF
First Example of Linear Strings of Equidistant Gold Atoms in Crystals of [(2,4,6-Me3C6H2NC)2Au] [Au(GeCl3)2]
Andreas Bauer, Wolfgang Schneider, and Hubert Schmidbaur
pp 2225 - 2226; DOI:
10.1021/ic9701468
PDF
Synthesis and Molecular Structures of the Magnesium and Aluminum Adducts of a Niobium-Oxo Complex. X-ray Crystal Structures of [{NbOCl4(THF)}2Mg(THF)4] and [{NbOCl4(THF)}2AlCl(THF)3]
Piotr Sobota, Józef Utko, and Sawomir Szafert
pp 2227 - 2229; DOI:
10.1021/ic9610804
PDF
Bimetallic Reactivity. Oxo Transfer Reactions with a Heterobimetallic Complex of Iron(II) and Vanadium(III)
David G. McCollum, Glenn P. A. Yap, Louise Liable-Sands, Arnold L. Rheingold, and B. Bosnich
pp 2230 - 2235; DOI:
10.1021/ic9609923
PDF
A New Charge Transfer Complex Involving ReH5(PPh3)3
Usama M. Rabie, Ben P. Patel, Robert H. Crabtree, and M. R. Mahmoud
pp 2236 - 2238; DOI:
10.1021/ic961361b
PDF

Issue 11


Properties of Ion Clusters: Interactions of [Ru(NH3)5H2O]3+ and [Ru(NH3)6]3+ with [Ru(CN)6]4- and [Fe(CN)6]4-
Vassiliki G. Poulopoulou and Henry Taube
pp 2240 - 2241; DOI:
10.1021/ic9614428
PDF
Activation of Thiourea Bound through Sulfur to Pentaammineruthenium(III): Structure and Reactivity
David P. Fairlie, Wasantha A. Wickramasinghe, Karl A. Byriel, and Henry Taube
pp 2242 - 2243; DOI:
10.1021/ic9611397
PDF
Magnetic Excitations in Tetrameric Clusters of Polyoxometalates Observed by Inelastic Neutron Scattering. Evidence for Anisotropic Exchange Interactions in Cobalt(II) Clusters
Juan M. Clemente, Hanspeter Andres, Michael Aebersold, Juan J. Borrás-Almenar, Eugenio Coronado, Hans U. Güdel, Herma Büttner, and Gordon Kearly
pp 2244 - 2245; DOI:
10.1021/ic9701672
PDF
Chlorination of Icosahedral Carborane Anions. X-ray Crystal Structure of [Me3NH][CH3-1-CB11Cl11]
Zuowei Xie, Chi-Wing Tsang, Feng Xue, and Thomas C. W. Mak
pp 2246 - 2247; DOI:
10.1021/ic9614935
PDF
Dicesium trans-Tetraaquadichlorochromium(III) Chloride: Redetermination of the Crystal Structure and Infrared Study of the Water Spectrum
Stanley C. Nyburg, Bojan optrajanov, Viktor Stefov, and Vladimir M. Petruevski
pp 2248 - 2251; DOI:
10.1021/ic9607907
PDF
Acid-Base and Electrochemical Properties of the MLCT Excited States and One-Electron-Reduced Forms of Ruthenium(II) Complexes Containing 2-(2'-Pyridyl)pyrimidine and 2,2'-Bipyridine in Aqueous Solution
Fiorella Casalboni, Quinto G. Mulazzani, Catherine D. Clark, Morton Z. Hoffman, Peter L. Orizondo, Marc W. Perkovic, and D. Paul Rillema
pp 2252 - 2257; DOI:
10.1021/ic960657e
PDF
NMR Spectroscopic Characterization of Methylcobalt(III) Compounds with Classical Ligands. Crystal Structures of [Co(NH3)5(CH3)]S2O6, trans-[Co(en)2(NH3)(CH3)]S2O6 (en = 1,2-Ethanediamine), and [Co(NH3)6]-mer,trans-[Co(NO2)3(NH3)2(CH3)]2-trans- [Co(NO2)4(NH3)2]
Pauli Kofod, Pernille Harris, and Sine Larsen
pp 2258 - 2266; DOI:
10.1021/ic961264i
PDF
Mononuclear Molybdenum(IV) Complexes with Two Multiply Bonded Chalcogen Ligands in Trans Configuration and Chelating Biphosphine Ligands
F. Albert Cotton and and Günter Schmid
pp 2267 - 2278; DOI:
10.1021/ic961071v
PDF
Pentacyano(pyridine)chromate(III): Synthesis, Characterization, and Photochemistry
Pietro Riccieri, Edoardo Zinato, and Andrea Aliboni
pp 2279 - 2286; DOI:
10.1021/ic9612156
PDF
Synthesis, Characterization, and Spectroscopy of Dipyridocatecholate Complexes of Platinum
Witold Paw and Richard Eisenberg
pp 2287 - 2293; DOI:
10.1021/ic9610851
PDF
Molecular Aggregation of Annular Dinuclear Gold(I) Compounds Containing Bridging Diphosphine and Dithiolate Ligands
Shaw Shiah Tang, Chen-Pin Chang, Ivan J. B. Lin, Lin-Shu Liou, and Ju-Chun Wang
pp 2294 - 2300; DOI:
10.1021/ic9607245
PDF
Molecular-Based Magnetism in Bimetallic Two-Dimensional Oxalate-Bridged Networks. An X-ray and Neutron Diffraction Study
René Pellaux, Helmut W. Schmalle, Reto Huber, Peter Fischer, Thomas Hauss, Bachir Ouladdiaf, and Silvio Decurtins
pp 2301 - 2308; DOI:
10.1021/ic960838g
PDF
Modeling of End-On (-Peroxo)dicopper(II) Complexes
Peter Comba, Peter Hilfenhaus, and Kenneth D. Karlin
pp 2309 - 2313; DOI:
10.1021/ic961317w
PDF
Synthesis, Characterization, and Electrochemistry of Heterometallic Dendrimers
Sudhir Achar, Chad E. Immoos, Michael G. Hill, and Vincent J. Catalano
pp 2314 - 2320; DOI:
10.1021/ic961435j
PDF
Silver(I) Pyrazolates. Synthesis and X-ray and 31P-NMR Characterization of Triphenylphosphine Complexes and Their Reactivity toward Heterocumulenes
G. Attilio Ardizzoia, Girolamo La Monica, Angelo Maspero, Massimo Moret, and Norberto Masciocchi
pp 2321 - 2328; DOI:
10.1021/ic960908j
PDF
Liquid-Crystalline Mono- and Dinuclear (Perhalophenyl)gold(I) Isocyanide Complexes
Rocio Bayón, Silverio Coco, Pablo Espinet, César Fernández-Mayordomo, and José M. Martín-Alvarez
pp 2329 - 2334; DOI:
10.1021/ic960917s
PDF
A New Chelating Cyclophane and Its Complexation with Ni2+, Cu2+, and Zn2+: Spectroscopic Properties and Allosterism via Ring Contraction
Michiko B. Inoue, Felipe Medrano, Motomichi Inoue, Arnold Raitsimring, and Quintus Fernando
pp 2335 - 2340; DOI:
10.1021/ic9614374
PDF
Osmium Hydrazido and Dinitrogen Complexes
George M. Coia, Martin Devenney, Peter S. White, Thomas J. Meyer, and David A. Wink
pp 2341 - 2351; DOI:
10.1021/ic961025v
PDF
Synthesis and Magnetic Properties of Six New Trinuclear Oxo-Centered Manganese Complexes of General Formula [Mn3O(X-benzoato)6L3] (X = 2-F, 2-Cl, 2-Br, 3-F, 3-Cl, 3-Br; L = Pyridine or Water) and Crystal Structures of the 2-F, 3-Cl, and 3-Br Complexes
Joan Ribas, Belen Albela, Helen Stoeckli-Evans, and George Christou
pp 2352 - 2360; DOI:
10.1021/ic961252x
PDF
Reaction of Nitrogen Chelates with the [Rh2]4+ Core: Bis-Chelate Products and Demonstration of Reversible, Chelate-Based Reduction Processes
Charles A. Crawford, John H. Matonic, John C. Huffman, Kirsten Folting, Kim R. Dunbar, and George Christou
pp 2361 - 2371; DOI:
10.1021/ic9610288
PDF
Oxidation of Thioether Ligands in Pseudotetrahedral Cyclopentadienylruthenium Complexes: Toward a New Stereoselective Synthesis of Chiral Sulfoxides
Wolfdieter A. Schenk, Jürgen Frisch, Michael Dürr, Nicolai Burzlaff, Dietmar Stalke, Roland Fleischer, Waldemar Adam, Frank Prechtl, and Alexander K. Smerz
pp 2372 - 2378; DOI:
10.1021/ic961280f
PDF
Synthesis and Characterization of (2,4,6-Trimethylphenylimido)molybdenum Complexes. X-ray Crystal Structures of (LOEt)Mo(Nmes)2Cl, (LOEt)Mo(Nmes)Cl2, and MoCl3(Nmes)(depe) (mes = 2,4,6-Trimethylphenyl, LOEt = (-C5H5)Co{P(O)(OEt)2}3, depe = Et2PCH2CH2PEt2)
Agustín Galindo, Francisco Montilla, Antonio Pastor, Ernesto Carmona, Enrique Gutiérrez-Puebla, Angeles Monge, and Caridad Ruiz
pp 2379 - 2385; DOI:
10.1021/ic961190a
PDF
Tris(amido)tingold Complexes in Different Oxidation States. First Structural Characterization of a Sn-Au-Au-Sn Linear Chain
Bernd Findeis, Maria Contel, Lutz H. Gade, Mariano Laguna, M. Concepción Gimeno, Ian J. Scowen, and Mary McPartlin
pp 2386 - 2390; DOI:
10.1021/ic961423y
PDF
Synthesis and Characterization of New Alkoxotitanates of Yttrium, Barium, and Copper: Single Crystal X-ray Diffraction Structures of Cl2Y{Ti2(OPri)9}, {Ti(OPri)5}Ba{Ti2(OPri)9}, and ClCu{Ti2(OPri)9}
Michael Veith, Sanjay Mathur, and Volker Huch
pp 2391 - 2399; DOI:
10.1021/ic9613218
PDF
Ferrocenoyl Amino Acids: A Synthetic and Structural Study
Heinz-Bernhard Kraatz, Janusz Lusztyk, and Gary D. Enright
pp 2400 - 2405; DOI:
10.1021/ic961454t
PDF
Metallo 2,3-Disulfidothienoquinoxaline, 2,3-Disulfidothienopyridine, and 2-Sulfido-3-oxidothienoquinoxaline Complexes: Synthesis and Characterization
Sharada P. Kaiwar, John K. Hsu, Anthony Vodacek, Glenn Yap, Louise M. Liable-Sands, Arnold L. Rheingold, and Robert S. Pilato
pp 2406 - 2412; DOI:
10.1021/ic961428v
PDF
Syntheses and Structures of [(THF)nM{(NSiMe3)2PPh2}2] Complexes (M = Be, Mg, Ca, Sr, Ba; n = 0-2): Deviation of Alkaline Earth Metal Cations from the Plane of an Anionic Ligand
Roland Fleischer and Dietmar Stalke
pp 2413 - 2419; DOI:
10.1021/ic9613117
PDF
Structural and Electron Self-Exchange Rate Variations in Isomeric (Hexaamine)cobalt(III/II) Complexes
Paul V. Bernhardt, Lathe A. Jones, and Philip C. Sharpe
pp 2420 - 2425; DOI:
10.1021/ic961345e
PDF
Syntheses, Structures, and Binding Constants of Cyclic Ether and Thioether Adducts of Soluble Cadmium(II) Carboxylates. Intermediates in the Homopolymerization of Oxiranes and Thiiranes and in Carbon Dioxide Coupling Processes
Donald J. Darensbourg, Sharon A. Niezgoda, Matthew W. Holtcamp, Jennifer D. Draper, and Joseph H. Reibenspies
pp 2426 - 2432; DOI:
10.1021/ic9701120
PDF
Synthesis, Structure, Magnetic Behavior, and Mössbauer Spectroscopy of Two New Iron(II) Spin-Transition Compounds with the Ligand 4-Isopropyl-1,2,4-triazole. X-ray Structure of [Fe3(4-isopropyl-1,2,4-triazole)6(H2O)6](tosylate)6·2H2O
Jeroen J. A. Kolnaar, Gytha van Dijk, Huub Kooijman, Anthony L. Spek, Vadim G. Ksenofontov, Philipp Gütlich, Jaap G. Haasnoot, and Jan Reedijk
pp 2433 - 2440; DOI:
10.1021/ic9612010
PDF
Vanadate-Inserted Layered Double Hydroxides: A 51V NMR Investigation of the Grafting Process
M. Ménétrier, K. S. Han, L. Guerlou-Demourgues, and C. Delmas
pp 2441 - 2445; DOI:
10.1021/ic9608861
PDF
71Ga Chemical Shielding and Quadrupole Coupling Tensors of the Garnet Y3Ga5O12 from Single-Crystal 71Ga NMR
Thomas Vosegaard, Dominique Massiot, Nathalie Gautier, and Hans J. Jakobsen
pp 2446 - 2450; DOI:
10.1021/ic970012u
PDF
Study of the P4O7, P4O6S, and P4O6Se Vibrational Spectra
A. R. S. Valentim, B. Engels, S. Peyerimhoff, J. Clade, and M. Jansen
pp 2451 - 2457; DOI:
10.1021/ic961202s
PDF
A Novel Dirhodium Compound with Neutral, Bridging 9-Ethyladenine Ligands
Kemal V. Catalan, Daniel J. Mindiola, Donald L. Ward, and Kim R. Dunbar
pp 2458 - 2460; DOI:
10.1021/ic960682k
PDF
The Apparent Flexibility of Bonds in Paddlewheel-Type Compounds
F. A. Cotton and and A. Yokochi
pp 2461 - 2462; DOI:
10.1021/ic961505m
PDF
A New Dinuclear Complex Derived from Cobaloxime Units Held Together by 3-Pyridylboronic Acid Residues
R. Dreos, G. Nardin, L. Randaccio, G. Tauzher, and S. Vuano
pp 2463 - 2464; DOI:
10.1021/ic960995f
PDF
Crystal Structure and Magnetic Behavior of Copper(II) Dimethylphosphinate: A Chain Polymer Containing Triangular Trimetallic Bis(-dimethylphosphinato)copper(II) Units
Katherine W. Oliver, Steven J. Rettig, Robert C. Thompson, James Trotter, and Shihua Xia
pp 2465 - 2468; DOI:
10.1021/ic961365g
PDF
DNA Strand Scission by Dioxygen + Light-Activated Cobalt Metallopeptides
Davina C. Ananias and Eric C. Long
pp 2469 - 2471; DOI:
10.1021/ic9613927
PDF
A Novel Dimeric Zinc Complex: Bis{- [(dimercaptomethylene)propanedinitrilato-S,S']}tetrakis(4-methylpyridine)dizinc(II)-Chloroform
Ren-Gen Xiong, Jing-Lin Zuo, and Xiao-Zeng You
pp 2472 - 2474; DOI:
10.1021/ic951029k
PDF
Solvothermal Synthesis of a New Mixed-Metal Polysulfide Cluster, [Me4N]3[MoS4Cu3(S5)2]
Guo-Cong Guo, Raymund W. M. Kwok, and Thomas C. W. Mak
pp 2475 - 2477; DOI:
10.1021/ic961289h
PDF
Template Synthesis and Crystal Structure of a Novel Mononuclear Nickel(II) Complex with a Face-to-Face Bis(macrocyclic) Ligand
Shin-Geol Kang, Kiseok Ryu, Myunghyun Paik Suh, and Jong Hwa Jeong
pp 2478 - 2481; DOI:
10.1021/ic961419m
PDF
Synthesis of Cobaltabis(dicarbollyl) Complexes Incorporating Exocluster SR Substituents and the Improved Synthesis of [3,3'-Co(1-R-2-R'-1,2-C2B9H9)2]- Derivatives
Clara Viñas, Josefina Pedrajas, Josep Bertran, Francesc Teixidor, Raikko Kivekäs, and Reijo Sillanpää
pp 2482 - 2486; DOI:
10.1021/ic961002g
PDF
A Mixed-Valence Tetranuclear Copper Cluster with Localized Valencies
Petra J. van Koningsbruggen, Jaap G. Haasnoot, Huub Kooijman, Jan Reedijk, and Anthony L. Spek
pp 2487 - 2489; DOI:
10.1021/ic9611002
PDF
Supramolecular Soft-Soft Interactions of Diiodo(tert-butyl)(isopropyl)phosphonium Cations with 2- to 5-Bridging Iodide Anions. Formation of Chains, Helices, and Columnar Structures
Volkmar Stenzel, Jörg Jeske, Wolf-Walther du Mont, and Peter G. Jones
pp 2490 - 2490; DOI:
10.1021/ic970249q
PDF

Issue 12


Terminal Chalcogenido Complexes of Gallium Supported by Tris(3,5-di-tert-butylpyrazolyl)hydroborato Ligation: [TpBut2]GaE (E = Se, Te)
Matthew C. Kuchta and Gerard Parkin
pp 2492 - 2493; DOI:
10.1021/ic970208u
PDF
The Kinetics and Mechanism of the Chlorine Dioxide-Iodide Ion Reaction
István Fábián and Gilbert Gordon
pp 2494 - 2497; DOI:
10.1021/ic961279g
PDF
Spectroscopy and Electrochemistry of Cobalt(III) Schiff Base Complexes
Arnd Böttcher, Toshihiko Takeuchi, Kenneth I. Hardcastle, Thomas J. Meade, Harry B. Gray, Dory Cwikel, Moshe Kapon, and Zvi Dori
pp 2498 - 2504; DOI:
10.1021/ic961146v
PDF
Structural Flexibility of the Hydrogen-Free Acceptor Ligand Octachloro-1,10-phenanthroline in Its Complexes with d10 Metal Ions
Christoph Titze, Wolfgang Kaim, and Stanislav Zalis
pp 2505 - 2510; DOI:
10.1021/ic960837o
PDF
Syntheses, Structure, and Magnetic Behavior of Two New Nickel(II) and Cobalt(II) Dinuclear Complexes with 1,4-Dicarboxylatopyridazine. MO Calculations of the Superexchange Pathway through the Pyridazine Bridge
Albert Escuer, Ramon Vicente, Bouchaid Mernari, Abdellatif El Gueddi, and Marcel Pierrot
pp 2511 - 2516; DOI:
10.1021/ic9608859
PDF
Reactivity of Mo-Ot Terminal Bonds toward Substrates Having Simultaneous Proton- and Electron-Donor Properties: A Rudimentary Functional Model for Oxotransferase Molybdenum Enzymes
Subodh Kanti Dutta, David B. McConville, Wiley J. Youngs, and Muktimoy Chaudhury
pp 2517 - 2522; DOI:
10.1021/ic960670z
PDF
Infrared Characterization of Simple Adducts of Matrix-Isolated Cesium Fluoride and Sodium Chloride with Dihydrogen: Evidence of a Cation Interaction
Ray L. Sweany and J. Steven Ogden
pp 2523 - 2526; DOI:
10.1021/ic960672j
PDF
Structures and Dynamics of Lanthanide(III) Complexes of Sugar-Based DTPA-bis(amides) in Aqueous Solution: A Multinuclear NMR Study
Hendrik Lammers, Frédéric Maton, Dirk Pubanz, Martijn W. van Laren, Herman van Bekkum, André E. Merbach, Robert N. Muller, and Joop A. Peters
pp 2527 - 2538; DOI:
10.1021/ic961359k
PDF
BaCu10P4: A New Structure Composed of Chains of Edge-Shared Cu4 Tetrahedra
Dianna M. Young, John Charlton, Marilyn M. Olmstead, Susan M. Kauzlarich, Chi-Shen Lee, and Gordon J. Miller
pp 2539 - 2543; DOI:
10.1021/ic961347z
PDF
Ab Initio and Semiempirical Calculations of Geometry and Electronic Spectra of Ruthenium Organic Complexes and Modeling of Spectroscopic Changes upon DNA Binding
Anders Broo and and Per Lincoln
pp 2544 - 2553; DOI:
10.1021/ic961193n
PDF
Zinc and Cadmium Tropocoronand Complexes: Effect of Metal Ion Radius on Macrocyclic Ligand Twist and Fold
Linda H. Doerrer and Stephen J. Lippard
pp 2554 - 2563; DOI:
10.1021/ic970033o
PDF
Disorder and Polymorphism in Tetramethylammonium Metaperiodate
Ross I. Wagner, Robert Bau, Robert Z. Gnann, Paul F. Jones, and Karl O. Christe
pp 2564 - 2569; DOI:
10.1021/ic961514v
PDF
Synthesis of the Reagent [Na][Pt(PEt3)2(5-7-CB10H11)] and Preparation of the Platinacarborane Complexes [PtX(PEt3)2(5-7-CB10H11)] (X = H, Au(PPh3), Cu(PPh3), HgPh)
Stewart A. Batten, John C. Jeffery, Peter L. Jones, Donald F. Mullica, Martin D. Rudd, Eric L. Sappenfield, F. Gordon A. Stone, and Andreas Wolf
pp 2570 - 2577; DOI:
10.1021/ic970042x
PDF
Sulfonyl-Containing Eight-Membered Rings Varying in Ring Conformation in Oxyphosphoranes. Hexacoordination vs Pentacoordination
A. Chandrasekaran, Roberta O. Day, and Robert R. Holmes
pp 2578 - 2585; DOI:
10.1021/ic961418u
PDF
Thermodynamic, Spectroscopic, and Structural Studies of Complexation of Phenol- and Pyridine-Armed Macrocyclic Ligands with Univalent Metal Ions
Xian Xin Zhang, Andrei V. Bordunov, Xiaolan Kou, N. Kent Dalley, Reed M. Izatt, John H. Mangum, Du Li, Jerald S. Bradshaw, and Paul C. Hellier
pp 2586 - 2593; DOI:
10.1021/ic961263q
PDF
Syntheses and Single-Crystal X-ray Structures of a Series of Monosubstituted cis,cis-1,3,5-Triaminocyclohexane-Based Complexes
Leroy Cronin, Bryan Greener, Simon P. Foxon, Sarah L. Heath, and Paul H. Walton
pp 2594 - 2600; DOI:
10.1021/ic9614529
PDF
Intercomponent Electronic Energy Transfer in Heteropolynuclear Complexes Containing Ruthenium- and Rhenium-Based Chromophores Bridged by an Asymmetric Quaterpyridine Ligand
Rosemary L. Cleary, Kate J. Byrom, David A. Bardwell, John C. Jeffery, Michael D. Ward, Giuseppe Calogero, Nicola Armaroli, Lucia Flamigni, and Francesco Barigelletti
pp 2601 - 2609; DOI:
10.1021/ic9615281
PDF
Kinetics and Mechanism of the Formation of Palladium Bis(benzylamine) Complexes from Reaction of Benzylamine with Palladium Tri-o-tolylphosphine Mono(amine) Complexes
H. Annita Zhong and Ross A. Widenhoefer
pp 2610 - 2616; DOI:
10.1021/ic961388v
PDF
Electronic Paramagnetic Resonance and Magnetic Properties of Model Complexes for Binuclear Active Sites in Hydrolase Enzymes
Brian E. Schultz, Bao-Hui Ye, Xiao-yuan Li, and Sunney I. Chan
pp 2617 - 2622; DOI:
10.1021/ic960988r
PDF
Chemistry of Gold in Molten Alkali Metal Polychalcophosphate Fluxes. Synthesis and Characterization of the Low-Dimensional Compounds A3AuP2Se8 (A = K, Rb, Cs), A2Au2P2Se6 (A = K, Rb), A2AuPS4 (A = K, Rb, Cs), and AAuP2S7 (A = K, Rb)
Konstantinos Chondroudis, Jason A. Hanko, and Mercouri G. Kanatzidis
pp 2623 - 2632; DOI:
10.1021/ic961376+
PDF
Products and Mechanisms in the Oxidation of Phosphorus by Sulfur at Low Temperature
Mark E. Jason, Toan Ngo, and Shahidur Rahman
pp 2633 - 2640; DOI:
10.1021/ic9614879
PDF
Transfer of Sulfur from Arsenic and Antimony Sulfides to Phosphorus Sulfides. Rational Syntheses of Several Less-Common P4Sn Species
Mark E. Jason
pp 2641 - 2646; DOI:
10.1021/ic9614881
PDF
A General Route to Labile Niobium and Tantalum d0 Monoimides. Discussion of Metal-Nitrogen Vibrational Modes
Andrey V. Korolev, Arnold L. Rheingold, and Darryl S. Williams
pp 2647 - 2655; DOI:
10.1021/ic961360j
PDF
Synthesis and Spectroscopic and Thermal Decomposition Studies of Alkali Metal Salts of 2-Oximidopropionate
Allen W. Apblett, Galina D. Georgieva, and Joel T. Mague
pp 2656 - 2661; DOI:
10.1021/ic9611204
PDF
Synthesis and Reactivity of Dinuclear Platinum Complexes. NMR Spectra of [Pt2(PMe3)6][hfac]2 and an Unusual -Diketonate Bridging Mode in [Pt2(-hfac)(PMe3)4][hfac]
Wenbin Lin, Scott R. Wilson, and Gregory S. Girolami
pp 2662 - 2669; DOI:
10.1021/ic960958o
PDF
W2Cl4(NR2)2(PR'3)2 Molecules. 8. Synthesis and Structural Characterization of Both Cis Isomers of Stoichiometry W2Cl4(NHR)2(PMe3)2, R = Et, Prn, and Bun. Direct Evidence Favoring an Internal Flip Mechanism for Cis-Trans Isomerization
F. Albert Cotton, Evgeny V. Dikarev, and Wai-Yeung Wong
pp 2670 - 2677; DOI:
10.1021/ic9700361
PDF
Speciation of Main-Group Metal Ions by Electrospray Mass Spectrometry. 1. Investigation of Aqueous Polyselenide Species and Effects of Cations and pH
Casey C. Raymond, Donald L. Dick, and Peter K. Dorhout
pp 2678 - 2681; DOI:
10.1021/ic9613366
PDF
Electrochemical Assessment of the Stability of [Os(NH3)5(OH2)]2+ in Aqueous Solutions
Chunnian Shi and Fred C. Anson
pp 2682 - 2687; DOI:
10.1021/ic961522b
PDF
Double Hydrogen Bond- and --Stacking-Assembled Two-Dimensional Copper(I) Complex of 2-Hydroxyquinoxaline
Jie Dai, Mikiko Yamamoto, Takayoshi Kuroda-Sowa, Masahiko Maekawa, Yusaku Suenaga, and Megumu Munakata
pp 2688 - 2690; DOI:
10.1021/ic961217q
PDF
Metal-Assisted Cleavage of the Porphyrinogen Skeleton: Reaction of meso-Octaethylporphyrinogen Complexes with Benzaldehyde
Giovanna Solari, Euro Solari, Gilles Lemercier, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli
pp 2691 - 2695; DOI:
10.1021/ic961446c
PDF
Synthesis, X-ray Structure, and Magnetic Properties of Ferromagnetically Coupled Binuclear Copper(II) Complexes Having a (-Hydroxo/methoxo)bis(-benzoato)dicopper(II) Core
Kannappan Geetha, Munirathinam Nethaji, Akhil R. Chakravarty, and Nagasampagi Y. Vasanthacharya
pp 2696 - 2696; DOI:
10.1021/ic970280s
PDF
Properties of Fluorocarbonyl Peroxynitrate
Dieter Scheffler, Iris Schaper, Helge Willner, Hans-Georg Mack, and Heinz Oberhammer
pp 2696 - 2696; DOI:
10.1021/ic970325p
PDF
Synthesis, Characterization, and Spectroelectrochemistry of Cobalt Porphyrins Containing Axially Bound Nitric Oxide
George B. Richter-Addo, Shelly J. Hodge, Geun-Bae Yi, Masood A. Khan, Tianshu Ma, Eric Van Caemelbecke, Ning Guo, and Karl M. Kadish
pp 2696 - 2696; DOI:
10.1021/ic970402g
PDF

Issue 13


Electrochemical Studies of C60-Triosmium Complexes: First Evidence for a C60-Mediated Electron Transfer to the Metal Center
Joon T. Park, Jeong-Ju Cho, Hyunjoon Song, Chang-Soo Jun, Youngbae Son, and Juhyoun Kwak
pp 2698 - 2699; DOI:
10.1021/ic961504u
PDF
Concerning the Identity of the Pb-Containing Heterometallic Product Obtained on Reacting [Mo3S4(H2O)8]4+ with Pb Metal
David M. Saysell and A. Geoffrey Sykes
pp 2700 - 2701; DOI:
10.1021/ic970024f
PDF
Synthesis of trans-[Mo(O)(F)(dppe)2](BF4), trans-[Mo(O)(OH)(dppe)2](ClO4), and trans-[Mo(O)2(dppe)2]·2L (L = H2O, CH3OH, CH3CH2OH, CH3CHOHCH3). Crystal Structure of trans-[Mo(O)2(dppe)2]·2CH3OH
Jesper Bendix, Henrik Birkedal, and Anders Bgevig
pp 2702 - 2703; DOI:
10.1021/ic9614071
PDF
Terminal Coordination of a Gallium(I) Species to a Transition Metal. Syntheses and Crystal Structures of Ru{GaCl(THF)2}{GaCl2(THF)}2(CO)3·0.5THF and Ru2{GaCl2(THF)}2(CO)8
George N. Harakas and Bruce R. Whittlesey
pp 2704 - 2707; DOI:
10.1021/ic9613772
PDF
Preparation of Cesium Trithionate by the Ultrasonic Reaction of CsF with SO2
Andreas Kornath and and Frank Neumann
pp 2708 - 2710; DOI:
10.1021/ic961290g
PDF
Migratory Transmetalation in Diphenoxo-Bridged CuIIMII Complexes of a Dinucleating Macrocycle with N(amine)2O2 and N(imine)2O2 Metal-Binding Sites
Masami Yonemura, Yukiko Matsumura, Hideki Furutachi, Masaaki Ohba, Hisashi kawa, and David E. Fenton
pp 2711 - 2717; DOI:
10.1021/ic9614430
PDF
Photoinduced Reactions of Tri-tert-butylindium with (Diethylamino)trimethylstannane and (Di-n-butylamino)trimethylstannane
Daniel L. Freeman, Jerome D. Odom, W. Rodger Nutt, and Lukasz Lebioda
pp 2718 - 2722; DOI:
10.1021/ic9606542
PDF
Synthesis and Characterization of (Tris(3,5-dimethylpyrazolyl)borato)rhodium Alkyl and Vinyl Chloride Complexes
Douglas D. Wick and William D. Jones
pp 2723 - 2729; DOI:
10.1021/ic961337y
PDF
Selective Reactivity of the Phosphorus-Chlorine and Carbon-Chlorine Bonds in Cyclic Chlorocarbaphosphazenes: An Unusual Activation of a Carbon-Nitrogen Bond in Trialkylamines
Ashwani Vij, Anil J. Elias, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 2730 - 2745; DOI:
10.1021/ic9612921
PDF
Kinetics and Equilibria of Dioxygen Binding to a Vacant Site in Cobalt(II) Complexes with Pentadentate Ligands
Elena V. Rybak-Akimova, William Otto, Peter Deardorf, Rebecca Roesner, and Daryle H. Busch
pp 2746 - 2753; DOI:
10.1021/ic961371c
PDF
Dynamic Cis-Trans Bridge Isomerism in the Cyclidene Family of Dioxygen Carriers: A Bicyclic Cyclidene with a Trans Bridge Orientation
Alexander G. Kolchinski, Nathaniel W. Alcock, and Daryle H. Busch
pp 2754 - 2759; DOI:
10.1021/ic961327x
PDF
A Heterobimetallic Vanadium-Manganese Complex as a Model for the Structural Dynamics in Oxo-Bridged Metal Dimers
Norman S. Dean, Jennifer K. Cooper, Roman S. Czernuszewicz, David Ji, and Carl J. Carrano
pp 2760 - 2764; DOI:
10.1021/ic9615335
PDF
Chemistry in Environmentally Benign Media. 7.1 Chelating Hydroxymethyl-Functionalized Bisphosphines as Building Blocks to Water-Soluble and in-Vitro-Stable Gold(I) Complexes. Synthesis, Characterization, and X-ray Crystal Structures of [Au{(HOH2C)2PC6H4P(CH2OH)2}2]Cl and [Au2{(HOH2C)2PCH2CH2P(CH2OH)2}2]Cl2
Douglas E. Berning, Kattesh V. Katti, Charles L. Barnes, Wynn A. Volkert, and Alan R. Ketring
pp 2765 - 2769; DOI:
10.1021/ic961396b
PDF
Synthesis and Structures of Intramolecularly Base-Coordinated Group 15 Aryl Halides
Claire J. Carmalt, Alan H. Cowley, Robert D. Culp, Richard A. Jones, Smuruthi Kamepalli, and Nicholas C. Norman
pp 2770 - 2776; DOI:
10.1021/ic9701165
PDF
Templating and Clipping Coordination Reactions Leading to Heteronuclear Trimetallic Complexes Containing Interlocking Rings
Diego J. Cárdenas and and Jean-Pierre Sauvage
pp 2777 - 2783; DOI:
10.1021/ic961469r
PDF
Carboxy and Phosphate Esters Cleavage with Mono- and Dinuclear Zinc(II) Macrocyclic Complexes in Aqueous Solution. Crystal Structure of [Zn2L1(-PP)2(MeOH)2](ClO4)2 (L1 = [30]aneN6O4, PP- = Diphenyl Phosphate)
Carla Bazzicalupi, Andrea Bencini, Antonio Bianchi, Vieri Fusi, Claudia Giorgi, Piero Paoletti, Barbara Valtancoli, and Daniela Zanchi
pp 2784 - 2790; DOI:
10.1021/ic961521j
PDF
Pressure Dependence Investigation of the Low-Temperature Structure of TlAu(CN)2 by High-Resolution Neutron Powder Diffraction and Optical Studies
Peter Fischer, Joël Mesot, Brian Lucas, Andreas Ludi, Howard Patterson, and Alan Hewat
pp 2791 - 2794; DOI:
10.1021/ic961405g
PDF
Anionic and Neutral Aluminum Bis(N,N'-di-tert-butylethylenediamide) Complexes: [Al{[N(t-Bu)CH2]2}2]- and [Al{[N(t-Bu)CH2]2}2]
Michael G. Gardiner, Colin L. Raston, Brian W. Skelton, and Allan H. White
pp 2795 - 2803; DOI:
10.1021/ic961233n
PDF
Ligand Dehydrogenation in Ruthenium-Amine Complexes: Reactivity of 1,2-Ethanediamine and 1,1,1-Tris(aminomethyl)ethane
Paul Bernhard, Daryl J. Bull, Hans-Beat Bürgi, Peter Osvath, Andrea Raselli, and Alan M. Sargeson
pp 2804 - 2815; DOI:
10.1021/ic961021q
PDF
Magnetic Susceptibility and EPR Spectra of (-Hydroxo)bis[pentaamminechromium(III)] Chloride Monohydrate
Jrgen Glerup and Hgni Weihe
pp 2816 - 2819; DOI:
10.1021/ic970029c
PDF
Structure and Stability of Carboxylate Complexes. 20. Diaqua Bis(methoxyacetato) Complexes of Nickel(II), Copper(II), and Zinc(II): A Structural Study of the Dynamic Pseudo-Jahn-Teller Effect
Keith Prout, Alison Edwards, Victor Mtetwa, Jon Murray, John F. Saunders, and Francis J. C. Rossotti
pp 2820 - 2825; DOI:
10.1021/ic9613467
PDF
Multielectron Reduction of -[S2Mo18O62]4- in Aprotic and Protic Media: Voltammetric Studies
David M. Way, Alan M. Bond, and Anthony G. Wedd
pp 2826 - 2833; DOI:
10.1021/ic961480r
PDF
Exchange Coupling in an Isostructural Series of Face-Sharing Bioctahedral Complexes [LMII(-X)3MIIL]BPh4 (M = Mn, Fe, Co, Ni, Zn; X = Cl, Br; L = 1,4,7-Trimethyl-1,4,7-triazacyclononane)
Ursula Bossek, Daniela Nühlen, Eckhard Bill, Thorsten Glaser, Carsten Krebs, Thomas Weyhermüller, Karl Wieghardt, Marek Lengen, and A. X. Trautwein
pp 2834 - 2843; DOI:
10.1021/ic970119h
PDF
Mechanism of the Formation of Organic Derivatives of -Zirconium Phosphate by Topotactic Reactions with Phosphonic Acids in Water and Water-Acetone Media
G. Alberti, E. Giontella, and S. Murcia-Mascarós
pp 2844 - 2849; DOI:
10.1021/ic970048m
PDF
Preparation and Probable Structure of Layered Complexes of Vanadyl Phosphate with 1-Alkanols and 1,-Alkanediols
Ludvík Bene, Klára Melánová, Vítzslav Zima, Jaroslava Kalousová and, and Jií Votinsk
pp 2850 - 2854; DOI:
10.1021/ic970073s
PDF
The Structurally Flexible Bicyclic Bis(2-hydroxyethanethiolato)bismuth(III) Complex: A Model for Asymmetric Monoanionic Chelation of Bismuth(III)
Lisa Agocs, Glen G. Briand, Neil Burford, T. Stanley Cameron, Witold Kwiatkowski, and Katherine N. Robertson
pp 2855 - 2860; DOI:
10.1021/ic961262y
PDF
Electrochemical, Spectroscopic, and Spectroelectrochemical Properties of Synthetically Useful Supramolecular Light Absorbers with Mixed Polyazine Bridging Ligands
Eric Brauns, Sumner W. Jones, Jeff A. Clark, Sharon M. Molnar, Yuji Kawanishi, and Karen J. Brewer
pp 2861 - 2867; DOI:
10.1021/ic961302y
PDF
Measurements of Structural and Quadrupolar Coupling Parameters for Chloroferrocene Using Microwave Spectroscopy
Brian J. Drouin, Paul A. Cassak, and Stephen G. Kukolich
pp 2868 - 2871; DOI:
10.1021/ic961516f
PDF
Stereochemical Control of Donor and Acceptor Groups in a Monomeric Chromophore-Quencher Complex of Ruthenium(II)
Todd J. Rutherford and F. Richard Keene
pp 2872 - 2878; DOI:
10.1021/ic9615279
PDF
Linear Chain Formation by an Oxovanadium(V) Complex of p-Methylhexahomotrioxacalix[3]arene
Philip D. Hampton, Charles E. Daitch, Todd M. Alam, and Eugene A. Pruss
pp 2879 - 2883; DOI:
10.1021/ic9611195
PDF
Iron Complexes Containing the Tripodal Tetraphosphine Ligand P(CH2CH2PMe2)3
Leslie D. Field, Barbara A. Messerle, Ronald J. Smernik, Trevor W. Hambley, and Peter Turner
pp 2884 - 2892; DOI:
10.1021/ic970030b
PDF
Mechanisms of Reactions of NO with Complexes with Metal-Carbon -Bonds and with Aliphatic Radicals
Sara Goldstein, Dan Meyerstein, and Gidon Czapski
pp 2893 - 2897; DOI:
10.1021/ic9614327
PDF
Is the "Unusual" Three-Center D-H---A-M Hydrogen Bond Really Unusual?
H. Dadon and J. Bernstein
pp 2898 - 2900; DOI:
10.1021/ic961508z
PDF
Resonance Raman Spectra of Fluoride Anion Ligated Ferryloxo Tetramesitylporphyrin Cation Radical Compounds
Ki-Jung Paeng, Dae-Ho Shin, and Insook Rhee Paeng
pp 2901 - 2903; DOI:
10.1021/ic961094+
PDF
Synthesis, Characterization, and Structure of (-Sulfido)bis[(octaethylporphyrinato)ruthenium(III)], [Ru(OEP)]2S
Gordon T. Yee, Bruce C. Noll, Daniel K. C. Williams, and Scott P. Sellers
pp 2904 - 2907; DOI:
10.1021/ic961511i
PDF
Synthesis and Crystal Structure of a Cationic Trinuclear Ruthenium(II) Complex, [Ru3(2-Cl)3(3-Cl)2{1,2-bis(diphenylphosphino)benzene}3]PF6
Kazushi Mashima, Naoki Komura, Tsuneaki Yamagata, Kazuhide Tani, and Masa-aki Haga
pp 2908 - 2912; DOI:
10.1021/ic961278o
PDF
Reductive Carbonylation of Ruthenium(III) by Ethylene Glycol in the Synthesis of Ruthenium(II) ,'-Diimine Complexes
Ramgopal Bhattacharyya, Russell S. Drago, and Khalil A. Abboud
pp 2913 - 2915; DOI:
10.1021/ic9609822
PDF
Sequential Growth of Heteropolymetallic (Pt2 AgPt2 Ag2Pt2 Ag2Pt4) Sulfide Aggregates. Structure of the Intermediate Ag2Pt2Cl2(PPh3)4(3-S)2 with a Flat {Pt2S2} Core and Two AgCl Molecular Pendants
Huang Liu, Agnes L. Tan, C. R. Cheng, K. F. Mok, and T. S. Andy Hor
pp 2916 - 2918; DOI:
10.1021/ic961173l
PDF
NMR Study of the Sequence-Specific Binding of the -Tris(ethylenediamine)cobalt(III) Cation with d(TCGGGATCCCGA)2
John V. Fry and J. Grant Collins
pp 2919 - 2921; DOI:
10.1021/ic960937u
PDF
A Density Functional Study of the Rotational Barrier of Tricarbonyl(4-norbornadiene)iron. Effect of the Torsional Angle on the Carbonyl Stretching Spectra
Michael Bühl and Walter Thiel
pp 2922 - 2924; DOI:
10.1021/ic961497+
PDF

Issue 14


Probing Copper-Thioether Coordination Chemistry in Rusticyanin and Azurin by 2D 1H-199Hg NMR
Lisa M. Utschig, Tahllee Baynard, Cynthia Strong, and Thomas V. O'Halloran
pp 2926 - 2927; DOI:
10.1021/ic960571l
PDF
Preparation of Complexes Containing Ti=E, Ti2(-E)2, and Ti(2-E2) (E = O, S) Functionalities from a Reactive Titanium Dinitrogen Complex
John R. Hagadorn and John Arnold
pp 2928 - 2929; DOI:
10.1021/ic970413+
PDF
Syntheses, Structures, and Thermal Behavior of Cu(hfacac) Complexes Derived from Ethanolamines
Jirí Pinkas, John C. Huffman, John C. Bollinger, William E. Streib, David V. Baxter, Malcolm H. Chisholm, and Kenneth G. Caulton
pp 2930 - 2937; DOI:
10.1021/ic960370h
PDF
Binary, Ternary, and Quarternary Complexes of Ruthenium(II) Involving the Flexidentate ONNS Donor Mono(4-(4-tolyl)thiosemicarbazone) of 2,6-Diacetylpyridine (L2H). First Report on Ruthenium Complexes of a Mono(thiosemicarbazone) of a Diketone: Crystal Structure of [Ru(L2)(PPh3)2]ClO4
Milan Maji, Saktiprosad Ghosh, Shyamal Kumar Chattopadhyay, and Thomas C. W. Mak
pp 2938 - 2943; DOI:
10.1021/ic9701118
PDF
Synthesis and Coordination Chemistry of the Bis(imidazole) Ligand, Bis(1-methyl-4,5-diphenylimidaz-2-oyl)(benzyloxy)methane
Rajiv Bhalla, Madeleine Helliwell, and C. David Garner
pp 2944 - 2949; DOI:
10.1021/ic961204c
PDF
Oxidatively Induced Isomerization of Square-Planar [Ni(1,4,8,11-tetraazacyclotetradecane)](ClO4)2
David T. Pierce, Thomas L. Hatfield, E. Joseph Billo, and Yao Ping
pp 2950 - 2955; DOI:
10.1021/ic9614172
PDF
Selective Binding of Trivalent Metals by Hexahomotrioxacalix[3]arene Macrocycles: Determination of Metal-Binding Constants and Metal Transport Studies
Philip D. Hampton, Charles E. Daitch, and Amy M. Shachter
pp 2956 - 2959; DOI:
10.1021/ic961445k
PDF
Coordination Networks of 3,3'-Dicyanodiphenylacetylene and Silver(I) Salts: Structural Diversity through Changes in Ligand Conformation and Counterion
Keith A. Hirsch, Scott R. Wilson, and Jeffrey S. Moore
pp 2960 - 2968; DOI:
10.1021/ic970150j
PDF
The mpz+/mpz Pair as Organic Analogue of the NO+/NO Ligand Redox System (mpz = N-Methylpyrazinium). A Combined Electrochemical and Spectroscopic Study (UV/Vis/NIR, IR, EPR) of Complexes [(mpz)M(CN)5]2-/3- (M = Fe, Ru, Os)
Eberhard Waldhör, Wolfgang Kaim, José A. Olabe, Leonardo D. Slep, and Jan Fiedler
pp 2969 - 2974; DOI:
10.1021/ic961426a
PDF
Spin Transition in [Fe(DPEA)(NCS)2], a Compound with the New Tetradentate Ligand (2-Aminoethyl)bis(2-pyridylmethyl)amine (DPEA): Crystal Structure, Magnetic Properties, and Mössbauer Spectroscopy
Galina S. Matouzenko, Azzedine Bousseksou, Sylvain Lecocq, Petra J. van Koningsbruggen, Monique Perrin, Olivier Kahn, and André Collet
pp 2975 - 2981; DOI:
10.1021/ic9615133
PDF
Preparation and Solution Properties of Chalcogenide-Rich Clusters [Mo3Y7(H2O)6]4+ (Y = S, Se): Kinetics of PR33- Abstraction of Y from -(Y22-) and H2O Substitution by Cl- and Br-
David M. Saysell, Vladimir P. Fedin, Gert J. Lamprecht, Maxim N. Sokolov, and A. Geoffrey Sykes
pp 2982 - 2987; DOI:
10.1021/ic961343u
PDF
First Example of a Bis(dicarbollide) Metallacarborane Containing a B,C'-Heteronuclear Bridge
Clara Viñas, Josefina Pedrajas, Francesc Teixidor, Raikko Kivekäs, Reijo Sillanpää, and Alan J. Welch
pp 2988 - 2991; DOI:
10.1021/ic961436b
PDF
Synthesis and NMR Studies of Three Pyridine-Containing Triaza Macrocyclic Triacetate Ligands and Their Complexes with Lanthanide Ions
Silvio Aime, Mauro Botta, Simonetta Geninatti Crich, Giovanni B. Giovenzana, Giancarlo Jommi, Roberto Pagliarin, and Massimo Sisti
pp 2992 - 3000; DOI:
10.1021/ic960794b
PDF
H+/AuPPh3+ Exchange for the Hydride Complexes CpMoH(CO)2(L) (L = PMe3, PPh3, CO). Formation and Structure of [Cp(CO)2(PMe3)Mo(AuPPh3)2]+[BF4]-
Rossana Galassi, Rinaldo Poli, E. Alessandra Quadrelli, and James C. Fettinger
pp 3001 - 3007; DOI:
10.1021/ic961265a
PDF
Spin Crossover in Novel Dihydrobis(1-pyrazolyl)borate [H2B(pz)2]-Containing Iron(II) Complexes. Synthesis, X-ray Structure, and Magnetic Properties of [FeL{H2B(pz)2}2] (L = 1,10-Phenanthroline and 2,2'-Bipyridine)
José Antonio Real, M. Carmen Muñoz, Juan Faus, and Xavier Solans
pp 3008 - 3013; DOI:
10.1021/ic960965c
PDF
Ferromagnetic Interactions between Imino Nitroxides through Diamagnetic Metal Ions: Crystal Structures, Magnetism, and Electronic Properties of [MI(imino nitroxide)2](PF6) (M = CuI and AgI)
Hiroki Oshio, Takashi Watanabe, Akihiro Ohto, Tasuku Ito, Tadaaki Ikoma, and Shozo Tero-Kubota
pp 3014 - 3021; DOI:
10.1021/ic960939e
PDF
Reinterpretation of the Lengths of Bonds to Fluorine in Terms of an Almost Ionic Model
Edward A. Robinson, Samuel A. Johnson, Ting-Hua Tang, and Ronald J. Gillespie
pp 3022 - 3030; DOI:
10.1021/ic961315b
PDF
Study of Bond Angles and Bond Lengths in Disiloxane and Related Molecules in Terms of the Topology of the Electron Density and Its Laplacian
Ronald J. Gillespie and Samuel A. Johnson
pp 3031 - 3039; DOI:
10.1021/ic961381d
PDF
Intraligand Charge Transfer in Pt(qol)2. Characterization of Electronic States by High-Resolution Shpol'skii Spectroscopy
Dirk Donges, Jeffrey K. Nagle, and Hartmut Yersin
pp 3040 - 3048; DOI:
10.1021/ic9609463
PDF
Cs5Mo8O24(OH)2AsO4·2H2O and Cs7Mo8O26AsO4: Two Novel Molybdenum(VI) Arsenates Containing Heteropolyanions [AsMo8O30H2]5- and [AsMo8O30]7-
Kuei-Fang Hsu and Sue-Lein Wang
pp 3049 - 3054; DOI:
10.1021/ic961459q
PDF
Studies of the Structure and Composition of Rhenium-1,1-Hydroxyethylidenediphosphonate (HEDP) Analogues of the Radiotherapeutic Agent 186ReHEDP
R. C. Elder, Jie Yuan, Bella Helmer, David Pipes, Karen Deutsch, and Edward Deutsch
pp 3055 - 3063; DOI:
10.1021/ic960980h
PDF
Synthesis of Bis(aliphatic amine)osmium(II), Bis(arylamido)osmium(IV), and Bis(imido)- and Oxo(imido)osmium(VI) Porphyrins
Zao-Ying Li, Jie-Sheng Huang, Michael Chi-Wang Chan, Kung-Kai Cheung, and Chi-Ming Che
pp 3064 - 3071; DOI:
10.1021/ic961228j
PDF
Syntheses and X-ray Powder Structures of K2(ZrSi3O9)·H2O and Its Ion-Exchanged Phases with Na and Cs
Damodara M. Poojary, Anatoly I. Bortun, Lyudmila N. Bortun, and Abraham Clearfield
pp 3072 - 3079; DOI:
10.1021/ic970052y
PDF
Cooperativity in the Iron(II) Spin-Crossover Compound [Fe(ptz)6](PF6)2 under the Influence of External Pressure (ptz = 1-n-Propyltetrazole)
Jelena Jefti, Roland Hinek, Silvia C. Capelli, and Andreas Hauser
pp 3080 - 3087; DOI:
10.1021/ic961404o
PDF
A Triangular Copper(I) Complex Displaying Allosteric Cooperativity in Its Electrochemical Behavior and a Mixed-Valence Cu(I)-Cu(I)-Cu(II) State with Unusual Temperature-Dependent Behavior
Peter L. Jones, John C. Jeffery, John P. Maher, Jon A. McCleverty, Philip H. Rieger, and Michael D. Ward
pp 3088 - 3095; DOI:
10.1021/ic970088q
PDF
The Complexing Properties of 1-Aminosquarate Derivatives with Lead
Lincoln A. Hall, David J. Williams, Stephan Menzer, and Andrew J. P. White
pp 3096 - 3101; DOI:
10.1021/ic961341+
PDF
Crystal Structures and Magnetic Properties of a Novel Layer Perovskite System: (3-Picoliniumylammonium)CuX4 (X = Cl, Br)
Greg S. Long, Mingyi Wei, and Roger D. Willett
pp 3102 - 3107; DOI:
10.1021/ic960849+
PDF
Monomeric Titanium(IV) Azides as a New Route to Titanium Nitride
Claire J. Carmalt, Alan H. Cowley, Robert D. Culp, Richard A. Jones, Yang-Ming Sun, Bill Fitts, Sandra Whaley, and Herbert W. Roesky
pp 3108 - 3112; DOI:
10.1021/ic9614834
PDF
Reactions of Hydroxylamine with Metal Porphyrins
In-Kyu Choi, Yanming Liu, Zhongcheng Wei, and Michael D. Ryan
pp 3113 - 3118; DOI:
10.1021/ic9605783
PDF
Characterization of Copper(III)-Tetrapeptide Complexes with Histidine as the Third Residue
Michael R. McDonald, Francoise C. Fredericks, and Dale W. Margerum
pp 3119 - 3124; DOI:
10.1021/ic9608713
PDF
Copper(II) Complexes of Bis(1,4,7-triazacyclononane) Ligands with Polymethylene Bridging Groups: An Equilibrium and Structural Study
Reem Haidar, Manus Ipek, Barnali DasGupta, Mohammed Yousaf, and Leverett J. Zompa
pp 3125 - 3132; DOI:
10.1021/ic970070f
PDF
Formation of Ruthenium(II) Complexes with Unsymmetrical Terdentate Ligands
Yurngdong Jahng, Randolph P. Thummel, and Simon G. Bott
pp 3133 - 3138; DOI:
10.1021/ic961061u
PDF
Homo- and Heteronuclear Ruthenium and Osmium Complexes Containing an Asymmetric Pyrazine-Based Bridging Ligand
Ronald Hage, Hans E. B. Lempers, Jaap G. Haasnoot, Jan Reedijk, Frances M. Weldon, and Johannes G. Vos
pp 3139 - 3145; DOI:
10.1021/ic961277w
PDF
Redox Polyether Hybrid Copper Bipyridine Complex Molten Salts
Franzpeter Emmenegger, Mary Elizabeth Williams, and Royce W. Murray
pp 3146 - 3151; DOI:
10.1021/ic970149k
PDF
Solution Dynamics of Thallium-Metal Carbonyl Compounds Using 205Tl NMR Spectroscopy
Jaap W. van Hal, Lawrence B. Alemany, and Kenton H. Whitmire
pp 3152 - 3159; DOI:
10.1021/ic961203k
PDF
Preparation and NMR Spectra of Difluoromethylated Silver(I) and Silver(III) Compounds. Structure of [PNP][Ag(CF2H)4]
Reint Eujen, Berthold Hoge, and David J. Brauer
pp 3160 - 3166; DOI:
10.1021/ic961398w
PDF
Crystal Structure of N,N-Dimethylthioformamide Solvates of the Divalent Group 12 Ions with Linear Coordination Geometry for Mercury(II), Tetrahedral for Zinc(II), and Octahedral for Cadmium(II)
Christina M. V. Stålhandske, Claes I. Stålhandske, Magnus Sandström, and Ingmar Persson
pp 3167 - 3173; DOI:
10.1021/ic960932x
PDF
Structure of the Solvated Zinc(II), Cadmium(II), and Mercury(II) Ions in N,N-Dimethylthioformamide Solution
Christina M. V. Stålhandske, Ingmar Persson, Magnus Sandström, and Ewa Kamienska-Piotrowicz
pp 3174 - 3182; DOI:
10.1021/ic961339i
PDF
Magnetic Interactions in the Copper Complex (L-Aspartato)(1,10-phenanthroline)copper(II) Hydrate. An Exchange-Coupled Extended System with Two Dissimilar Copper Ions
Carlos D. Brondino and, Rafael Calvo, Ana María Atria, Evgenia Spodine, Otaciro R. Nascimento, and Octavio Peña
pp 3183 - 3189; DOI:
10.1021/ic9610501
PDF
Electronic and Molecular Structures of Pentaammineruthenium Pyridine and Benzonitrile Complexes as a Function of Oxidation State
Yeung-gyo K. Shin, David J. Szalda, Bruce S. Brunschwig, Carol Creutz, and Norman Sutin
pp 3190 - 3197; DOI:
10.1021/ic9700967
PDF
A Binuclear Zirconium(IV) Oxalate Complex with a -Oxalate Coordination Mode. Crystal Structure of K6[{Zr(C2O4)3}2(-C2O4)]·4H2O
Ricardo Baggio, Maria Teresa Garland, and Mireille Perec
pp 3198 - 3200; DOI:
10.1021/ic9613826
PDF
The Ferromagnetic Chain System catena-(-CrO4-O,O')[NiII(cyclam)]·2H2O
Hiroki Oshio, Hiroshi Okamoto, Toshihiko Kikuchi, and Tasuku Ito
pp 3201 - 3203; DOI:
10.1021/ic970180m
PDF
Substituent Steric Strain: Enthalpic Estimates for the Consequences of Interactions between Bulky Substituents
Neil Burford, Jason A. C. Clyburne, and Mary S. W. Chan
pp 3204 - 3206; DOI:
10.1021/ic961091x
PDF
On the Geometry of the CuCl2 Molecule
I. R. Beattie, J. M. Brown, P. Crozet, A. J. Ross, and A. Yiannopoulou
pp 3207 - 3208; DOI:
10.1021/ic961509r
PDF

Issue 15


C3-Symmetric Chiral Amidate Complexes: Effects of Ligand Binding on Cavity Structure
Brian S. Hammes, Dorisa Ramos-Maldonado, Glenn P. A. Yap, Louise Liable-Sands, Arnold L. Rheingold, Victor G. Young, Jr., and A. S. Borovik
pp 3210 - 3211; DOI:
10.1021/ic970124l
PDF
Lanthanide Phosphido Complexes: A Comparison of the Divalent Homoleptic Species Ln[(-PtBu2)2Li(thf)]2 (Ln = Yb, Eu, Sm) Including the Structural Characterization and a Europium-151 Mössbauer Spectrum of Eu[(-PtBu2)2Li(thf)]2
Gerd W. Rabe, Glenn P. A. Yap, and Arnold L. Rheingold
pp 3212 - 3215; DOI:
10.1021/ic9607954
PDF
Evidence for the Unexpected Associative Displacement of Adenosyl by Cyanide in Coenzyme B12
Nicola E. Brasch, Mohamed S. A. Hamza, and Rudi van Eldik
pp 3216 - 3222; DOI:
10.1021/ic961312z
PDF
-Bond Metathesis Reactions Involving Palladium(II) Hydride and Methyl Complexes: A Theoretical Assessment
Anne Milet, Alain Dedieu, Gerard Kapteijn, and G. van Koten
pp 3223 - 3231; DOI:
10.1021/ic960807l
PDF
Carbonylation of a Tetrameric Aryloxocopper(I) Cluster
Cesar Lopes, Mikael Håkansson, and Susan Jagner
pp 3232 - 3236; DOI:
10.1021/ic961287x
PDF
Synthesis and Characterization of Rhenium(III) and Technetium(III) Organohydrazide Chelate Complexes. Reactions of 2-Hydrazinopyridine with Complexes of Rhenium and Technetium
Melissa Hirsch-Kuchma, Terrence Nicholson, Alan Davison, William M. Davis, and Alun G. Jones
pp 3237 - 3241; DOI:
10.1021/ic961489t
PDF
Probing the Balance between Localization and Delocalization of the Metal-Based Electrons in Face-Shared Bioctahedral Complexes
John E. McGrady, Timothy Lovell, and Robert Stranger
pp 3242 - 3247; DOI:
10.1021/ic961208h
PDF
Paramagnetism of Tetranuclear Complexes between TCNX Ligands (TCNE, TCNQ, TCNB) and Four Pentaammineruthenium or Dicarbonyl(pentamethylcyclopentadienyl)manganese Fragments
Eberhard Waldhör, Wolfgang Kaim, Max Lawson, and Jeanne Jordanov
pp 3248 - 3252; DOI:
10.1021/ic960998s
PDF
Effect of Conformational Constraints on Gated Electron Transfer Kinetics. 2. Copper(II/I) Complexes with Phenyl-Substituted [14]aneS4 Ligands in Acetonitrile
Brian C. Dunn, L. A. Ochrymowycz, and D. B. Rorabacher
pp 3253 - 3257; DOI:
10.1021/ic960793j
PDF
Incorporation of Ru2(O2C(CH2)6CH3)4 into Extended Chains: Interaction of Ru2(O2C(CH2)6CH3)4 with Pyrazine, 4-Cyanopyridine, TCNE, and p-Benzoquinone
Jodi L. Wesemann and and Malcolm H. Chisholm
pp 3258 - 3267; DOI:
10.1021/ic970173y
PDF
W2Cl4(NR2)2(PR'3)2 Molecules. 7. Preparation, Characterization, and Structures of W2Cl4(NHR)2(NH2R)2 and W2Cl4(NHR)2(PMe3)2 (R = sec-Butyl and Cyclohexyl) and 31P{1H} NMR Studies of Trans-to-Cis Isomerizations of W2Cl4(NHR)2(PMe3)2
F. Albert Cotton, Evgeny V. Dikarev, and Wai-Yeung Wong
pp 3268 - 3276; DOI:
10.1021/ic961485o
PDF
Kinetically and Thermodynamically Controlled Formation of Homo- and Heterobinuclear Platinum(II) and Palladium(II) Complexes Supported by Bidentate Triazolopyrimidine Ligands
Jorge A. R. Navarro, M. Angustias Romero, Juan M. Salas, and Miguel Quirós
pp 3277 - 3283; DOI:
10.1021/ic9609214
PDF
Large Molecular Quadratic Hyperpolarizabilities in Donor/Acceptor-Substituted trans-Tetraammineruthenium(II) Complexes
Benjamin J. Coe, Michelle C. Chamberlain, Jonathan P. Essex-Lopresti, Simon Gaines, John C. Jeffery, Stephan Houbrechts, and André Persoons
pp 3284 - 3292; DOI:
10.1021/ic961465m
PDF
Titanium(IV) Neopentoxides. X-ray Structures of Ti3(3-O)(3-Cl)(-OCH2CMe3)3(OCH2CMe3)6 and [Ti(-OCH2CMe3)(OCH2CMe3)3]2
Timothy J. Boyle, Todd M. Alam, Eric R. Mechenbier, Brian L. Scott, and Joseph W. Ziller
pp 3293 - 3300; DOI:
10.1021/ic960924g
PDF
An Azide-Bridged Copper(II) Ferromagnetic Chain Compound Exhibiting Metamagnetic Behavior
Laurence K. Thompson, Santokh S. Tandon, Francesc Lloret, Juan Cano, and Miguel Julve
pp 3301 - 3306; DOI:
10.1021/ic970023n
PDF
Electrochemistry of Oxygenation Catalysts. 3.1 Thermodynamic Characterization of Electron Transfer and Solvent Exchange Reactions of Co(salen)/[Co(salen)]+ in DMF, Pyridine, and Their Mixtures
Emerich Eichhorn, Anton Rieker, Bernd Speiser, and Hartmut Stahl
pp 3307 - 3317; DOI:
10.1021/ic9703336
PDF
Electroabsorption Studies of Metal-to-Ligand Charge Transfer in Ru(phenanthroline)32+: Evidence for Intrinsic Charge Localization in the Initially Formed Excited State
Laba Karki and Joseph T. Hupp
pp 3318 - 3321; DOI:
10.1021/ic961349j
PDF
Inner Coordination Sphere Control of Metal-Metal Superexchange in Ruthenium Dimers
Ali R. Rezvani, Corinne Bensimon, Benoit Cromp, Christian Reber, J. E. Greedan, Veniamin V. Kondratiev, and Robert J. Crutchley
pp 3322 - 3329; DOI:
10.1021/ic9700260
PDF
Synthesis of Homoleptic Neopentoxide and Hydrido-Neopentoxide Trirhenium(III) Clusters
Wei-Wei Zhuang, Brandon E. Truitt, and David M. Hoffman
pp 3330 - 3334; DOI:
10.1021/ic9613422
PDF
Oligomerization and Oxide Formation in Bismuth Aryloxides: Synthesis, Characterization, and Structures of [NaBi(OC6F5)4(THF)] and Na4Bi2(6-O)(OC6F5)8(THF)4
Jennifer L. Jolas, Silke Hoppe, and Kenton H. Whitmire
pp 3335 - 3340; DOI:
10.1021/ic961481j
PDF
Comparison of H-H versus Si-H -Bond Coordination and Activation on 16e Metal Fragments. Organosilane, N2, and Ethylene Addition to the Agostic Complex W(CO)3(PR3)2 and Dynamic NMR Behavior of the Latter
Matthew D. Butts, Jeffrey C. Bryan, Xiao-Liang Luo, and Gregory J. Kubas
pp 3341 - 3353; DOI:
10.1021/ic960870a
PDF
A Bidentate Bisphosphine Functioning in Intramolecular Aliphatic Metalation and as an NMR Spectroscopic Probe for the Metal Coordination Environment
William Lesueur, Euro Solari, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli
pp 3354 - 3362; DOI:
10.1021/ic9700819
PDF
Structural, Electrical, Magnetic, and Spectroscopic Properties of Ring-Oxidized Molecular Metals Produced by Iodination of Metal-Free and Nickel Tetrabenzporphyrins
Kazuhiko Murata, Kwangkyoung Liou, Julia A. Thompson, Ellen M. McGhee, Dean E. Rende, Donald E. Ellis, Ronald L. Musselman, Brian M. Hoffman, and James A. Ibers
pp 3363 - 3369; DOI:
10.1021/ic961490s
PDF
Synthesis, Structure, and Thiolysis Reactions of Pyridine Soluble Alkaline Earth and Yttrium Thiolates
Andrew P. Purdy, Alan D. Berry, and Clifford F. George
pp 3370 - 3375; DOI:
10.1021/ic970045+
PDF
New Synthesis Routes to Lithium and Cesium Cyanide Salts
Thomas J. Markley, Brian H. Toby, Ronald M. Pearlstein, and Dorai Ramprasad
pp 3376 - 3378; DOI:
10.1021/ic961395j
PDF
Preparation and Molecular Structure of the Unconventional Tantalum Chloride Complex [(5-C9H7)2TaCl2][TaCl6]
Jesse M. Jefferis, Robert J. Morris, and John C. Huffman
pp 3379 - 3381; DOI:
10.1021/ic970178v
PDF
Hysteresis of the Pressure-Induced Jahn-Teller Switch in Deuterated Ammonium Copper(II) Tutton Salt, (ND4)2[Cu(D2O)6](SO4)2
Arthur J. Schultz, Michael A. Hitchman, James D. Jorgensen, Sergei Lukin, Paolo G. Radaelli, Charles J. Simmons, and Horst Stratemeier
pp 3382 - 3385; DOI:
10.1021/ic970028k
PDF
Carbidoheptarhenate Complexes of Mercury Hydroxide and Arenethiolate. Crystal Structures of [NEt3Bz]2[Re7C(CO)21HgOH] and [PPh4]2[Re7C(CO)21HgSC6H4Br]
Udo Brand, Jeffery L. Coffer, Timothy J. Henly, Scott R. Wilson, and John R. Shapley
pp 3386 - 3389; DOI:
10.1021/ic970068o
PDF
Synthesis and X-ray Structures of Elusive Imine/Oxime-Type Organocobalt B12 Complexes. NMR Study Suggesting Steric Strain within the Axially Ligated Benzimidazole
Suzette M. Polson, Renzo Cini, Claudia Pifferi, and Luigi G. Marzilli
pp 3390 - 3390; DOI:
10.1021/ic9704492
PDF
Preparation and Characterization of a Diamagnetic and Dinuclear Titanium(III) Formamidinate Complex. Evidence for the Existence of a Ti-Ti Bond?
Shoukang Hao, Khalil Feghali, and Sandro Gambarotta
pp 3390 - 3390; DOI:
10.1021/ic9705610
PDF

Issue 16


Formation of a Tantalum Siloxane Cage Complex in the Reaction of (5-C5Me5)TaMe4 with a Silanetriol
Alexander I. Gouzyr, Helge Wessel, Craig E. Barnes, Herbert W. Roesky, Markus Teichert, and Isabel Usón
pp 3392 - 3393; DOI:
10.1021/ic970566x
PDF
Bond Valence Sums in Coordination Chemistry Using Oxidation State Independent R0 Values. A Simple Calculation of the Oxidation State of Titanium in Complexes Containing Ti-N, Ti-O, and Ti-Cl Bonds
Gus J. Palenik
pp 3394 - 3397; DOI:
10.1021/ic970239p
PDF
Novel Alkali-Metal Coordination in Phenoxides: Powder Diffraction Results on C6H5OM (M = Li, Na, K, Rb, Cs)
R. E. Dinnebier, Maren Pink, J. Sieler, and P. W. Stephens
pp 3398 - 3401; DOI:
10.1021/ic961385i
PDF
Synthesis and X-ray Powder Structures of Nickel(II) and Copper(II) Coordination Polymers with 2,5-Bis(2-pyridyl)pyrazine
Antonia Neels, Bernard Mathez Neels, Helen Stoeckli-Evans, Abraham Clearfield, and Damodara M. Poojary
pp 3402 - 3409; DOI:
10.1021/ic970175i
PDF
Layered Iron(III) Arsenates: Synthesis and Characterization of A2Fe2O(AsO4)2 (A = K, Rb)
Rei-Shyang Chang, Sue-Lein Wang, and Kwang-Hwa Lii
pp 3410 - 3413; DOI:
10.1021/ic970004d
PDF
Synthesis and Crystal Structure of a Novel Lamellar Barium Derivative: Ba(VOPO4)2·4H2O. Synthetic Pathways for Layered Oxovanadium Phosphate Hydrates M(VOPO4)2·nH2O
Manuel Roca, M. Dolores Marcos, Pedro Amorós, Jaime Alamo, Aurelio Beltrán-Porter, and Daniel Beltrán-Porter
pp 3414 - 3421; DOI:
10.1021/ic970166+
PDF
Intercalative Ion Exchange of Polyamine Transition Metal Complexes into Hydrogen Uranyl Phosphate
Daniel Grohol and Elliott L. Blinn
pp 3422 - 3428; DOI:
10.1021/ic970079h
PDF
A General Route to Strictly Dinuclear Cu(II)/Ln(III) Complexes. Structural Determination and Magnetic Behavior of Two Cu(II)/Gd(III) Complexes
J.-P. Costes, F. Dahan, A. Dupuis, and J.-P. Laurent
pp 3429 - 3433; DOI:
10.1021/ic970264v
PDF
Ferromagnetic Coupling between Copper(II) Centers through the Diamagnetic Zinc(II) Ion: Crystal Structure and Magnetic Properties of [Cu2Zn(Hdmg)2(dmg)2(H2O)]·0.5H2dmg·H2O (H2dmg = Dimethylglyoxime)
Rafael Ruiz, Miguel Julve, Juan Faus, Francesc Lloret, M. Carmen Muñoz, Yves Journaux, and Claudette Bois
pp 3434 - 3439; DOI:
10.1021/ic9700011
PDF
A New Family of High-Dimensional Molecular Magnets Built from the Manganese-Azido System. Syntheses, Structures, and Magnetic Characterization of Two New Ferro-Antiferromagnetic Two-Dimensional Complexes
Albert Escuer, Ramon Vicente, Mohamed A. S. Goher, and Franz A. Mautner
pp 3440 - 3446; DOI:
10.1021/ic961476f
PDF
Roles of Bridging Ligand Topology and Conformation in Controlling Exchange Interactions between Paramagnetic Molybdenum Fragments in Dinuclear and Trinuclear Complexes
Vn Ân Ung, Alexander M. W. Cargill Thompson, David A. Bardwell, Dante Gatteschi, John C. Jeffery, Jon A. McCleverty, Federico Totti, and Michael D. Ward
pp 3447 - 3454; DOI:
10.1021/ic9610086
PDF
Does the Mode of Dioxygen Binding to Dinuclear Copper Complexes Depend on the Spectator Nitrogen-Containing Ligands? An ab Initio Theoretical Study
O. Eisenstein, H. Getlicherman, C. Giessner-Prettre, and J. Maddaluno
pp 3455 - 3460; DOI:
10.1021/ic9515766
PDF
Solution Spectroscopic and Chemical Properties of the Complex Hydride [FeH6]4-
Donald E. Linn, Jr. and Sidney G. Gibbins
pp 3461 - 3465; DOI:
10.1021/ic961300d
PDF
Spin-Orbit Mixing and Nephelauxetic Effects in the Electronic Spectra of Nickel(II)-Encapsulating Complexes Involving Nitrogen and Sulfur Donors
Robert Stranger, Katie L. McMahon, Lawrence R. Gahan, James I. Bruce, and Trevor W. Hambley
pp 3466 - 3475; DOI:
10.1021/ic9614531
PDF
Synthesis and Structural Characterization of P-Functionalized Metallacyclophosphazenes
Michael Witt, Herbert W. Roesky, and Matthias Noltemeyer
pp 3476 - 3479; DOI:
10.1021/ic961284k
PDF
Synthesis and Structure of a New Lithium Amide Ligand Precursor: A Tridentate Nitrogen-Based Donor Set of the Formula N(SiMe2CH2NMe2)2. Synthesis and Structure of the Group 4 Amides MCl3[N(SiMe2CH2NMe2)2] (M = Ti, Zr, Hf)
Michael D. Fryzuk, Vera Hoffman, James E. Kickham, Steven J. Rettig, and Sandro Gambarotta
pp 3480 - 3484; DOI:
10.1021/ic970168u
PDF
Electron Transfer. 134. Reduction of Bound Ruthenium(III) by Indium(I)
Swapan K. Chandra and Edwin S. Gould
pp 3485 - 3487; DOI:
10.1021/ic961393z
PDF
Origin of the Oxygen Atom in C-H Bond Oxidations Catalyzed by a Water-Soluble Metalloporphyrin
Robert J. Balahura, Alexander Sorokin, Jean Bernadou, and Bernard Meunier
pp 3488 - 3492; DOI:
10.1021/ic9700765
PDF
Ion-Pairing Interactions between Co(en)33+ and the 23Na NMR Frequency Shift Reagent TmDOTP5-
Jimin Ren, Charles S. Springer, Jr., and A. Dean Sherry
pp 3493 - 3498; DOI:
10.1021/ic970128q
PDF
Magnetic Properties of Group 8 Metal-Metal-Bonded Porphyrin and Tetraazaporphyrin Dimers
Hilary Arnold Godwin, James P. Collman, Jean-Claude Marchon, Pascale Maldivi, Gordon T. Yee, and Brenda J. Conklin
pp 3499 - 3502; DOI:
10.1021/ic9607853
PDF
Spin Transition in a Manganese(III) Porphyrin Cation Radical, Its Transformation to a Dichloromanganese(IV) Porphyrin, and Chlorination of Hydrocarbons by the Latter
Lilia Kaustov, Merav E. Tal, Alexander I. Shames, and Zeev Gross
pp 3503 - 3511; DOI:
10.1021/ic961207p
PDF
Chemistry of Iron(III) in a Hemin-like Macrocyclic [N4]2- Environment: Relationship between CT Absorption and EPR Spectra
Ernst-G. Jäger and Heike Keutel
pp 3512 - 3519; DOI:
10.1021/ic9702633
PDF
Stereoselective Photoinduced Electron-Transfer Reactions of Zinc Myoglobin with Optically Active Viologens
Keiichi Tsukahara, Chieko Kimura, Junko Kaneko, Kaya Abe, Miho Matsui, and Tomoko Hara
pp 3520 - 3524; DOI:
10.1021/ic970108o
PDF
Selective Metal-Assisted Oxidative Cleavage of a C-N Bond: Synthesis and Characterization of the Mononuclear Iron(III) [Fe(BPG)Cl2] Complex and Its Two [Fe(BPA)Cl3] and [Fe(BPE)Cl3] Derivatives
Marie-Carmen Rodriguez, François Lambert, Irène Morgenstern-Badarau, Michèle Cesario, Jean Guilhem, Bineta Keita, and Louis Nadjo
pp 3525 - 3531; DOI:
10.1021/ic961369l
PDF
Diffusional and Internal Rotation in Single and Linked Trinuclear Bis(carbyne) Cluster Complexes Determined by 13C NMR Relaxation Time Measurements
Frank H. Försterling, Craig E. Barnes, and William D. King
pp 3532 - 3538; DOI:
10.1021/ic961243o
PDF
Single-Crystal 31P NMR and X-ray Diffraction Study of a Molybdenum Phosphine Complex: (5-Methyldibenzophosphole)pentacarbonylmolybdenum(0)
Klaus Eichele, Roderick E. Wasylishen, Kalyani Maitra, John H. Nelson, and James F. Britten
pp 3539 - 3544; DOI:
10.1021/ic970260q
PDF
Volatile Donor-Functionalized Alkoxy Derivatives of Lutetium and Their Structural Characterization
Reiner Anwander, Florian C. Munck, Thomas Priermeier, Wolfgang Scherer, Oliver Runte, and Wolfgang A. Herrmann
pp 3545 - 3552; DOI:
10.1021/ic9700157
PDF
Preparation of Rhenium(I) and Rhenium(II) Amine Dinitrogen Complexes and the Characterization of an Elongated Dihydrogen Species
R. Martin Chin, Joseph Barrera, Raymond H. Dubois, Lisa E. Helberg, Michal Sabat, Tanya Y. Bartucz, Alan J. Lough, Robert H. Morris, and W. Dean Harman
pp 3553 - 3558; DOI:
10.1021/ic9700866
PDF
K8Tl10Zn: A Zintl Phase Containing the Zinc-Centered Thallium Polyanion Tl10Zn8-
Zhen-Chao Dong, Robert W. Henning, and John D. Corbett
pp 3559 - 3561; DOI:
10.1021/ic970309s
PDF
Thioether-Coordinated Nickel Oxidation States. A NiIIIS2N4 Family Incorporating Hexadentate Thioether-Azo-Oxime Chelation
Kausikisankar Pramanik, Soma Karmakar, Suranjan Bhanja Choudhury, and Animesh Chakravorty
pp 3562 - 3564; DOI:
10.1021/ic970009a
PDF
The First Molecule Incorporating [5-NC4H4]- and an Organic C-NC4H4 Group. Synthesis of [Co(7-C4H4N(CH2)3-8-R-7,8-C2B9H9)(5-NC4H4)] (R = CH3, C6H5)
S. Gómez, C. Viñas, M. Lamrani, F. Teixidor, R. Kivekäs, and R. Sillanpää
pp 3565 - 3567; DOI:
10.1021/ic970075c
PDF
Highly Stabilized Low-Spin Iron(III) and Cobalt(III) Complexes of a Tridentate Bis-Amide Ligand 2,6-Bis(N-phenylcarbamoyl)pyridine. Novel Nonmacrocyclic Tetraamido-N Coordination and Two Unusually Short Metal-Pyridine Bonds
Manabendra Ray, Debalina Ghosh, Zahida Shirin, and Rabindranath Mukherjee
pp 3568 - 3572; DOI:
10.1021/ic961118c
PDF
The Strong Acidity and the Process for Deprotonation of (6-Toluene)Fe(H)2(SiCl3)2
Zhengui Yao and Kenneth J. Klabunde
pp 3572 - 3572; DOI:
10.1021/ic970675b
PDF

Issue 17


Zirconium Phosphate Chloride Dimethyl Sulfoxide, a Reactive Precursor of a Large Family of Layered Compounds
Giulio Alberti, Massimiliano Bartocci, Mauro Santarelli, and Riccardo Vivani
pp 3574 - 3575; DOI:
10.1021/ic9704389
PDF
Sr2CuGaO3S, a Rare Example of Square Pyramidal Gallium
W. J. Zhu and and P. H. Hor
pp 3576 - 3577; DOI:
10.1021/ic970322c
PDF
Tuning of Electronic Properties and Reactivity in Four-Coordinate Cobalt(III) Complexes by the Tetraazamacrocyclic Tropocoronand Ligand
Linda H. Doerrer, Maria T. Bautista, and Stephen J. Lippard
pp 3578 - 3579; DOI:
10.1021/ic9703235
PDF
Isolation of the Stereoisomers of [{Ru(bpy)2}2{Os(bpy)2}(-HAT)]6+ (HAT = 1,4,5,8,9,12-Hexaazatriphenylene; bpy = 2,2'-Bipyridine)
Todd J. Rutherford and F. Richard Keene
pp 3580 - 3581; DOI:
10.1021/ic9702532
PDF
Synthesis and Characterization of Nitrido Tc(V) and Re(V) Complexes with Ferrocenedithiocarboxylate {FcCS2 = [Fe(C5H4CS2)(C5H5)]-}
Cristina Bolzati, Licia Uccelli, Adriano Duatti, Mirko Venturini, Christophe Morin, Stephane Chéradame, Fiorenzo Refosco, Franco Ossola, and Francesco Tisato
pp 3582 - 3585; DOI:
10.1021/ic961408t
PDF
Bonding, Hyperfine Interactions, and Lattice Dynamics of Cationic and Neutral Ferrocenyl-Substituted Allylic and Cumulenic Compounds
Rolfe H. Herber, Benno Bildstein, Peter Denifl, and Herwig Schottenberger
pp 3586 - 3594; DOI:
10.1021/ic9614226
PDF
Variable-Valent ReNAr Species. A Family of ReVINAr Amide Complexes and Their ReVNAr Imine Precursors Related by Oxygen Atom Transfer
Bimal Kumar Dirghangi, Mahua Menon, Sangeeta Banerjee, and Animesh Chakravorty
pp 3595 - 3601; DOI:
10.1021/ic9701322
PDF
Apically Linked Small Metallacarborane Clusters. Directed Synthesis and Structural Characterization of 7,7'-[Cp*Co(2,3-Et2C2B4H3]2 and [Cp*Co(2,3-Et2C2B4H3-7)]2X Complexes (X = MeCH, HC=CH, CC)
Michael A. Curtis, Thomas Müller, Volker Beez, Hans Pritzkow, Walter Siebert, and Russell N. Grimes
pp 3602 - 3608; DOI:
10.1021/ic970221e
PDF
A Short Pb···Pb Separation in the Polymeric Compound Bis(pyrrolidinecarbodithioato)lead(II) and a Conformational Pathway Interconversion for the "PbIIS4" Framework
Francesco Caruso, Mei-Ling Chan, and Miriam Rossi
pp 3609 - 3615; DOI:
10.1021/ic970059f
PDF
Titanium Imido Complexes Supported by Amidinate Ligands: Synthesis, Solution Dynamics, and Solid State Structures
Peter J. Stewart, Alexander J. Blake, and Philip Mountford
pp 3616 - 3622; DOI:
10.1021/ic9702274
PDF
Structural Distortions in Six-Coordinate Adducts of Niobium(V) and Tantalum(V)
Janet R. Clark, April L. Pulvirenti, Phillip E. Fanwick, Michaelis Sigalas, Odile Eisenstein, and Ian P. Rothwell
pp 3623 - 3631; DOI:
10.1021/ic970331l
PDF
Quantitative Interpretation of the Goodenough-Kanamori Rules: A Critical Analysis
Hgni Weihe and and Hans U. Güdel
pp 3632 - 3639; DOI:
10.1021/ic961502+
PDF
Oxo Ligand Reactivity in the [ReO2L4]+ Complex of 1-Methylimidazole. Preparation and Crystal Structures of Salts Containing the ReOL43+ Core and Apical CH3O-, BF3O2-, and (CH3O)2PO2- Groups
Suzanne Bélanger and André L. Beauchamp
pp 3640 - 3647; DOI:
10.1021/ic970067w
PDF
Amino Acid Complexes of Metal Carbonyls: Mechanistic Aspects of the CO-Labilizing Ability of Glycinate Ligands in Zero-Valent Chromium and Tungsten Derivatives
Donald J. Darensbourg, Jennifer D. Draper, and Joseph H. Reibenspies
pp 3648 - 3656; DOI:
10.1021/ic961344m
PDF
Modulation of Nucleotide Binding of trans Platinum(II) Complexes by Planar Ligands. A Combined Proton NMR and Molecular Mechanics Study
Ulrich Bierbach and Nicholas Farrell
pp 3657 - 3665; DOI:
10.1021/ic970154o
PDF
Cis Effects in the Cobalt Corrins. 1. Crystal Structures of 10-Chloroaquacobalamin Perchlorate, 10-Chlorocyanocobalamin, and 10-Chloromethylcobalamin
Kenneth L. Brown, Shifa Cheng, Xiang Zou, Jeffrey D. Zubkowski, Edward J. Valente, Leanne Knapton, and Helder M. Marques
pp 3666 - 3675; DOI:
10.1021/ic9615077
PDF
Molecular Recognition Effects in Metal Complex Mediated Double-Strand Cleavage of DNA: Reactivity and Binding Studies with Model Substrates
Charles A. Detmer, III, Filomena V. Pamatong, and Jeffrey R. Bocarsly
pp 3676 - 3682; DOI:
10.1021/ic970199p
PDF
Structural Modeling and Magneto-Structural Correlations for Hydroxo-Bridged Copper(II) Binuclear Complexes
Eliseo Ruiz, Pere Alemany, Santiago Alvarez, and Joan Cano
pp 3683 - 3688; DOI:
10.1021/ic970310r
PDF
Analysis of Exchange Interaction and Electron Delocalization as Intramolecular Determinants of Intermolecular Electron-Transfer Kinetics
E. L. Bominaar, C. Achim, S. A. Borshch, J.-J. Girerd, and E. Münck
pp 3689 - 3701; DOI:
10.1021/ic961298q
PDF
Metal- versus Ligand-Centered Oxidations in Phenolato-Vanadium and -Cobalt Complexes: Characterization of Phenoxyl-Cobalt(III) Species
Achim Sokolowski, Britta Adam, Thomas Weyhermüller, Akihiro Kikuchi, Knut Hildenbrand, Robert Schnepf, Peter Hildebrandt, Eckhard Bill, and Karl Wieghardt
pp 3702 - 3710; DOI:
10.1021/ic970256e
PDF
Electrospray Mass Spectrometry of Thiophenolate-Capped Clusters of CdS, CdSe, and ZnS and of Cadmium and Zinc Thiophenolate Complexes: Observation of Fragmentation and Metal, Chalcogenide, and Ligand Exchange Processes
Thomas Lver, William Henderson, Graham A. Bowmaker, John M. Seakins, and Ralph P. Cooney
pp 3711 - 3723; DOI:
10.1021/ic970203x
PDF
1,2-Diamidolenes, -Diphosphidolenes, and -Dithiolenes as Riders on Sawhorses (L6M2 Units). A Theoretical Interpretation of the Stereochemistries, Residual Bonding Capabilities, and Contrasts to the Behavior of 1,2-Dioxolenes
Carlo Mealli, Andrea Ienco, Adela Anillo, Santiago Garcìa-Granda, and Ricardo Obeso-Rosete
pp 3724 - 3729; DOI:
10.1021/ic961206x
PDF
Intermetallic Hydrides as Zintl Phases: A3TtH2 Compounds (A = Ca, Yb; Tt = Sn, Pb) and Their Structural Relationship to the Corresponding Oxides
Baoquan Huang and John D. Corbett
pp 3730 - 3734; DOI:
10.1021/ic970289u
PDF
Convenient Synthesis and Characterization of the Chiral Complexes cis- and trans-[Ru((SS)-Pripybox)(py)2Cl]PF6 and [Ru((SS)-Pripybox)(bpy)Cl]PF6
Xiao Hua, Maoyu Shang, and A. Graham Lappin
pp 3735 - 3740; DOI:
10.1021/ic970062z
PDF
Bonding of Phosphinidene or Arsenidene Fragments to a Fluorenylidene. Interrelationships between Phosphaalkenes or Arsaalkenes and Donor-Acceptor Complexes
Andreas Decken, Claire J. Carmalt, Jason A. C. Clyburne, and Alan H. Cowley
pp 3741 - 3744; DOI:
10.1021/ic970281k
PDF
(Phosphinoalkyl)silanes. 4.1 Hydrozirconation as a Non-Photochemical Route to (Phosphinopropyl)silanes: Facile Assembly of the Bis(3-(diphenylphosphino)propyl)silyl ("biPSi") Ligand Framework. Access to the Related Poly(3-(dimethylsilyl)propyl)phosphines RnP(CH2CH2CH2SiMe2H)3-n (n = 1, R = Ph; n = 0)
Xiaobing ("Joe") Zhou, Stephen R. Stobart, and Robert A. Gossage
pp 3745 - 3749; DOI:
10.1021/ic970098r
PDF
Synthesis and Structure of the Zintl Phase SrSn3Sb4
Donna T. Chow, Robert McDonald, and Arthur Mar
pp 3750 - 3753; DOI:
10.1021/ic9612212
PDF
Kinetics of Hypobromous Acid Disproportionation
Richard C. Beckwith and Dale W. Margerum
pp 3754 - 3760; DOI:
10.1021/ic970155g
PDF
Iron-Rhodium and Iron-Iridium Mixed-Metal Nitrido-Carbonyl Clusters. Synthesis, Characterization, Redox Properties, and Solid-State Structure of the Octahedral Clusters [Fe5RhN(CO)15]2-, [Fe5IrN(CO)15]2-, and [Fe4Rh2N(CO)15]-. Infrared and Nuclear Magnetic Resonance Spectroscopic Studies on the Interstitial Nitride
Roberto Della Pergola, Arnaldo Cinquantini, Eliano Diana, Luigi Garlaschelli, Franco Laschi, Paola Luzzini, Mario Manassero, Andrea Repossi, Mirella Sansoni, Pier Luigi Stanghellini, and Piero Zanello
pp 3761 - 3771; DOI:
10.1021/ic961451g
PDF
Rapid Inversion at Phosphorus in the [4-(C6H11)3SnP7W(CO)3]2- and [(en)(CO)3W(1,4-P7)M(CO)3]3- Ions Where M = Cr, W
Scott Charles, Janet A. Danis, James C. Fettinger, and Bryan W. Eichhorn
pp 3772 - 3778; DOI:
10.1021/ic961177q
PDF
The Nonexistent Crystals of Macrocyclic Nickel(III). Structure of the Cobalt(III) Complex of 1,4,7-Triazacyclononane-N,N',N''-triacetate
Jan C. A. Boeyens and Magdalena J. van der Merwe
pp 3779 - 3780; DOI:
10.1021/ic960605p
PDF
Effect of Stabilizing Ligands on the Rate of Reaction of CuIL with CCl3CO2- in Aqueous Solutions. 1. L = HOOCCH=CHCOO-
Nadav Navon, Haim Cohen, and Dan Meyerstein
pp 3781 - 3783; DOI:
10.1021/ic9702173
PDF
Synthesis and Molecular Structure of the First Metal Complex of an Analogue of Guanine with PdII-C(8) Binding
Antonio Romerosa, José Suarez-Varela, M. Angel Hidalgo, J. Carlos Avila-Rosón, and Enrique Colacio
pp 3784 - 3786; DOI:
10.1021/ic961334l
PDF
Bis- and Tris(pyrazolyl)hydroborato Ligands with Bulky Triptycyl Substituents: The Synthesis and Structural Characterization of Tl[BpTrip] and Tl[TpTrip]
Tauqir Fillebeen, Tony Hascall, and Gerard Parkin
pp 3787 - 3790; DOI:
10.1021/ic970259r
PDF
Equilibration of syn- and anti(Me)-[Co(Mecyclen)(S-AlaO)]2+ Isomers via One-Ended Dissociation of (S)-Alanine
David A. Buckingham, Charles R. Clark, and Andrew J. Rogers
pp 3791 - 3793; DOI:
10.1021/ic970118p
PDF
Formation of Ruthenium Nitrosyl Complexes: Reactions of Ru(bpy)(CO)2Cl2 and Its Methyl-Substituted Analogues Ru(4,4'-dmbpy)(CO)2Cl2 and Ru(6,6'-dmbpy)(CO)2Cl2 in Oxidizing Acidic Solutions
Pertti Homanen, Matti Haukka, Markku Ahlgrén, and Tapani A. Pakkanen
pp 3794 - 3797; DOI:
10.1021/ic970007q
PDF
Syntheses and Crystal Structures of [K(2.2.2-cryptand)]2[(-O){-O2Si(CH3)2}2(GeSe)2] and [K(2.2.2-cryptand)]2[Sb2Se6]
Donna M. Smith, Chang-Woo Park, and James A. Ibers
pp 3798 - 3800; DOI:
10.1021/ic970137z
PDF
Structure and Reactivity of 1-Isothiocyanatosilatrane: The First Silatrane with a Direct Si-NCS Bond
Suraj P. Narula, Ravi Shankar, Manish Kumar, Raj K. Chadha, and Christoph Janiak
pp 3800 - 3800; DOI:
10.1021/ic9705608
PDF

Issue 18


ACS Award Addresses in Inorganic Chemistry

pp 3801 - 3801; DOI:
10.1021/ic970970w
PDF
The New Octanuclear Europium Cluster Eu8(DMF)13(4-O)(3-OH)12(Se3)(Se4)2(Se5)2 Comprising Oxo, Hydroxo, and Polyselenido Ligands
Christopher G. Pernin and James A. Ibers
pp 3802 - 3803; DOI:
10.1021/ic970379z
PDF
KThSb2Se6 and BaLaBi2Q6 (Q = S, Se) Adopt a New Structure Type Stabilized with Dichalcogenide Groups
Kyoung-Shin Choi, Lykourgos Iordanidis, Konstantinos Chondroudis, and Mercouri G. Kanatzidis
pp 3804 - 3805; DOI:
10.1021/ic970224r
PDF
Synthesis and Characterization of Two New Telluroindates: K6In2Te6·4C2H8N2 and (Ph4P)2In2Te6
Chwanchin Wang and Robert C. Haushalter
pp 3806 - 3807; DOI:
10.1021/ic9702882
PDF
New Fe/Mo/S Clusters with MoFe3S3 Cuboidal Cores Similar to the One in the Fe/Mo Cofactor of Nitrogenase. Synthesis and Structural Characterization of the (C14-cat)MoFe3S3(PEt3)2(CO)6 and (C14-cat)Mo(O)Fe3S3(PEt3)3(CO)5 Clusters
Marni A. Tyson and Dimitri Coucouvanis
pp 3808 - 3809; DOI:
10.1021/ic970761b
PDF
Resistance of the [Re2(-dppm)2]4+ Core (dppm = Ph2PCH2PPh2) to Cleavage by -Acceptor Ligands. Novel Isomers of the [Re2Cl2(-dppm)2(CO)(CNxyl)3]2+ Cation
Wengan Wu, Phillip E. Fanwick, and Richard A. Walton
pp 3810 - 3811; DOI:
10.1021/ic970538e
PDF
Self-Assembly of Infinite Double Helical and Tubular Coordination Polymers from Ag(CF3SO3) and 1,3-Bis(4-pyridyl)propane
Lucia Carlucci, Gianfranco Ciani, Dorothea W. v. Gudenberg, and Davide M. Proserpio
pp 3812 - 3813; DOI:
10.1021/ic970803w
PDF
Mechanism of Water Oxidation Catalyzed by the -Oxo Dimer [(bpy)2(OH2)RuIIIORuIII(OH2)(bpy)2]4+
Chris W. Chronister, Robert A. Binstead, Jinfeng Ni, and Thomas J. Meyer
pp 3814 - 3815; DOI:
10.1021/ic970393b
PDF
Electrides: From 1D Heisenberg Chains to 2D Pseudo-Metals
James L. Dye
pp 3816 - 3826; DOI:
10.1021/ic970551z
PDF
Prediction of the Coordination Scheme of Lanthanide N-Tetrasubstituted Tetraazamacrocycles: An X-ray Crystallography and Molecular Modeling Study
Claude Lecomte, Valérie Dahaoui-Gindrey, Hervé Chollet, Claude Gros, Anil K. Mishra, Frédéric Barbette, Pluton Pullumbi, and Roger Guilard
pp 3827 - 3838; DOI:
10.1021/ic960934h
PDF
Synthesis and Physical Characterization of Novel Heme-Based Model Systems for Photoinitiated Electron Transfer. 1. Complexation of a RuProHis Bifunctional Peptide and Microperoxidase-11
B. Fan, D. L. Fontenot, R. W. Larsen, M. C. Simpson, J. A. Shelnutt, R. Falcon, L. Martinez, S. Niu, S. Zhang, T. Niemczyk, and M. R. Ondrias
pp 3839 - 3846; DOI:
10.1021/ic9700415
PDF
Synthesis and Physical Characterization of Novel Heme-Based Model Systems for Photoinitiated Electron Transfer. 2. Direct Ruthenation of Microperoxidase-11
B. Fan, M. C. Simpson, J. A. Shelnutt, L. Martinez, R. Falcon, T. Buranda, A. J. Pastuszyn, and M. R. Ondrias
pp 3847 - 3853; DOI:
10.1021/ic970040c
PDF
B12 Models with Highly Distorted N4 Equatorial Ligation and a Co-C-N Ring: Structural Assessment of the Steric Influence of Benzimidazole and Imidazole Axial Ligands
Luigi G. Marzilli, Suzette M. Polson, Lory Hansen, Scott J. Moore, and Patricia A. Marzilli
pp 3854 - 3860; DOI:
10.1021/ic970022v
PDF
Synthesis, Crystal Structures, and Catalytic Activity of Dicopper(II) Complexes with Dinucleating Tetraimidazole Ligands [Cu2(RO)(mbipl)](ClO4)2 (R = Me, Et, 2-Pr; Hmbipl = 1,5-Bis[bis[(1-methyl-4-imidazolyl)methyl]amino]-3-pentanol) and [Cu2(MeO)(pbipl)](ClO4)2 (Hpbipl = 1,5-Bis[bis[(1-isopropyl-4-imidazolyl)methyl]amino]-3-pentanol)
Masahito Kodera, Norihisa Terasako, Toshio Kita, Yoshimitsu Tachi, Koji Kano, Mikio Yamazaki, Masayuki Koikawa, and Tadashi Tokii
pp 3861 - 3868; DOI:
10.1021/ic961267v
PDF
Structures and Spectral Properties of Iron(II), Cobalt(II), and Copper(II) Complexes Involving 2-(Dimethylamino)-4(3H)-pteridinone
Yasuhiro Funahashi, Yuichi Hara, Hideki Masuda, and Osamu Yamauchi
pp 3869 - 3875; DOI:
10.1021/ic961430m
PDF
Activation of Thionitrites and Isoamyl Nitrite by Group 8 Metalloporphyrins and the Subsequent Generation of Nitrosyl Thiolates and Alkoxides of Ruthenium and Osmium Porphyrins
Geun-Bae Yi, Li Chen, Masood A. Khan, and George B. Richter-Addo
pp 3876 - 3885; DOI:
10.1021/ic970282c
PDF
Molecular Structures of Ge(tpp)(OAc)2 and In(tpp)(OAc) and Their Implications: Correlations between the 13C NMR Chemical Shift of the Acetato Ligand and Different Types of Carboxylate Coordination in M(por)(OAc)n {por = tpp (5,10,15,20-Tetraphenylporphyrinate), tmpp (5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinate), tpyp (5,10,15,20-Tetrakis(4-pyridyl)porphyrinate); M = Ga, In, Tl, Ge, Sn; n = 1, 2}
Shwu-Juian Lin, Tay-Ning Hong, Jo-Yu Tung, and Jyh-Horung Chen
pp 3886 - 3891; DOI:
10.1021/ic961304i
PDF
Coupled Oxidation of Heme without Pyridine. Formation of Cyano Complexes of Iron Oxophlorin and 5-Oxaporphyrin (Verdoheme) from Octaethylheme
Alan L. Balch, Richard Koerner, Lechosaw Latos-Grayski, Jane E. Lewis, Tamara N. St. Claire, and Edward P. Zovinka
pp 3892 - 3897; DOI:
10.1021/ic970503e
PDF
O-TRENSOX, a New Tripodal Iron Chelator Based on 8-Hydroxyquinoline Subunits: Thermodynamic and Kinetic Studies
Guy Serratrice, Hakim Boukhalfa, Claude Béguin, Paul Baret, Catherine Caris, and Jean-Louis Pierre
pp 3898 - 3910; DOI:
10.1021/ic9608096
PDF
(-Phenoxo)2CoIIMII (M = Mn, Fe, Co) Core Complexes Having a "Co(salen)" Entity Embedded in a Macrocyclic Framework: Synthesis, Structure, and Properties
Hideki Furutachi and Hisashi kawa
pp 3911 - 3918; DOI:
10.1021/ic9700563
PDF
Selective Platination of Biologically Relevant Polyamines. Linear Coordinating Spermidine and Spermine as Amplifying Linkers in Dinuclear Platinum Complexes
Holger Rauter, Roberto Di Domenico, Ernesto Menta, Ambrogio Oliva, Yun Qu, and Nicholas Farrell
pp 3919 - 3927; DOI:
10.1021/ic9701827
PDF
Syntheses and Characterization of Chemically Flexible, Water-Soluble Dithio-Bis(phosphine) Compounds: (HOH2C)2P(CH2)2S(CH2)3S(CH2)2P(CH2OH)2, (HOH2C)2PCH2CH2S(CH2)4SCH2CH2P(CH2OH)2, and (HOH2C)2PCH2CH2CH2S(CH2)3SCH2CH2CH2P(CH2OH)2. Systematic Investigation of the Effect of Chain Length on the Coordination Chemistry of Rhenium(V). X-ray Crystal Structures of [ReO2(HOH2C)2P(CH2)2S(CH2)3S(CH2)2P(CH2OH)2]2(Cl)2, [ReO2(HOH2C)2P(CH2)2S(CH2)4S(CH2)2P-(CH2OH)2]2(ReO4-)2, and [ReO2(HOH2C)2P(CH2)3S(CH2)3S(CH2)3P(CH2OH)2](Cl)
C. Jeffrey Smith, Kattesh V. Katti, Wynn A. Volkert, and Leonard J. Barbour
pp 3928 - 3935; DOI:
10.1021/ic970097z
PDF
Theoretical and Experimental Study of the Gas-Phase Reactions of PFn+ (n = 1, 2) Ions with n-Bases. A Novel Route to Phosphorus Ions Present in Interstellar Clouds
Antonello Filippi, Giorgio Occhiucci, and Maurizio Speranza
pp 3936 - 3946; DOI:
10.1021/ic961394r
PDF
Steric Effects on Dinitrogen Cleavage by Three-Coordinate Molybdenum(III) Complexes: A Molecular Mechanics Study
Jutta Hahn, Clark R. Landis, Vladimir A. Nasluzov, Konstantin M. Neyman, and Notker Rösch
pp 3947 - 3951; DOI:
10.1021/ic961466e
PDF
Luminescence Properties of Salts of the [Pt(trpy)Cl]+ and [Pt(trpy)(MeCN)]2+ Chromophores: Crystal Structure of [Pt(trpy)(MeCN)](SbF6)2
Riaan Büchner, John S. Field, Raymond J. Haines, Corey T. Cunningham, and David R. McMillin
pp 3952 - 3956; DOI:
10.1021/ic961068b
PDF
Determination of Relaxation Paths in the Manifold of Excited States of Pt(2-thpy)2 and [Ru(bpy)3]2+ by Time-Resolved Excitation and Emission
Josef Schmidt, Johann Strasser, and Hartmut Yersin
pp 3957 - 3965; DOI:
10.1021/ic960565p
PDF
Density Functional Study of the Valence-Tautomeric Interconversion Low-Spin [CoIII(SQ)(Cat)(phen)] High-Spin [CoII(SQ)2(phen)]
David M. Adams, Louis Noodleman, and David N. Hendrickson
pp 3966 - 3984; DOI:
10.1021/ic9611812
PDF
Dicopper(II) Complexes Bridged by Single N-N Bonds. Magnetic Exchange Dependence on the Rotation Angle between the Magnetic Planes
Zhiqiang Xu, Laurence K. Thompson, and David O. Miller
pp 3985 - 3995; DOI:
10.1021/ic970235k
PDF
Octanuclearity in Copper(II) Chemistry: Preparation, Characterization, and Magnetochemistry of [Cu8(dpk·OH)8(O2CCH3)4](ClO4)4·9H2O (dpk·H2O = the Hydrated, gem-Diol Form of Di-2-pyridyl Ketone)
Vasilis Tangoulis, Catherine P. Raptopoulou, Aris Terzis, Sofia Paschalidou, Spyros P. Perlepes, and Evangelos G. Bakalbassis
pp 3996 - 4006; DOI:
10.1021/ic961137m
PDF
A Twist on the Copper Center in the Crystal Structure of [Cu(dnpp)2]PF6 and the Charge-Transfer Excited State? (dnpp = 2,9-Dineopentyl-1,10-phenanthroline)
Michèle K. Eggleston, Phillip E. Fanwick, Alexander J. Pallenberg, and David R. McMillin
pp 4007 - 4010; DOI:
10.1021/ic970135e
PDF
Synthesis, Characterization, and Structure of Mixed Chloride-Selenide Tungsten Cluster Complexes
Xiaobing Xie and Robert E. McCarley
pp 4011 - 4016; DOI:
10.1021/ic970038l
PDF
Cramping a Molecular Rollerball. Investigation of the Effect of Pressure on the Mössbauer Spectra of Three Cyclopentadienyl(arene)iron(II) Salts
Jack Silver, John R. Miller, Dominic A. Davies, and Catherine A. McCammon
pp 4017 - 4023; DOI:
10.1021/ic970419z
PDF
Vanadium Complexes in a Lewis Basic Room-Temperature 1-Ethyl-3-methyl-1H-imidazolium Chloride/Aluminum Chloride Molten Salt
Kevin R. Hanz and Thomas L. Riechel
pp 4024 - 4028; DOI:
10.1021/ic970201c
PDF
Molecular Modeling of Vanadium Peroxides
Thomas R. Cundari, Laura L. Sisterhen, and Chryssanthi Stylianopoulos
pp 4029 - 4034; DOI:
10.1021/ic970266f
PDF
Synthesis and Characterization of a Novel Class of Dicopper(I) Bis(carboxylate)-Bridged Complexes
Daniel D. LeCloux and Stephen J. Lippard
pp 4035 - 4046; DOI:
10.1021/ic970302a
PDF
Synthesis and Structural Characterization of Compounds Containing the [Zr6Cl18H5]3- Cluster Anion. Determination of the Number of Cluster Hydrogen Atoms
Linfeng Chen, F. Albert Cotton, and William A. Wojtczak
pp 4047 - 4054; DOI:
10.1021/ic960173i
PDF
Synthesis of and NMR T1 Relaxation in the Bimetallic Trihydride Complexes Cp2TaH2(-H)M(CO)5 (M = Cr, Mo, W)
Vladimir I. Bakhmutov, Evgenii V. Vorontsov, Gilles Boni, and Claude Moise
pp 4055 - 4059; DOI:
10.1021/ic9607346
PDF
Bimetallic Borate Derivatives of the Salen Ligands
Pingrong Wei and David A. Atwood
pp 4060 - 4065; DOI:
10.1021/ic970089i
PDF
Comparative Isotropic Shifts, Redox Potentials, and Ligand Binding Propensities of [1:3] Site-Differentiated Cubane-Type [Fe4Q4]2+ Clusters (Q = S, Se)
Chaoyin Zhou and R. H. Holm
pp 4066 - 4077; DOI:
10.1021/ic970254u
PDF
The closo-Ge52- Anion: Synthesis, Crystal Structure, and Raman Spectrum of (2,2,2-crypt-K+)2Ge52-·THF
Janette Campbell and Gary J. Schrobilgen
pp 4078 - 4081; DOI:
10.1021/ic970191f
PDF
Synthesis and Characterization of Gallium-Containing Silsesquioxanes
Frank J. Feher, Theodore A. Budzichowski, and Joseph W. Ziller
pp 4082 - 4086; DOI:
10.1021/ic9703033
PDF
Synthesis and Crystal Structures of Lithium Salts of New Iminophosphide/Phosphinoamide Anions
Norbert Poetschke, Martin Nieger, Masood A. Khan, Edgar Niecke, and Michael T. Ashby
pp 4087 - 4093; DOI:
10.1021/ic9700720
PDF
Synthesis and Structure of Alkoxy- and (Aryloxy)alanes. Observation of a Ring-Opening Reaction Involving Tetrahydrofuran
John P. Campbell and Wayne L. Gladfelter
pp 4094 - 4098; DOI:
10.1021/ic970171d
PDF
Designing Copper(I) Photosensitizers for the Norbornadiene-Quadricyclane Transformation Using Visible Light: An Improved Solar Energy Storage System
Federico Franceschi, Massimo Guardigli, Euro Solari, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli
pp 4099 - 4107; DOI:
10.1021/ic9706156
PDF
Tetramethyl Carboxylic Acids Derived from o-Phenylenediamines as Sequestering Agents for Iron(III): Thermodynamic Studies. X-ray Crystal Structure of Sodium Aqua(4-chloro-1,2-phenylenediamine-N,N,N',N'-tetraacetato)ferrate(III)-Water (1/1.5)
Joaquín Sanchiz, Sixto Domínguez, Alfredo Mederos, Felipe Brito, and Juan Manuel Arrieta
pp 4108 - 4114; DOI:
10.1021/ic9700617
PDF
Kinetics of [FeII(edta)] Oxidation by Molecular Oxygen Revisited. New Evidence for a Multistep Mechanism
Sabine Seibig and Rudi van Eldik
pp 4115 - 4120; DOI:
10.1021/ic970158t
PDF
Selective Blocking of Coordination Modes in 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol: Enforced Formation of a Low-Spin Iron(III) Hexaamine Complex
Kaspar Hegetschweiler, Michael Weber, Volker Huch, Michael Veith, Helmut W. Schmalle, Anthony Linden, Rodney J. Geue, Peter Osvath, Alan M. Sargeson, Anthony C. Willis, and Werner Angst
pp 4121 - 4127; DOI:
10.1021/ic970291l
PDF
NMR Studies of the Lanthanide(III) Complexes of 1,4,7,10-Tetraazacyclododecane-1,4,7,10-tetrakis(methanephosphonic acid mono(2',2',2'-trifluoroethyl) ester)
Won D. Kim, Garry E. Kiefer, Jurriaan Huskens, and A. Dean Sherry
pp 4128 - 4134; DOI:
10.1021/ic970169m
PDF
An Alternative Synthesis of Cyclotrigallazane, [H2GaNH2]3, a Precursor to Nanocrystalline, Phase-Inhomogeneous Gallium Nitride, GaN
Jerzy F. Janik and and Richard L. Wells
pp 4135 - 4137; DOI:
10.1021/ic970296i
PDF
[5,10,15,20-Tetrakis(4-((pentaammineruthenio)- cyano)phenyl)porphyrinato]cobalt(II) Immobilized on Graphite Electrodes Catalyzes the Electroreduction of O2 to H2O, but the Corresponding 4-Cyano-2,6-dimethylphenyl Derivative Catalyzes the Reduction Only to H2O2
Beat Steiger and Fred C. Anson
pp 4138 - 4140; DOI:
10.1021/ic970275o
PDF
Synthesis and Spectroscopic and Structural Characterization of Two Novel Dilutetium Cofacial Porphyrin Dimers
Mohammed Lachkar, Alain Tabard, Stéphane Brandès, Roger Guilard, Aziz Atmani, André De Cian, Jean Fischer, and Raymond Weiss
pp 4141 - 4146; DOI:
10.1021/ic960696q
PDF

Issue 19


Chain-Structured cis-Hydroxoaquachromium(III) Complexes and Their Magnetic Properties
Michael Ardon, Avi Bino, Kirsten Michelsen, Erik Pedersen, and Robert C. Thompson
pp 4147 - 4150; DOI:
10.1021/ic9701221
PDF
Bonding Forces in Short Hydrogen Bonds. Crystal Structure of PdII(dpgH)2
Ronald F. See, Christopher J. Curtis, Kevin W. McConnell, Seethraman Santhanam, William M. Strub, and Joseph W. Ziller
pp 4151 - 4155; DOI:
10.1021/ic9701266
PDF
Reactivity of Peroxynitric Acid (O2NOOH): A Pulse Radiolysis Study
Sara Goldstein and and Gidon Czapski
pp 4156 - 4162; DOI:
10.1021/ic961186z
PDF
Electrically Conducting Materials Based On -Tetrathiooxalato-Bridged Bimetallic Ni(II) Anionic Complexes
Anthony E. Pullen, Stephan Zeltner, Ruth-Maria Olk, Eberhard Hoyer, Khalil A. Abboud, and John R. Reynolds
pp 4163 - 4171; DOI:
10.1021/ic9701219
PDF
Preparation and Crystal Structure of Ruthenium Metaphosphate Ru(PO3)3 with an 8-fold Superstructure. Analysis of Structural Frustration with a Simple Model
Hideo Imoto, Hiroshi Fukuoka, Shigenori Tsunesawa, Hisaya Horiuchi, Takao Amemiya, and Noboru Koga
pp 4172 - 4181; DOI:
10.1021/ic9701773
PDF
Conversion of Dinuclear, Diamagnetic [MoV2O3(NCS)8]4- into Mononuclear, Paramagnetic [MoVO(NCS)5]2- through Photolytic Ligand Redistribution
Patricia C. Secrest, Steven J. Geib, and N. John Cooper
pp 4182 - 4186; DOI:
10.1021/ic9607898
PDF
Chiral Inversion around a Seven-Coordinated Cobalt Center Induced by an Interaction between Sugars and Sulfate Anions
Shigenobu Yano, Masako Nakagoshi, Akemi Teratani, Masako Kato, Tomoko Onaka, Masayasu Iida, Tomoaki Tanase, Yasuhiro Yamamoto, Hidehiro Uekusa, and Yuji Ohashi
pp 4187 - 4194; DOI:
10.1021/ic970010+
PDF
Platinum(II) Complexes with Diglycine: X-ray Crystal Structure, 15N NMR Spectra, and Growth-Inhibitory Activity against Mouse Meth A Solid Tumor in Vivo
Noriharu Nagao, Takao Kobayashi, Toshio Takayama, Yoshio Koike, Yukie Ono, Toshihiko Watanabe, Takeshi Mikami, Masuko Suzuki, Tatuji Matumoto, and Masatoshi Watabe
pp 4195 - 4201; DOI:
10.1021/ic9615180
PDF
Syntheses, Spectroscopy, Structures, and Reactivity of Neutral Cubic Group 13 Molecular Phosphonates
Mrinalini G. Walawalkar, Ramaswamy Murugavel, Herbert W. Roesky, and Hans-Georg Schmidt
pp 4202 - 4207; DOI:
10.1021/ic970346j
PDF
Multiiron Polyoxoanions. Syntheses, Characterization, X-ray Crystal Structures, and Catalysis of H2O2-Based Hydrocarbon Oxidations by [FeIII4(H2O)2(P2W15O56)2]12-
Xuan Zhang, Qin Chen, Dean C. Duncan, Charles F. Campana, and Craig L. Hill
pp 4208 - 4215; DOI:
10.1021/ic970690g
PDF
Synthesis of [Li(THF)4]2[Th(5-C2B9H11)2X2] (X = Cl, Br, I): The First Dicarbollide Complexes of Thorium
Daniel Rabinovich, Rebecca M. Chamberlin, Brian L. Scott, Jon B. Nielsen, and Kent D. Abney
pp 4216 - 4217; DOI:
10.1021/ic970198x
PDF
Water-Soluble Organometallic Compounds. 6.1 Synthesis, Spectral Properties, and Crystal Structures of Complexes of 1,3,5-Triaza-7-phosphaadamantane with Group 10 Metals
Donald J. Darensbourg, Tara J. Decuir, Nicole White Stafford, Jeffrey B. Robertson, Jennifer D. Draper, Joseph H. Reibenspies, Agnes Kathó, and Ferenc Joó
pp 4218 - 4226; DOI:
10.1021/ic970238x
PDF
Systematic Electrochemical Synthesis of Reduced Forms of the -[S2Mo18O62]4-Anion
David M. Way, John B. Cooper, Maruse Sadek, Truc Vu, Peter J. Mahon, Alan M. Bond, Robert T. C. Brownlee, and Anthony G. Wedd
pp 4227 - 4233; DOI:
10.1021/ic970592v
PDF
Synthesis and Properties of Heterocyclic Substituted 1,2-Enedithiolates of Nickel, Palladium, and Platinum
Sharada P. Kaiwar, John K. Hsu, Louise M. Liable-Sands, Arnold L. Rheingold, and Robert S. Pilato
pp 4234 - 4240; DOI:
10.1021/ic970194s
PDF
Reactions of H2X=XH2 and H2X=O Double Bonds (X = Si, Ge, Sn, Pb): Are 1,3-Dioxa-2,4-dimetaletanes Unusual Molecules?
Jürgen Kapp, Milan Remko, and Paul v. R. Schleyer
pp 4241 - 4246; DOI:
10.1021/ic961519s
PDF
Photoinduced Electron Transfer in Ruthenium(II)-Rhodium(III) Terpyridine Dyads
M. T. Indelli and, F. Scandola, L. Flamigni, J.-P. Collin, J.-P. Sauvage, and A. Sour
pp 4247 - 4250; DOI:
10.1021/ic9702577
PDF
A Nonempirical Approach to Ground-State Jahn-Teller Distortion: Case Study of VCl4
Raf Bruyndonckx, Claude Daul, P. T. Manoharan, and Eric Deiss
pp 4251 - 4256; DOI:
10.1021/ic961220+
PDF
Preparation of Mercury(II) Complexes of Tris[(2-pyridyl)methyl]amine and Characterization by X-ray Crystallography and NMR Spectroscopy
Deborah C. Bebout, David E. Ehmann, Jonathan C. Trinidad, Kathleen K. Crahan, Margaret E. Kastner, and Damon A. Parrish
pp 4257 - 4264; DOI:
10.1021/ic9702779
PDF
Electrochemical Synthesis and Crystallization of a Novel Tetraarylaurate Anion: Synthesis, Structure, and Physical Properties of (BEDT-TTF)Au(C6Cl5)4
John A. Schlueter, Urs Geiser, H. Hau Wang, Michael L. VanZile, Shannon B. Fox, Jack M. Williams, Antonio Laguna, Mariano Laguna, Dieter Naumann, and Thomas Roy
pp 4265 - 4269; DOI:
10.1021/ic970274w
PDF
Systematic Study of New Rare Earth Element-Iron-Antimony Skutterudites Synthesized Using Multilayer Precursors
Marc D. Hornbostel, Edward J. Hyer, Julie H. Edvalson, and David C. Johnson
pp 4270 - 4274; DOI:
10.1021/ic9702375
PDF
-Octamolybdate as a Building Block. Synthesis and Structural Characterization of Rare Earth-Molybdate Adducts
A. Kitamura, T. Ozeki, and A. Yagasaki
pp 4275 - 4279; DOI:
10.1021/ic970335q
PDF
Tetramethylammonium Difluorobromate(I), (CH3)4N+BrF2-
Rolf Minkwitz and, Raimund Bröchler, and Ralf Ludwig
pp 4280 - 4283; DOI:
10.1021/ic961283s
PDF
Experimental Evidence of a Ferromagnetic Ground State (S = 9/2) for a Dinuclear Gd(III)-Ni(II) Complex
J.-P. Costes, F. Dahan, A. Dupuis, and J.-P. Laurent
pp 4284 - 4286; DOI:
10.1021/ic970720f
PDF
A Novel Compound in the Lanthanide(III) DOTA Series. X-ray Crystal and Molecular Structure of the Complex Na[La(DOTA)La(HDOTA)]·10H2O
Silvio Aime, Alessandro Barge, Franco Benetollo, Gabriella Bombieri, Mauro Botta, and Fulvio Uggeri
pp 4287 - 4289; DOI:
10.1021/ic9704501
PDF
Synthesis and Structures of N-Alkylated Azatitanatranes
Martin Schubart, Liam O'Dwyer, Lutz H. Gade, Wan-Sheung Li, and Mary McPartlin
pp 4290 - 4290; DOI:
10.1021/ic970606x
PDF

Issue 20


A Molecular Railroad with Large Pores: Synthesis and Structure of Ni(4,4'-bpy)2.5(H2O)2(ClO4)2·1.5(4,4'-bpy)·2H2O
O. M. Yaghi, Hailian Li, and Thomas L. Groy
pp 4292 - 4293; DOI:
10.1021/ic970423a
PDF
Electroreduction of O2 to H2O at Unusually Positive Potentials Catalyzed by the Simplest of the Cobalt Porphyrins
Chunnian Shi, Beat Steiger, Makoto Yuasa, and Fred C. Anson
pp 4294 - 4295; DOI:
10.1021/ic970516s
PDF
Formation of a Novel -Tetrasulfido-Bridged Dimer of a Dinuclear Platinum Complex
Keisuke Umakoshi and and Yoichi Sasaki
pp 4296 - 4297; DOI:
10.1021/ic970848x
PDF
Synthesis, Characterization, and Bonding of Heteroatomic Clusters: Na13Cd20E7 (E = Pb, Sn), a Further Example of a Structure Containing Empty Icosahedra without an Element of Group 13
Evgeny Todorov and Slavi C. Sevov
pp 4298 - 4302; DOI:
10.1021/ic970588j
PDF
Synthesis, Structure, and Magnetic Properties of Low-Valent Triangulo Cobalt-Hydride Clusters [XCo3(-CO)3(PMe3)6]
Hans-Friedrich Klein, Michael Mager, Andreas Schmidt, Martina Hüber, Wolfgang Haase, Ulrich Flörke and, Hans-Jürgen Haupt, and Roman Boca
pp 4303 - 4306; DOI:
10.1021/ic970431r
PDF
The Phase Co1-xNixSn2: Structural Variations Based on the Stacking of Two Different Planar Nets
Ulrich Häussermann, Angel R. Landa-Cánovas, and Sven Lidin
pp 4307 - 4315; DOI:
10.1021/ic9703134
PDF
Na5Sn13: A New Zintl Phase with a Complex Network Structure Constructed from Tin Pentagons
J. T. Vaughey and John D. Corbett
pp 4316 - 4320; DOI:
10.1021/ic9703181
PDF
Dinuclear Paddle-Wheel Copper(II) Carboxylates in the Catalytic Oxidation of Carboxylic Acids. Unusual Polymeric Chains Found in the Single-Crystal X-ray Structures of [Tetrakis(-1-phenylcyclopropane-1-carboxylato-O,O')bis(ethanol-O)dicopper(II)] and catena-Poly[[bis(-diphenylacetato-O:O')dicopper](3-diphenylacetato-1-O:2-O':1'-O')(3-diphenylacetato-1-O:2-O':2'-O')]
Frank P. W. Agterberg, Hajo A. J. Provó Kluit, Willem L. Driessen, Henk Oevering, Wim Buijs, Miles T. Lakin, Anthony L. Spek, and Jan Reedijk
pp 4321 - 4328; DOI:
10.1021/ic9614733
PDF
Copper(II) Complexes of N,N'-Bis((2-substituted-imidazol-4-yl)methylene)-3,3'-diaminodi- propylamine (2-Substituent = H, Me): and Enantiomorphs of the Protonated Complex and Helical Structure of the Deprotonated Complex Formed by Hydrogen Bonds
Hitoshi Miyasaka, Shingo Okamura, Toshio Nakashima, and Naohide Matsumoto
pp 4329 - 4335; DOI:
10.1021/ic970425v
PDF
X-ray Structure and Variable Temperature Magnetic Properties of a Zigzag (Cu-Cl)n Chain
C. Robert Lucas and Shuang Liu
pp 4336 - 4340; DOI:
10.1021/ic961242w
PDF
Synthesis, Crystal Structure, Magnetic Properties, and EPR of Cu(bp3ca)Br2·H2O (bp3ca = 2,2'-Bipyridine-3,3'-dicarboxylic Acid). Ferromagnetic Interactions via Unsymmetrical Bromide Bridges
Sindhu Menon, M. V. Rajasekharan, and J.-P. Tuchagues
pp 4341 - 4346; DOI:
10.1021/ic9615234
PDF
The Valence-Detrapping Phase Transition in a Crystal of the Mixed-Valence Trinuclear Iron Cyanoacetate Complex [Fe3O(O2CCH2CN)6(H2O)3]
Tadahiro Nakamoto, Minoru Hanaya, Motomi Katada, Kazutoyo Endo, Susumu Kitagawa, and Hirotoshi Sano
pp 4347 - 4359; DOI:
10.1021/ic961438w
PDF
Synthesis of Volatile Cyclic Silylamines and the Molecular Structures of Two 1-Aza-2,5-disilacyclopentane Derivatives
Norbert W. Mitzel, Hubert Schmidbaur, David W. H. Rankin, Bruce A. Smart, Matthias Hofmann, and Paul von Ragué Schleyer
pp 4360 - 4368; DOI:
10.1021/ic9703179
PDF
Synthesis of the Tris(trimethylphosphine)tetrahydrotriboron(1+) Cation
Mitsuaki Kameda and Goji Kodama
pp 4369 - 4371; DOI:
10.1021/ic9705195
PDF
-Benzene in a Heterobimetallic Fluoroalkoxide: CH···FC Hydrogen Bonding?
Daniel J. Teff, John C. Huffman, and Kenneth G. Caulton
pp 4372 - 4380; DOI:
10.1021/ic970633n
PDF
Multiiron Polyoxoanions. Synthesis, Characterization, X-ray Crystal Structure, and Catalytic H2O2-Based Alkene Oxidation by [(n-C4H9)4N]6[FeIII4(H2O)2(PW9O34)2]
Xuan Zhang, Qin Chen, Dean C. Duncan, Rene J. Lachicotte, and Craig L. Hill
pp 4381 - 4386; DOI:
10.1021/ic970391r
PDF
Halide Ion Addition to Bismuth-Containing Iron Carbonyl Compounds: Synthesis and Characterization of the Two Bridged-Butterfly Cluster Compounds [Et4N][(-H)Fe2(CO)6Bi2{-Fe(CO)4}] and [{PhCH2NMe3}{(-H)Fe2(CO)6Bi2(-Cl)2}] and Stabilization of Reduced-Hypervalent Bismuth Centers by Coordination to a Metal Center in [PhCH2NMe3]3[Bi3Cl4(-Cl)4{Fe(CO)3}]
Jeffrey R. Eveland, Jean-Yves Saillard, and Kenton H. Whitmire
pp 4387 - 4396; DOI:
10.1021/ic9609721
PDF
Synthesis and Properties of IrRe2(-H)2(CO)9(5-C9H7)
Matthew C. Comstock, Teresa Prussak-Wieckowska, Scott R. Wilson, and John R. Shapley
pp 4397 - 4404; DOI:
10.1021/ic960990i
PDF
Synthesis of a ,2-Disulfide-Bridged Hexanuclear RuII-Na Cluster Formed from the Reductive Coupling of a ,1-Disulfide-Bridged Dinuclear RuIII Complex
Kazuko Matsumoto and and Yoichi Sano
pp 4405 - 4407; DOI:
10.1021/ic961015u
PDF
Reactions of Triosmium Carbonyl Clusters with Thionylaniline. Crystal Structures of Os3(CO)9(3-NPh)(3-S), Os3(CO)9(3-2-(PhN)2SO)(3-S), and Os3(CO)8(NCMe)(3-NPh)(3-S)
Wen-Yann Yeh, Charlotte L. Stern, and Duward F. Shriver
pp 4408 - 4414; DOI:
10.1021/ic961153j
PDF
Structural Diversity in the Reaction of Mono- and Disubstituted Pyrazoles with Titanium Tetrachloride. Importance of Hydrogen Bonding and Trends in cis/trans Geometry of Binary Adducts with Unidentate Ligands
Ilia A. Guzei and Charles H. Winter
pp 4415 - 4420; DOI:
10.1021/ic961468z
PDF
Syntheses and X-ray Structures of a Series of Chalcogen-Containing Manganese Carbonylates [E2Mn3(CO)9]-, [E8C2Mn2(CO)6]2-, and [E2Mn4(CO)12]2- (E = Se, S)
Kuo-Chih Huang, Yi-Chou Tsai, Gene-Hsiang Lee, Shie-Ming Peng, and Minghuey Shieh
pp 4421 - 4425; DOI:
10.1021/ic961482b
PDF
Synthesis, Molecular Structure, and Reactivity of the Tetranuclear Complex [NBu4]2[Pd4(-PPh2)2(-Cl)4(C6F5)4]. Molecular Structure of [Pd2(-PPh2)(C6F5)2(bipy)2]ClO4·C6H14
Ester Alonso, Juan Forniés, Consuelo Fortuño, Antonio Martín, Georgina M. Rosair, and Alan J. Welch
pp 4426 - 4431; DOI:
10.1021/ic9701930
PDF
Oxidation Reactions of Dithiocarbamate Complexes of Ruthenium(II)
Wa-Hung Leung, Joyce L. C. Chim, Hongwei Hou, Tom S. M. Hun, Ian D. Williams, and Wing-Tak Wong
pp 4432 - 4437; DOI:
10.1021/ic970053q
PDF
Gold(I) Complexes with N-Donor Ligands. 2.1 Reactions of Ammonium Salts with [Au(acac-C2)(PR3)] To Give [Au(NH3)L]+, [(AuL)2(2-NH2)]+, [(AuL)4(4-N)]+, or [(AuL)3(3-O)]+. A New and Facile Synthesis of [Au(NH3)2]+ Salts. Crystal Structure of [{AuP(C6H4OMe-4)3}3(3-O)]CF3SO3
José Vicente, María-Teresa Chicote, Rita Guerrero, Peter G. Jones, and M. Carmen Ramírez de Arellano
pp 4438 - 4443; DOI:
10.1021/ic970225j
PDF
Aqua Complexes of [(2-Methoxyethyl)cyclopentadienyl]zirconium Trichloride
Adolphus A. H. van der Zeijden, Chris Mattheis, Roland Fröhlich and, and Frank Zippel
pp 4444 - 4450; DOI:
10.1021/ic970245l
PDF
Monomeric, Four-Coordinate Group 4 Metal Complexes with Chelating Bis(tert-butylamido)cyclodisilazane Ligands: Syntheses and Molecular Structures of {(MeSiNtBu)2(NtBu)2}MCl2 and {(MeSiNtBu)2(NtBu)2}MMe2, M = Zr, Hf
Luke Grocholl, Volker Huch, Lothar Stahl, Richard J. Staples, Phaedra Steinhart, and Alison Johnson
pp 4451 - 4457; DOI:
10.1021/ic970287+
PDF
Hydrogen Bonding of CHCl3 to Coordinated Nitric Oxide in a Binuclear Metallomacrocycle and the Crystal Structures of anti-[Mo(NO){HB(3,5-Me2C3HN2)3}(2,7-O2C10H6)]2·2CHCl3·CH2Cl2, syn-[Mo(NO){HB(3,5-Me2C3HN2)3}(2,7-O2C10H6)]2·0.67CHCl3·2.7H2O, and syn-[Mo(NO){HB(3,5-Me2C3HN2)3}(2,7-O2C10H6)]2·3(CH3)2CO
Ferida S. McQuillan, Hongli Chen, Thomas A. Hamor, Christopher J. Jones, and Keith Paxton
pp 4458 - 4464; DOI:
10.1021/ic9706820
PDF
Stereoisomers of Mono-, Di-, and Triruthenium(II) Complexes Containing the Bridging Ligand 1,4,5,8,9,12-Hexaazatriphenylene and Studies of Their Photophysical Properties
Todd J. Rutherford, Olivier Van Gijte, Andrée Kirsch-De Mesmaeker, and F. Richard Keene
pp 4465 - 4474; DOI:
10.1021/ic961374p
PDF
Cyclic Voltammetric Evaluation of Rate Constants for Conformational Transitions Accompanying Electron Transfer. Effect of Varying Structural Constraints in Copper(II/I) Complexes with Dicyclohexanediyl-Substituted Macrocyclic Tetrathiaethers
Nicole M. Villeneuve, Ronald R. Schroeder, L. A. Ochrymowycz, and D. B. Rorabacher
pp 4475 - 4483; DOI:
10.1021/ic960866z
PDF
Electron-Transfer Kinetics and Thermodynamic Characterization of Copper(II/I) Complexes with Acyclic Tetrathiaethers in Aqueous Solution
Brian C. Dunn, Prabodha Wijetunge, James R. Vyvyan, Turner A. Howard, Andrew J. Grall, L. A. Ochrymowycz, and D. B. Rorabacher
pp 4484 - 4489; DOI:
10.1021/ic970441s
PDF
Complexation of Copper(II) with Carbonate Ligands in Aqueous Solution: A CW and Pulse EPR Study
P. M. Schosseler, B. Wehrli, and A. Schweiger
pp 4490 - 4499; DOI:
10.1021/ic9703383
PDF
Modeling of the Redox Properties of (Hexaamine)cobalt(III/II) Couples
Peter Comba and Achim F. Sickmüller
pp 4500 - 4507; DOI:
10.1021/ic9701625
PDF
Metal Complexes of 1-Oxa-4,7-dithiacyclononane
C. Robert Lucas, Weimin Liang, David O. Miller, and John N. Bridson
pp 4508 - 4513; DOI:
10.1021/ic961536h
PDF
Synthesis, Structure, and Reactivity of Arylchlorobis(dialkyl sulfide)platinum(II) Complexes
Ola F. Wendt, Åke Oskarsson, Johann G. Leipoldt, and Lars I. Elding
pp 4514 - 4519; DOI:
10.1021/ic970189o
PDF
Kinetic Studies on the Redox Interconversion of GOasesemi and GOaseox Forms of Galactose Oxidase with Inorganic Complexes as Redox Partners
Colin G. Saysell, Christopher D. Borman, Andrew J. Baron, Michael J. McPherson, and A. Geoffrey Sykes
pp 4520 - 4525; DOI:
10.1021/ic970255m
PDF
(-Oxo)bis(-carboxylato)bis(2,2'-bipyridyl)bis(X)diiron(III) Complexes, X = NCS-, NCSe-, and N3-: Synthetic Models of Pseudohalide Derivatives of Carboxylate-Bridged Diiron Proteins
Tadashi J. Mizoguchi and Stephen J. Lippard
pp 4526 - 4533; DOI:
10.1021/ic970397g
PDF
A New Class of Supramolecular, Mixed-Metal DNA-Binding Agents: The Interaction of RuII,PtII and OsII,PtII Bimetallic Complexes with DNA
Matthew Milkevitch, Hannah Storrie, Eric Brauns, Karen J. Brewer, and Brenda W. Shirley
pp 4534 - 4538; DOI:
10.1021/ic970054i
PDF
Synthesis and Characterization of the Benzoylformato Ferrous Complexes with the Hindered Tris(pyrazolyl)borate Ligand as a Structural Model for Mononuclear Non-Heme Iron Enzymes
Shiro Hikichi, Tamako Ogihara, Kiyoshi Fujisawa, Nobumasa Kitajima, Munetaka Akita, and Yoshihiko Moro-oka
pp 4539 - 4547; DOI:
10.1021/ic960903m
PDF
Cyclic Metalloporphyrin Trimers: 1H NMR Identification of Trimeric Heterometallic (Iron(III), Gallium(III), Manganese(III)) 2-Hydroxy-5,10,15,20-tetraphenylporphyrins and X-ray Crystal Structure of the Iron(III) 2-Hydroxy-5,10,15,20-tetra-p-tolylporphyrin Trimer
Jacek Wojaczyski, Lechosaw Latos-Grayski, Marilyn M. Olmstead, and Alan L. Balch
pp 4548 - 4554; DOI:
10.1021/ic970214q
PDF
Compound I and Compound II Analogues from Porpholactones
K. Jayaraj, A. Gold, R. N. Austin, L. M. Ball, J. Terner, D. Mandon, R. Weiss, J. Fischer, A. DeCian, E. Bill, M. Müther, V. Schünemann, and A. X. Trautwein
pp 4555 - 4566; DOI:
10.1021/ic970597s
PDF
Paramagnetic NMR Spectroscopy of Cobalt(II) and Copper(II) Derivatives of Pseudomonas aeruginosa His46Asp Azurin
A. J. Vila, B. E. Ramirez, A. J. Di Bilio, T. J. Mizoguchi, J. H. Richards, and H. B. Gray
pp 4567 - 4570; DOI:
10.1021/ic9703282
PDF
Characterization of the Self-Condensation Equilibrium of [Fe4S4(SH)4]2-: Spectroscopic Identification of a Unique Sulfido-Bridged Acyclic Tricubane Cluster
H. R. Hoveyda and R. H. Holm
pp 4571 - 4578; DOI:
10.1021/ic970412h
PDF
Fixation of CO2 by Zinc(II) Chelates in Alcoholic Medium. X-ray Structures of {[Zn(cyclen)]3(3-CO3)}(ClO4)4 and [Zn(cyclen)EtOH](ClO4)2
Antje Schrodt, Anton Neubrand, and Rudi van Eldik
pp 4579 - 4584; DOI:
10.1021/ic961368t
PDF
A Trapped Intermediate in the Copper(II)-Mediated Template Synthesis of an Amino Acid-Containing Ligand
Nydia D. Villanueva, Jeffrey R. Bocarsly, and Joseph W. Ziller
pp 4585 - 4592; DOI:
10.1021/ic961409l
PDF
Alkylammonium Hexachlorometalates. 5.1 Bis(1,6-diammoniohexane) Tetraaquahydrogen(1+) Hexachlororhodate(III) Dichloride, [H3N(CH2)6NH3]2[H9O4][RhCl6]Cl2: Chain-like [H9O4]+ Ions Enclosed in the Cavities of a Complex Organic-Inorganic Framework
Walter Frank and and Guido J. Reiss
pp 4593 - 4595; DOI:
10.1021/ic970337a
PDF
Evidence for Charge-Dipole Effects in the Rubredoxin Model Compound [(CH3)4N]2Fe[SCH2CON(CH3)2]4
K. Bose, J. Huang, B. S. Haggerty, A. L. Rheingold, R. J. Salm, and M. A. Walters
pp 4596 - 4599; DOI:
10.1021/ic960448u
PDF
Tricationic Metal Complexes ([ML][NO3]3, M = Ga, In) of N,N',N''-Tris(2-pyridylmethyl)- cis-1,3,5-triaminocyclohexane: Preparation and Structure
Kerry A. Hilfiker, Martin W. Brechbiel, Robin D. Rogers, and Roy P. Planalp
pp 4600 - 4603; DOI:
10.1021/ic9614024
PDF
Condensation Polymerization of Cobalt Dicarbollide Dicarboxylic Acid
Steve A. Fino, Kyle A. Benwitz, Kris M. Sullivan, Dan L. LaMar, Kristen M. Stroup, Stacy M. Giles, Gary J. Balaich, Rebecca M. Chamberlin, and Kent D. Abney
pp 4604 - 4606; DOI:
10.1021/ic961182u
PDF
Novel Disulfido- and Diselenido-Bridged Zirconium and Hafnium Porphyrin Dimers with Unusual Coordination Geometries: [M(TPP)]2(-2-Q2)2 (M = Zr, Hf; Q = S, Se)
Sanghoon Ryu, Dongmok Whang, Hee-Joon Kim, Kimoon Kim, Maki Yoshida, Keisuke Hashimoto, and Kazuyuki Tatsumi
pp 4607 - 4609; DOI:
10.1021/ic970078p
PDF
Preparation and Crystal Structure of (Sb4O5)(ReO4)2 with Cationic Antimony Oxide Layers
Hiroyuki Watanabe and Hideo Imoto
pp 4610 - 4612; DOI:
10.1021/ic970395w
PDF

Issue 21


205Tl(III)-NMR Study of Thallium(III) Metalloporphyrins
Athanassios G. Coutsolelos and Dimitra Daphnomili
pp 4614 - 4615; DOI:
10.1021/ic9704602
PDF
A Unique Mononuclear Nickel Disulfonato Complex Obtained by Oxidation of a Mononuclear Nickel Dithiolate Complex
Richard K. Henderson, Elisabeth Bouwman, Anthony L. Spek, and Jan Reedijk
pp 4616 - 4617; DOI:
10.1021/ic9707218
PDF
Synthesis and X-ray Crystal Structure of a Triple-Stranded Helical Supramolecular Complex Formed between Tris(3-(pyridin-2-yl)pyrazole)ruthenium(II) and Copper(I)
Michael H. W. Lam, Samuel T. C. Cheung, Ka-Man Fung, and Wing-Tak Wong
pp 4618 - 4619; DOI:
10.1021/ic970537m
PDF
Excitation Energy Dependence of Competitive Photosolvation in W(CO)5py
Lawton E. Shaw, David B. Gibson, and Cooper H. Langford
pp 4620 - 4621; DOI:
10.1021/ic970383a
PDF
An in Situ X-ray Absorption Fine Structure Study of Different Oxidation States of Oxo- and Hydroxo-Bridged Ruthenium Dimers in Acetonitrile Solution
Mats Valli, Seiya Miyata, Hisanobu Wakita, Toshio Yamaguchi, Akihiro Kikuchi, Keisuke Umakoshi, Taira Imamura, and Yoichi Sasaki
pp 4622 - 4626; DOI:
10.1021/ic970339v
PDF
Origin of the Metal-to-Insulator Transition in H0.33MoO3
Roger Rousseau, Enric Canadell, Pere Alemany, Donald H. Galván, and Roald Hoffmann
pp 4627 - 4632; DOI:
10.1021/ic9705296
PDF
Magnetic Studies on -Azido Polynuclear Nickel(II) Compounds with the 222-tet Ligand. Crystal Structure of (-N3)2[Ni(222-tet)]2(BPh4)2 (222-tet = Triethylenetetramine) and EXAFS Structural Characterization of the Triangular Compounds (-N3)3[Ni(222-tet)]3(X)3 (X = PF6-, ClO4-)
Albert Escuer, Isabel Castro, Franz Mautner, Mohamed Salah El Fallah, and Ramon Vicente
pp 4633 - 4640; DOI:
10.1021/ic9702476
PDF
Magnetic Properties of a Series of Trinuclear Complexes (CuL)2Mn·xB (L Representing the Deprotonated Form of N-(4-Methyl-6-oxo-3-azahept-4-enyl)oxamic Acid and B Representing Respectively H2O (x = 5, 4.5, 3, 1), (CH3)2SO (x = 2), and C5H5N (x = 4)). Crystal and Molecular Structure of (CuL)2Mn·2(CH3)2SO
Jean-Pierre Costes, Jean-Pierre Laurent, Jose Maria Moreno Sanchez, Jose Suarez Varela, Markku Ahlgren, and Markku Sundberg
pp 4641 - 4646; DOI:
10.1021/ic970372h
PDF
Commensurate Modulated Displacement and Disorder in the Mixed Valent Vanadium Monophosphate Sr2V2O(PO4)3
S. Boudin, O. Pérez, H. Leligny, D. Grebille, Ph. Labbé, and B. Raveau
pp 4647 - 4655; DOI:
10.1021/ic970285p
PDF
Macrocyclic CuII2, CuII4, NiII3, and NiII4 Complexes: Magnetic Properties of Tetranuclear Systems
Sasankasekhar Mohanta, Kausik K. Nanda, Rüdiger Werner, Wolfgang Haase, Alok K. Mukherjee, Sujit K. Dutta, and Kamalaksha Nag
pp 4656 - 4664; DOI:
10.1021/ic9611103
PDF
Synthesis, Characterization, and Structure of Neutral and Anionic Complexes Containing Octahedral W6Te8 Cluster Units
Xiaobing Xie and Robert E. McCarley
pp 4665 - 4675; DOI:
10.1021/ic970037t
PDF
Investigation of Aquo and Chloro Complexes of UO22+, NpO2+, Np4+, and Pu3+ by X-ray Absorption Fine Structure Spectroscopy
P. G. Allen, J. J. Bucher, D. K. Shuh, N. M. Edelstein, and T. Reich
pp 4676 - 4683; DOI:
10.1021/ic970502m
PDF
Electron Transfer. 135. Pendant Carbonyl Groups in the Mediation of the Reactions of Indium(I) with Bound Ruthenium(III)
Swapan K. Chandra, Pradip C. Paul, and Edwin S. Gould
pp 4684 - 4687; DOI:
10.1021/ic970365t
PDF
Synthesis, 9Be NMR Spectroscopy, and Structural Characterization of Sterically Encumbered Beryllium Compounds
Mark Niemeyer and Philip P. Power
pp 4688 - 4696; DOI:
10.1021/ic970319t
PDF
Synthesis, Structure Analysis, and Characterization of a New Thiostannate, (C12H25NH3)4[Sn2S6]·2H2O
Jianquan Li, Bernd Marler, Henri Kessler, Michel Soulard, and Stefan Kallus
pp 4697 - 4701; DOI:
10.1021/ic970064j
PDF
Syntheses and Crystal Structures of the New Zinc Phosphonates Zn(O3PCH2P(O)(R)(C6H5))·xH2O, Based on Mixed Phosphonic Acid-Phosphine Oxide Building Blocks
Florence Fredoueil, Virginie Penicaud, Martine Bujoli-Doeuff, and Bruno Bujoli
pp 4702 - 4706; DOI:
10.1021/ic970392j
PDF
An Experimental and Theoretical Study of the Electronic Structure of Zinc Thiophenolate-Capped Clusters
Renzo Bertoncello, Marco Bettinelli, Maurizio Casarin, Chiara Maccato, Luciano Pandolfo, and Andrea Vittadini
pp 4707 - 4716; DOI:
10.1021/ic970165h
PDF
Electron Transfer in Mixed-Valence [FeIII2FeIIO(O2CCH3)6(3-Cl-py)3]·3-Cl-py: Effects of a Crystallographic Phase Transition and Conversion of Solvate and Ligand Molecules from Statically Disordered to Dynamically Disordered on the Valence Detrapping
Chi-Cheng Wu, Sheri A. Hunt, Peter K. Gantzel, Philipp Gütlich, and David N. Hendrickson
pp 4717 - 4733; DOI:
10.1021/ic9700314
PDF
Multicomponent Self-Assembly: Generation of Rigid-Rack Multimetallic Pseudorotaxanes
Hanadi Sleiman, Paul N. W. Baxter, Jean-Marie Lehn, Karri Airola, and Kari Rissanen
pp 4734 - 4742; DOI:
10.1021/ic9702227
PDF
Ruthenium Complexes of a Simple Tridentate Ligand Bearing Two "Distal" Pyridine Bases
Seth M. Redmore, Clifton E. F. Rickard, Simon J. Webb, and L. James Wright
pp 4743 - 4748; DOI:
10.1021/ic961534x
PDF
Multinuclear NMR Spectroscopic and X-ray Crystallographic Studies of a Series of Mercury(II) Complexes Containing the Bidentate Phosphine Ligand Ph2PCH2Si(CH3)2CH2PPh2 (L2)
Elmer C. Alyea, George Ferguson, Ram P. Shakya, and Paul R. Meehan
pp 4749 - 4752; DOI:
10.1021/ic9704243
PDF
Synthesis, Characterization, and Reactivity of Isocyanato Dicarbaboranes Obtained from o-Carborane
Ye Wu, Patrick J. Carroll, Sang O. Kang, and William Quintana
pp 4753 - 4761; DOI:
10.1021/ic970360w
PDF
Tetraammineruthenium(II) and -ruthenium(III) Complexes of o-Benzoquinone Diimine and Their Redox Series
Robert A. Metcalfe and A. B. P. Lever
pp 4762 - 4771; DOI:
10.1021/ic970236c
PDF
Experimental and Theoretical Studies on 1,4,5,7-Dithiadiazepinyl Radicals: Preparation and X-ray Structure of 5-(Trimethylsilyl)tetrachlorobenzo-1,4,5,7-dithiadiazepine
Vadapalli Chandrasekhar, Tristram Chivers, Masood Parvez, Ignacio Vargas-Baca, and Tom Ziegler
pp 4772 - 4777; DOI:
10.1021/ic970230n
PDF
Hydroboration of (-H)2Os3(CO)10: Formation of the Borylidyne Cluster (-H)2Os3(CO)9(-H)2BH. An Improved Synthesis of (-H)3Os3(CO)9(3-BCO)
Jang-Hoon Chung, Edwin P. Boyd, Jianping Liu, and Sheldon G. Shore
pp 4778 - 4781; DOI:
10.1021/ic970683s
PDF
Kinetic Effects in Outer Sphere Ion Clusters: Interactions of [Ru(NH3)5H2O]3+ with [Ru(CN)6]4-, [Fe(CN)6]4-, [Os(CN)6]4- and [Co(CN)6]3-
Vassiliki G. Poulopoulou and Henry Taube
pp 4782 - 4788; DOI:
10.1021/ic970496u
PDF
Reactivity of the Acyclic Diazadioxa Redox Active Ligand [(C5H5)Fe(C5H4CH2N(CH3)(CH2)2OCH2-)]2: NMR, Electrochemical, and Mössbauer Studies. Crystal Structure of Its Copper Complex
Béatrice Delavaux-Nicot, Agnès Bigeard, Azzedine Bousseksou, Bruno Donnadieu, and Gérard Commenges
pp 4789 - 4797; DOI:
10.1021/ic970017r
PDF
1H and 13C NMR Studies of an Oxidized HiPIP
Ivano Bertini, Antonio Donaire, Isabella C. Felli, Claudio Luchinat, and Antonio Rosato
pp 4798 - 4803; DOI:
10.1021/ic970057v
PDF
Characterization of the Bis(azido)(meso-tetraphenylporphinato)ferrate(III) Anion. An Unusual Spin-Equilibrium System
Mary K. Ellison, Habib Nasri, Y.-M. Xia, Jean-Claude Marchon, Charles E. Schulz, Peter G. Debrunner, and W. Robert Scheidt
pp 4804 - 4811; DOI:
10.1021/ic970527l
PDF
Electron-Rich Oxoruthenium(IV) Cleavage Agents: A Zero-Order Rate Law for DNA Catalysis
Thomas W. Welch, Suzanne A. Ciftan, P. S. White, and H. Holden Thorp
pp 4812 - 4821; DOI:
10.1021/ic9703944
PDF
Structure-Reactivity Correlations for the Dissociative Uncatalyzed Isomerization of Monoalkylbis(phosphine)platinum(II) Solvento Complexes
Raffaello Romeo and Giuseppe Alibrandi
pp 4822 - 4830; DOI:
10.1021/ic970210l
PDF
Ligand Effects in the Models and Mimics of Oxyhemocyanin and Oxytyrosinase. A Density Functional Study of Reversible Dioxygen Binding and Reversible O-O Bond Cleavage
Attila Bérces
pp 4831 - 4837; DOI:
10.1021/ic970396o
PDF
Synthesis and Structural Characterization of Several Ruthenium Porphyrin Nitrosyl Complexes
Katrina M. Miranda, Xianhui Bu, Ivan Lorkovi, and Peter C. Ford
pp 4838 - 4848; DOI:
10.1021/ic970065b
PDF
Conformation Control of Peptides by Metal Ions. Coordination Conformation Correlation Observed in a Model for Cys-X-Y-Cys/M2+ in Proteins
Takeshi Yamamura, Tsutomu Watanabe, Atsushi Kikuchi, Tsutomu Yamane, Masato Ushiyama, and Hiroshi Hirota
pp 4849 - 4859; DOI:
10.1021/ic961009y
PDF
Pocket Semiquinonate Complexes of Cobalt(II), Copper(II), and Zinc(II) Prepared with the Hydrotris(cumenylmethylpyrazolyl)borate Ligand
Michael Ruf, Bruce C. Noll, Markus D. Groner, Gordon T. Yee, and Cortlandt G. Pierpont
pp 4860 - 4865; DOI:
10.1021/ic970244t
PDF
Structural and Solution Characterization of Mononuclear Vanadium(IV) Complexes That Help To Elucidate the Active Site Structure of the Reduced Vanadium Haloperoxidases
Brent J. Hamstra, Andrew L. P. Houseman, Gerard J. Colpas, Jeff W. Kampf, Russell LoBrutto, Wayne D. Frasch, and Vincent L. Pecoraro
pp 4866 - 4874; DOI:
10.1021/ic970284x
PDF
Synthesis and Characterization of Novel Oxo-Bridged Dinuclear and Hydroxo-Bridged Trinuclear Chromium(III) Assemblies
Anthony Harton, Katisha Terrell, John C. Huffman, Chris MacDonald, Alicia Beatty, Sichu Li, Charles J. O'Connor, and John B. Vincent
pp 4875 - 4882; DOI:
10.1021/ic961247t
PDF
Cr3Si2O7·1/4MX (MX = NaCl, NaBr, KCl, KBr): A Cage Structure Built from [CrIIO4] and [Si2O7] Units
Anita Schmidt and Robert Glaum
pp 4883 - 4887; DOI:
10.1021/ic9700718
PDF
Bond Valence Sums in Coordination Chemistry Using Oxidation State Independent R0 Values. A Simple Method for Calculating the Oxidation State of Manganese in Complexes Containing Only Mn-O Bonds
Gus J. Palenik
pp 4888 - 4890; DOI:
10.1021/ic9705554
PDF
Formation of an Association Complex without a Substitution Reaction Occurring between Methylcobalamin and Cyanide
Nicola E. Brasch, Frank Müller, Achim Zahl, and Rudi van Eldik
pp 4891 - 4894; DOI:
10.1021/ic970295q
PDF
Pb2BaCuFeO5X (X = Cl, Br): New Intergrowth Compounds Composed of CsCl Type and Bipyramidal Defective Perovskite Blocks
Rukang Li
pp 4895 - 4896; DOI:
10.1021/ic970314w
PDF
Structures of the 12-Vertex Oxa- and Thia-nido-dodecaborates and B13H132-: A Theoretical DFT/GIAO/NMR Investigation
Xiaomei Yang, Haijun Jiao, and Paul von Ragué Schleyer
pp 4897 - 4899; DOI:
10.1021/ic970498e
PDF
Comparative UV-Vis Studies of Uranyl Chloride Complex in Two Basic Ambient-Temperature Melt Systems: The Observation of Spectral and Thermodynamic Variations Induced via Hydrogen Bonding
Sheng Dai, Y. S. Shin, L. M. Toth, and C. E. Barnes
pp 4900 - 4902; DOI:
10.1021/ic970251h
PDF
Construction and Conductivity of W-Type Sandwich Silver(I) Polymers with Pyrene and Perylene
Megumu Munakata, Liang Ping Wu, Takayoshi Kuroda-Sowa, Masahiko Maekawa, Yusaku Suenaga, and Kunihisa Sugimoto
pp 4903 - 4905; DOI:
10.1021/ic9706360
PDF
A Hydrogen Polyphosphide Salt of the First Homoleptic Strontium Ammine Complex: Synthesis and Structure Analysis of [Sr(NH3)8]HP11·NH3
Nikolaus Korber and and Jörg Daniels
pp 4906 - 4908; DOI:
10.1021/ic970664i
PDF
Synthesis, Structure, and Reactions of Triphenylphosphine N-((Perfluoroalkyl)sulfonyl)imine and Triphenylarsine N-((Perfluoroalkyl)sulfonyl)imine
Shizheng Zhu, Bin Xu, Chaoyue Qin, and Guolin Xu
pp 4909 - 4911; DOI:
10.1021/ic9611610
PDF
Effect of Pyridyl Donors in the Chelation of Aluminum(III), Gallium(III), and Indium(III)
P. Caravan, Steven J. Rettig, and Chris Orvig
pp 4912 - 4912; DOI:
10.1021/ic9708778
PDF

Issue 22


Synthesis and X-ray Crystal Structure Determination of the First Lanthanide Complexes Containing Primary Phosphide Ligands: Ln[P(H)Mes*]2(thf)4 (Ln = Yb, Eu)
Gerd W. Rabe, Ilia A. Guzei, and Arnold L. Rheingold
pp 4914 - 4915; DOI:
10.1021/ic970422i
PDF
Gas-Phase Iron Tricarbonyl Cyclooctatetraene Exhibits a "Rigid-Rotor" Microwave Spectrum
S. G. Kukolich, S. M. Breckenridge-Estes, and S. M. Sickafoose
pp 4916 - 4918; DOI:
10.1021/ic970902+
PDF
New Insights into the Structure and Properties of Electroactive Polymer Films Derived from [Ni(salen)]
Miguel Vilas-Boas, Cristina Freire, Baltazar de Castro, Paul A. Christensen, and A. Robert Hillman
pp 4919 - 4929; DOI:
10.1021/ic970467j
PDF
Synthesis and Characterization of [Acridinium][Ni(dmit)2]3 and [Phenazinium][Ni(dmit)2]3 (dmit = 2-Thioxo-1,3-dithiole-4,5-dithiolate)
Yvonne S. J. Veldhuizen, Wilberth J. J. Smeets, Nora Veldman, Anthony L. Spek, Christophe Faulmann, Pascale Auban-Senzier, Denis Jérome, Peter M. Paulus, Jaap G. Haasnoot, and Jan Reedijk
pp 4930 - 4937; DOI:
10.1021/ic970347b
PDF
Restricted Rotation around the P-C Bond in Metalated Phosphonium Salts: A Variable-Temperature 1H NMR Study. X-ray Crystal Structures of [{AuP(C6H11)3}2{-C(PTo3)(py-2)}]ClO4 and [(AuPPh3)2{-{C(PPh3)(py-2)}(AuPPh3)}](CF3SO3)2
José Vicente, María-Teresa Chicote, María-Cristina Lagunas, Peter G. Jones, and Birte Ahrens
pp 4938 - 4944; DOI:
10.1021/ic970367d
PDF
Crystal Structure of Bis(N,N-dimethylthioformamide)mercury(II) Iodide, Bromide, and Chloride and Solvation of the Neutral Mercury(II) Halide Complexes in N,N-Dimethylthioformamide, a Resonance-Induced Hydrogen-Bonding Solvent and Ligand
Christina M. V. Stålhandske, Ingmar Persson, Magnus Sandström, and Märtha Åberg
pp 4945 - 4953; DOI:
10.1021/ic970330t
PDF
Intramolecular Electron Transfer in (BzImH)[(LOV)2O] (H2L = S-Methyl 3-((2-Hydroxyphenyl)methyl)dithiocarbazate): A Novel -Oxo Dinuclear Oxovanadium(IV/V) Compound with a Trapped-Valence (V2O3)3+ Core
Subodh Kanti Dutta, Sujit Baran Kumar, Sudeep Bhattacharyya, Edward R. T. Tiekink, and Muktimoy Chaudhury
pp 4954 - 4960; DOI:
10.1021/ic970113s
PDF
Iron-Substituted Dawson-Type Tungstodiphosphates: Synthesis, Characterization, and Single or Multiple Initial Electronation Due to the Substituent Nature or Position
Roland Contant, Mostefa Abbessi, Jacqueline Canny, Abderrahman Belhouari, Bineta Keita, and Louis Nadjo
pp 4961 - 4967; DOI:
10.1021/ic970215i
PDF
Multinuclear Paramagnetic NMR Spectra and Solid State X-ray Crystallographic Characterization of Manganese(III) Schiff-Base Complexes
Yangzhen Ciringh, Scott W. Gordon-Wylie, Richard E. Norman, George R. Clark, Susan T. Weintraub, and Colin P. Horwitz
pp 4968 - 4982; DOI:
10.1021/ic970747z
PDF
A Channel-Forming Polyiodide Network in [Cu(dafone)3]I12. A Tris Chelate of Dafone and a New Planar Structure for the I122- Ion (Dafone = 4,5-Diazafluoren-9-one)
Sindhu Menon and M. V. Rajasekharan
pp 4983 - 4987; DOI:
10.1021/ic970087y
PDF
First Example of Equatorial-Equatorial Disposition of End-to-End Thiocyanate Bridges in a Polynuclear Copper(II) Complex and Its Relation to the Very Efficient Transmission of the Magnetic Interaction
Jorge A. R. Navarro, M. Angustias Romero, Juan M. Salas, Miguel Quirós, and Edward R. T. Tiekink
pp 4988 - 4991; DOI:
10.1021/ic970083t
PDF
Synthesis, Crystal Structures, and Spectroscopic Characterization of Two Pairs of Racemic Isomers of [{Co2(aet)2}{Co(aet)3}2]4+ (aet = 2-Aminoethanethiolate): A Novel S-Bridged Tetranuclear Cobalt(III) Complex Formed by Ligand Transfer from Nickel(II) to Cobalt(III)
Takumi Konno, Yumi Gotoh, and Ken-ichi Okamoto
pp 4992 - 4997; DOI:
10.1021/ic970669f
PDF
Crystallographic, Theoretical, and Spectroscopic Studies of the Luminescent d10-d10 Binuclear Copper Acetate Complex Cu2(dppm)2(O2CCH3)+
Pierre D. Harvey, Marc Drouin, and Tianle Zhang
pp 4998 - 5005; DOI:
10.1021/ic961353v
PDF
Structure and Magnetism of a Bimetallic Pentanuclear Cluster [(Ni(bpm)2)3(Fe(CN)6)2]·7H2O (bpm = Bis(1-pyrazolyl)methane)). The Role of the Hydrogen-Bonded 7H2O "Cluster" in Long-Range Magnetic Ordering
Kenneth Van Langenberg, Stuart R. Batten, Kevin J. Berry, David C. R. Hockless, Boujemaa Moubaraki, and Keith S. Murray
pp 5006 - 5015; DOI:
10.1021/ic970160k
PDF
Influence of Pseudohalide Ions on the Molecular Structure and Magnetic Properties of the Manganese(II)-Bipyrimidine-Pseudohalide System
Roberto Cortés, M. Karmele Urtiaga, Luis Lezama, J. Luis Pizarro, M. Isabel Arriortua, and Teófilo Rojo
pp 5016 - 5021; DOI:
10.1021/ic960969h
PDF
Density Functional Calculations of Magnetic Exchange Interactions in Polynuclear Transition Metal Complexes
Alessandro Bencini, Federico Totti, Claude A. Daul, Karel Doclo, Piercarlo Fantucci, and Vincenzo Barone
pp 5022 - 5030; DOI:
10.1021/ic961448x
PDF
Dissociation Energies, Vibrational Frequencies, and 13C NMR Chemical Shifts of the 18-Electron Species [M(CO)6]n (M = Hf-Ir, Mo, Tc, Ru, Cr, Mn, Fe). A Density Functional Study
Andreas W. Ehlers, Yosadara Ruiz-Morales, Evert Jan Baerends, and Tom Ziegler
pp 5031 - 5036; DOI:
10.1021/ic970223z
PDF
Topological Effects on Intramolecular Electron Transfer via Quantum Interference
Cendrine Patoux, Christophe Coudret, Jean-Pierre Launay, Christian Joachim, and André Gourdon
pp 5037 - 5049; DOI:
10.1021/ic970013m
PDF
Oxidation States, Transport Properties, and Te···Te Short Contacts in the Ternary Transition Metal Tellurides Ta3Pd3Te14 and Ta4Pd3Te16
Pere Alemany, Stéphane Jobic, Raymond Brec, and Enric Canadell
pp 5050 - 5057; DOI:
10.1021/ic970554b
PDF
Heterometallic Fluoroalkoxides of Barium and Copper(I). Syntheses and Structures of [(Me3NO)2Ba2Cu4(TFTB)8] and [(THF)2Ba2Cu2(HFTB)6]
Björn Borup, William E. Streib, and Kenneth G. Caulton
pp 5058 - 5063; DOI:
10.1021/ic970234s
PDF
Heterometallic Lanthanide-Group 14 Metal Chalcogenolates
Jongseong Lee, T. J. Emge, and J. G. Brennan
pp 5064 - 5068; DOI:
10.1021/ic961293t
PDF
Thermal and Photochemical Reactions of Methylrhenium Diperoxide: Formation of Methyl Hydroperoxide in Acetonitrile
Wei-Dong Wang and James H. Espenson
pp 5069 - 5075; DOI:
10.1021/ic970650c
PDF
Novel Alkyl(dialkylamido)zinc(II) Compounds: X-ray Single-Crystal Structures of [MeZnNMe(CH2)3NMe2]2, [MeZnNMe(CH2)2NMe2]2, [EtZnNMe(CH2)3NMe2]2, [EtZnNMe(CH2)2NMe2]2, [Me4Zn6O2(MeN(CH2)3NMe2)4], and [Et4Zn6O2(MeN(CH2)2NMe2)4]
M. Azad Malik, P. O'Brien, M. Motevalli, and A. C. Jones
pp 5076 - 5081; DOI:
10.1021/ic9704546
PDF
Pentacoordination and Pseudopentacoordination via Sulfur Donor Action in Cyclic Phosphates and Phosphites
David J. Sherlock, A. Chandrasekaran, Roberta O. Day, and Robert R. Holmes
pp 5082 - 5089; DOI:
10.1021/ic970508b
PDF
Coordination Networks Based on Tetrahedral Silane Building Blocks: Influence of the Anion on Structures Adopted by Ag+-Si(p-C6H4CN)4 Arrays
Feng-Quan Liu and T. Don Tilley
pp 5090 - 5096; DOI:
10.1021/ic9703484
PDF
Hydrotris(indazolyl)borates: Homoscorpionates with Tunable Regiochemistry
Arnold L. Rheingold, Brian S. Haggerty, Glenn P. A. Yap, and Swiatoslaw Trofimenko
pp 5097 - 5103; DOI:
10.1021/ic970734l
PDF
A Multinuclear NMR Study on the Structure and Dynamics of Lanthanide(III) Complexes of the Poly(amino carboxylate) EGTA4- in Aqueous Solution
Silvio Aime, Alessandro Barge, Alain Borel, Mauro Botta, Sergei Chemerisov, André E. Merbach, Ute Müller, and Dirk Pubanz
pp 5104 - 5112; DOI:
10.1021/ic970240o
PDF
The Effect of Bicarbonate on Oxidation by Peroxynitrite: Implication for Its Biological Activity
Sara Goldstein and and Gidon Czapski
pp 5113 - 5117; DOI:
10.1021/ic970471v
PDF
Room-Temperature Molten Salts of Ruthenium Tris(bipyridine)
Hitoshi Masui and Royce W. Murray
pp 5118 - 5126; DOI:
10.1021/ic9706111
PDF
Preparation, Characterization, and Acidity of a Silica Gel/Tungsten Oxide Solid Acid
Nicholas Kob, Russell S. Drago, and Vaneica Young
pp 5127 - 5131; DOI:
10.1021/ic970090h
PDF
Copper(II) Template Synthesis of a 20-Membered [1+1] Schiff Base Macrocycle and Nickel(II) Template Synthesis of a 40-Membered [2+2] Schiff Base Macrocycle from 2,6-Pyridinedicarboxaldehyde and 1,13-Diamino-4,7,10-trioxatridecane
Andrew L. Vance, Nathaniel W. Alcock, Daryle H. Busch, and Joseph A. Heppert
pp 5132 - 5134; DOI:
10.1021/ic961531k
PDF
Self-Assembled Dimers of Copper(II) Complexes of Tripodal Dianionic Ligands, 2-Pyridyl-2,2'-dipyrrolylmethanes
Jun-ichiro Setsune, Setsuo Muraoka, and Tatsuo Yokoyama
pp 5135 - 5137; DOI:
10.1021/ic970426n
PDF
Ring Opening of Tetrahydropyran Attached to Undecahydro-closo-dodecaborate(1-) by Nucleophiles
Toralf Peymann, Kirsten Kück, and Detlef Gabel
pp 5138 - 5139; DOI:
10.1021/ic970647t
PDF
A Polymeric Structure Containing Cu2Cl2 Units Bridged by 4,4'-Bipyridine: (PPh3)2Cu2(-Cl)2(-4,4'-bipyridine)
Jian Lu, Gerardo Crisci, Tianyan Niu, and Allan J. Jacobson
pp 5140 - 5141; DOI:
10.1021/ic9705507
PDF
A -Phosphaalkyne Complex of Ruthenium(0)
Robin B. Bedford, Anthony F. Hill, James D. E. T. Wilton-Ely, Matthew D. Francis, and Cameron Jones
pp 5142 - 5144; DOI:
10.1021/ic961383y
PDF

Issue 23


Functional Analogs of Heme Protein Active Sites
James P. Collman
pp 5145 - 5155; DOI:
10.1021/ic971037w
PDF
Vibrational Spectra and Gas-Phase Structure of Pentafluorosulfanyl Hypochlorite
Andreas Kornath and, Nina Hartfeld, and Heinz Oberhammer
pp 5156 - 5159; DOI:
10.1021/ic970648l
PDF
Synthesis and Reactivity of a Dimeric Platinum Phosphinidene Complex
Igor V. Kourkine and David S. Glueck
pp 5160 - 5164; DOI:
10.1021/ic970730g
PDF
Synthetic and Structural Studies of Gallium-Phosphorus, Gallium-Arsenic, and Indium-Phosphorus Compounds with Chromophoric Substituents
Robert D. Culp, Alan H. Cowley, Andreas Decken, Richard A. Jones, Marcus R. Bond, Ladd M. Mokry, and Carl J. Carrano
pp 5165 - 5172; DOI:
10.1021/ic970359x
PDF
Cluster Condensation by Thermolysis: Synthesis of a Rhomb-Linked Re12Se16 Dicluster and Factors Relevant to the Formation of the Re24Se32 Tetracluster
Zhiping Zheng and R. H. Holm
pp 5173 - 5178; DOI:
10.1021/ic970727x
PDF
Rearrangement Reactions in Dinuclear Triple Helicates
Michel Meyer, Berthold Kersting, Ryan E. Powers, and Kenneth N. Raymond
pp 5179 - 5191; DOI:
10.1021/ic970864u
PDF
Synthesis of the first Metallasila-closo-dodecaborates(1-). Silaborate Complexes of Cobalt, Rhodium, and Iridium
Lars Wesemann, Yves Ramjoie, Michael Trinkaus, and Beate Ganter
pp 5192 - 5197; DOI:
10.1021/ic970455y
PDF
Molecular Structure of C(GeBr3)4 Determined by Gas-Phase Electron Diffraction and Density Functional Theory Calculations: Implications for the Length and Stability of Ge-C Bonds in Crystalline Semiconductor Solids
Arne Haaland, Dmitry J. Shorokhov, Tor G. Strand, John Kouvetakis and, and Michael O'Keeffe
pp 5198 - 5201; DOI:
10.1021/ic970582u
PDF
Syntheses and Structures of [Sn{NR}2{Sn(-NMe2)}2]: Model Intermediates in the Formation of Imido Group 14 Cages and Rings [R = 2,6-Pri2C6H3 (Dipp), 2,4,6-Me3C6H2 (Mes)]
Robert E. Allan, Michael A. Beswick, Georgina R. Coggan, Paul R. Raithby, Andrew E. H. Wheatley, and Dominic S. Wright
pp 5202 - 5205; DOI:
10.1021/ic970336i
PDF
Substitution Reaction Studies on [Au2Cl2(-dppf)] (dppf = 1,1'-Bis(diphenylphosphino)ferrocene). Synthesis of the First Gold(I) Complex with a 3-2-Pyridinethiolate Ligand
Fernando Canales, M. Concepción Gimeno, Peter G. Jones, Antonio Laguna, and Cristina Sarroca
pp 5206 - 5211; DOI:
10.1021/ic9704445
PDF
A Facile Synthesis of Diphosphasilacyclopropanes and 1,3-Diphospha-2,4-disilabicyclo[1.1.0]butanes and an ab Initio Study of Diphosphadisilabicyclo[1.1.0]butanes and Their Respective 1,3-Diene Isomers
Matthias Driess, Hans Pritzkow, Stefan Rell, and Rudolf Janoschek
pp 5212 - 5217; DOI:
10.1021/ic970580+
PDF
Inelastic Neutron Scattering, Infrared, and Raman Spectroscopic Studies of Mg2FeH6 and Mg2FeD6
Stewart F. Parker, Kenneth P. J. Williams, Manfred Bortz, and Klaus Yvon
pp 5218 - 5221; DOI:
10.1021/ic970355s
PDF
Synthesis and Chemistry of CF3C6F4OC6F4 Group 14/16 Derivatives
Burkhard Krumm, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 5222 - 5230; DOI:
10.1021/ic970528d
PDF
Architecture of Crystalline Polymers Formed from the Binuclear Complexes XAuPh2P(CH2)nPPh2AuX through Weak Au(I)···Au(I) Interactions
Pamela M. Van Calcar, Marilyn M. Olmstead, and Alan L. Balch
pp 5231 - 5238; DOI:
10.1021/ic970269s
PDF
Polyoxovanadates: High-Nuclearity Spin Clusters with Interesting Host-Guest Systems and Different Electron Populations. Synthesis, Spin Organization, Magnetochemistry, and Spectroscopic Studies
Achim Müller, Roberta Sessoli, Erich Krickemeyer, Hartmut Bögge, Jochen Meyer, Dante Gatteschi, Luca Pardi, Jörg Westphal, Kai Hovemeier, Ralf Rohlfing, Joachim Döring, Frank Hellweg, Christian Beugholt, and Marc Schmidtmann
pp 5239 - 5250; DOI:
10.1021/ic9703641
PDF
P(CH2CH2Py)nPh3-n (Py = 2-Pyridyl; n = 1, 2, 3) as Chelating and as Binucleating Ligands for Palladium
Juan A. Casares, Pablo Espinet, Katerina Soulantica, Isabel Pascual, and A. Guy Orpen
pp 5251 - 5256; DOI:
10.1021/ic970745e
PDF
Kinetics and Mechanism of the Oxidation of Secondary Hydroxylamines to Nitrones with Hydrogen Peroxide, Catalyzed by Methylrhenium Trioxide
Timothy H. Zauche and James H. Espenson
pp 5257 - 5261; DOI:
10.1021/ic970649d
PDF
Enhancement of the Dimensionality of Molecular Conductors by the Selone Substitution of M(dmit)2 (M = Ni, Pd) Systems: Newly Synthesized dmise Compounds [MexH4-xN][Ni(dmise)2]2 (x = 1-3) and Cs[Pd(dmise)2]2 (dmise = 4,5-Dimercapto-1,3-dithiole-2-selone)
Akane Sato, Hayao Kobayashi, Toshio Naito, Fumiko Sakai, and Akiko Kobayashi
pp 5262 - 5269; DOI:
10.1021/ic970507j
PDF
The Case of a Cu4 Rhombus in Molecular Magnetism: Preparation, Crystal Structure, and Magnetic Properties of [Cu4(dpk·CH3O)4(CH3O)2](ClO4)2 (dpk·CH3OH = Monomethylated Diol of Di-2-pyridyl Ketone), an Example of a Cluster Allowing the Determination of All Its Exchange Parameters, Ranging from Very Strong to Very Weak
Vasilis Tangoulis, Catherine P. Raptopoulou, Sofia Paschalidou, Alexandros E. Tsohos, Evangelos G. Bakalbassis, Aris Terzis, and Spyros P. Perlepes
pp 5270 - 5277; DOI:
10.1021/ic970332d
PDF
Synthesis, Structure, Optical Properties, and Magnetism of the Manganese Chalcogenide Beryllosilicate and Beryllogermanate Sodalites
S. E. Dann, M. T. Weller, B. D. Rainford, and D. T. Adroja
pp 5278 - 5283; DOI:
10.1021/ic970511v
PDF
Neutron Diffraction of Homopolyatomic Bismuth Ions in Liquid Bi5(AlCl4)3 and ab Initio Study of the Structure and Bonding of the Isolated Bi53+ Ion
Kazuhiko Ichikawa, Tetsuo Yamanaka, Atsushi Takamuku, and Rainer Glaser
pp 5284 - 5290; DOI:
10.1021/ic970608h
PDF
Polymorphism in [Cu(cyclam)(TCNQ)2](TCNQ) Stacked Systems (cyclam = 1,4,8,11-Tetraazacyclotetradecane, TCNQ = 7,7,8,8-Tetracyanoquinodimethane)
Loreto Ballester, Ana M. Gil, Angel Gutiérrez, M. Felisa Perpiñán, M. Teresa Azcondo, Ana E. Sánchez, Ulises Amador, Javier Campo, and Fernando Palacio
pp 5291 - 5298; DOI:
10.1021/ic9703585
PDF
Structure-Spectroscopy Correlations in Silver Thiolates: Application to the Structure of Silver 1,5-Pentanedithiolate
Hilary G. Fijolek, Pilar González-Duarte, Sang Hyun Park, Steven L. Suib, and Michael J. Natan
pp 5299 - 5305; DOI:
10.1021/ic9608307
PDF
Helix Induction and Springboard Strain in Peptide-Sandwiched Mesohemes
Paige A. Arnold, David R. Benson, Daniel J. Brink, Michael P. Hendrich, Gouri S. Jas, Michelle L. Kennedy, Doros T. Petasis, and Manxue Wang
pp 5306 - 5315; DOI:
10.1021/ic960444p
PDF
Synthetic Multinuclear Chromium Assembly Activates Insulin Receptor Kinase Activity: Functional Model for Low-Molecular-Weight Chromium-Binding Substance
C. Michele Davis, April C. Royer, and John B. Vincent
pp 5316 - 5320; DOI:
10.1021/ic970568h
PDF
Solution NMR Studies and Crystal Structure of the Water-Soluble Iron(III) Porphyrin Iron 5,10,15,20-Tetrakis(2,3,5,6-tetrafluoro-4-N,N,N-trimethylaniliniumyl)porphyrin ([FeTF4TMAP]5+)
Timothy La, Gordon M. Miskelly, and Robert Bau
pp 5321 - 5328; DOI:
10.1021/ic961486g
PDF
Complexes Containing 2,9-Bis(p-biphenylyl)-1,10-phenanthroline Units Incorporated into a 56-Membered Ring. Synthesis, Electrochemistry, and Photophysical Properties
Jean-Marc Kern, Jean-Pierre Sauvage, Jean-Luc Weidmann, Nicola Armaroli, Lucia Flamigni, Paola Ceroni, and Vincenzo Balzani
pp 5329 - 5338; DOI:
10.1021/ic970707v
PDF
LIESST Effect Studies of Iron(II) Spin-Crossover Complexes with Phosphine Ligands: Relaxation Kinetics and Effects of Solvent Molecules
Chi-Cheng Wu, Jürgen Jung, Peter K. Gantzel, Philipp Gütlich, and David N. Hendrickson
pp 5339 - 5347; DOI:
10.1021/ic9700359
PDF
Density Functional Calculations of g Values and Molybdenum Hyperfine Coupling Constants for a Series of Molybdenum(V) Oxyhalide Anions
Jacob Swann and T. David Westmoreland
pp 5348 - 5357; DOI:
10.1021/ic961097m
PDF
Ab Initio Characterization of [H3N·BH3]2, [H3N·AlH3]2, and [H3N·GaH3]2
Christopher J. Cramer and Wayne L. Gladfelter
pp 5358 - 5362; DOI:
10.1021/ic970211d
PDF
Ab Initio SCF Nonlinear Pair Population Analysis. A New Means of Detection and Localization of Multicenter Bonding
Roberto C. Bochicchio, Robert Ponec, and Filip Uhlík
pp 5363 - 5368; DOI:
10.1021/ic961525o
PDF
Structure, Isomerism, and Ligand Dynamics in Dioxouranium(VI) Complexes
Zoltán Szabó, Wenche Aas, and Ingmar Grenthe
pp 5369 - 5375; DOI:
10.1021/ic9708172
PDF
Synthesis, Spectroscopy, and Redox Behavior of the Binuclear Complex Cation [Ni2(6,6'-spirobi(cyclam))]4+ (cyclam = 1,4,8,11-Tetraazacyclotetradecane): Characteristics of a Transient Ni(II)-Ni(III) Species
A. McAuley and and S. Subramanian
pp 5376 - 5383; DOI:
10.1021/ic970327+
PDF
Selective Synthesis and Electrochemical Behavior of trans(Cl)- and cis(Cl)-[Ru(bpy)(CO)2Cl2] Complexes (bpy = 2,2'-Bipyridine). Comparative Studies of Their Electrocatalytic Activity toward the Reduction of Carbon Dioxide
Sylvie Chardon-Noblat, Alain Deronzier, Raymond Ziessel, and Daniela Zsoldos
pp 5384 - 5389; DOI:
10.1021/ic9701975
PDF
Copper(I) Complexes of 3,3'-Bridged 2,2'-Biquinoline: Synthesis, Properties, and Structure
Yurngdong Jahng, John Hazelrigg, David Kimball, Elvira Riesgo, Feiyue Wu, and Randolph P. Thummel
pp 5390 - 5395; DOI:
10.1021/ic970385v
PDF
Stability and Kinetics of Acid- and Anion-Assisted Dissociation Reactions of Hexaamine Macrobicyclic Mercury(II) Complexes
Lisbeth Grndahl, Anders Hammershi, Alan M. Sargeson, and Vivienne J. Thöm
pp 5396 - 5403; DOI:
10.1021/ic9705148
PDF
Formal Oxidation States vs -Effects in Isostructural Low-Symmetry [MoNO]3+ and [MoO]3+ Complexes: A Photoelectron Spectroscopy Study
Barry L. Westcott and John H. Enemark
pp 5404 - 5405; DOI:
10.1021/ic9706818
PDF
A New Copper(II) Coordination Polymer from the Methyl Ester of 2,3-Pyrazinedicarboxylic Acid: Crystal Structure Determination from Laboratory X-ray Powder Diffraction Data
Antonia Neels, Helen Stoeckli-Evans, Yi Wang, Abraham Clearfield, and Damodara M. Poojary
pp 5406 - 5408; DOI:
10.1021/ic9705204
PDF
Kinetics of the Aquation of Amminepentacyanoferrate(II). A Volume Profile Analysis
Iwona Maciejowska, Rudi van Eldik, Grazyna Stochel, and Zofia Stasicka
pp 5409 - 5412; DOI:
10.1021/ic961375h
PDF
Heavy Alkaline-Earth Polyether Carboxylates. The Crystal Structure of {Ca[OOC(CH2)O(CH2)2]2O(H2O)2}2
Anand M. Bahl, Sujatha Krishnaswamy, Neal G. Massand, David J. Burkey, and Timothy P. Hanusa
pp 5413 - 5415; DOI:
10.1021/ic970617q
PDF
Two Types of New Polymeric Copper(I) Complexes of Pyrazinecarboxamide Having Channel and Helical Structures
Megumu Munakata, Liang Ping Wu, Takayoshi Kuroda-Sowa, Masahiko Maekawa, Kazuma Moriwaki, and Susumu Kitagawa
pp 5416 - 5418; DOI:
10.1021/ic970427f
PDF
An Exploratory Evaluation of the Reactions of Organic Oxidants with Polyhedral Borane Anions
Rachel A. Watson-Clark and M. Frederick Hawthorne
pp 5419 - 5420; DOI:
10.1021/ic970279t
PDF
A New Bridging Ligand for the [Mo2]4+ Dimer: Syntheses and X-ray Crystal Structures of the Redox Pair [Mo2{-2-(NPh)2CNHPh}4]0/+
Philip J. Bailey, Simon F. Bone, Lindsey A. Mitchell, Simon Parsons, Kenneth J. Taylor, and Lesley J.Yellowlees
pp 5420 - 5420; DOI:
10.1021/ic970430z
PDF

Issue 24


Synthesis, Characterization, and Preliminary Host-Guest Binding Studies of Porphyrinic Molecular Squares Featuring fac-Tricarbonylrhenium(I) Chloro Corners
Robert V. Slone and Joseph T. Hupp
pp 5422 - 5423; DOI:
10.1021/ic9703991
PDF
Models for Amide Ligation in Nonheme Iron Enzymes
Sanjay K. Mandal and Lawrence Que, Jr.
pp 5424 - 5425; DOI:
10.1021/ic970541y
PDF
Synthesis and X-ray Structure of an H2S Complex, RuCl2(P-N)(P(p-tolyl)3)(SH2) (P-N = o-(Diphenylphosphino)-N,N-dimethylaniline)
D. Chandrika Mudalige, Erin S. Ma, Steven J. Rettig, Brian R. James, and William R. Cullen
pp 5426 - 5427; DOI:
10.1021/ic9707772
PDF
Dynamic Behavior of [Pd(C6F5)2(SPPynPh3-n)] Complexes: Evidence for a Turnstile Mechanism in Intramolecular Exchange
Juan A. Casares and Pablo Espinet
pp 5428 - 5431; DOI:
10.1021/ic970749j
PDF
Inter-Metal Nitrogen Atom Transfer Reactions between Nitridochromium(V) and Chromium(III) Porphyrins
Frank L. Neely and Lawrence A. Bottomley
pp 5432 - 5434; DOI:
10.1021/ic960918k
PDF
Stereoelectronic Aspects of Inter-Metal Nitrogen Atom Transfer Reactions between Nitridomanganese(V) and Chromium(III) Porphyrins
Lawrence A. Bottomley and Frank L. Neely
pp 5435 - 5439; DOI:
10.1021/ic960919c
PDF
Stability and Ligand Exchange Reactions of Chromium(IV) Carboxylato Complexes in Aqueous Solutions
Rachel Codd, Peter A. Lay, and Aviva Levina
pp 5440 - 5448; DOI:
10.1021/ic970834r
PDF
Isomer Effect on the Structure and Chemical Reactivity of Diruthenium Complexes. Synthesis and Characterization of the (4,0), (3,1), and (2,2) Trans Isomers of Ru2(F5ap)4Cl and Ru2(F5ap)4(CCC6H5)2 Where F5ap Is the 2-(2,3,4,5,6-Pentafluoroanilino)pyridinate Anion
John L. Bear, Yulan Li, Baocheng Han, Eric Van Caemelbecke, and Karl M. Kadish
pp 5449 - 5456; DOI:
10.1021/ic9602658
PDF
Complexes of Cobalt(II) Chloride with the Tripodal Trisphosphane triphos: Solution Dynamics, Spin-Crossover, Reactivity, and Redox Activity
Katja Heinze, Gottfried Huttner, Laszlo Zsolnai, and Peter Schober
pp 5457 - 5469; DOI:
10.1021/ic9705352
PDF
Condensation Reactions of Cobalt Amino Acid Complexes with Formaldehyde: Preparation and Crystal Structures of Cobalt Complexes Containing New Hexadentate, Pendant-Arm Macrocyclic and Acyclic Ligands
Penelope J. Brothers, George R. Clark, Helen R. Palmer, and David C. Ware
pp 5470 - 5477; DOI:
10.1021/ic970482o
PDF
Organometallic Iron Indium Derivatives Prepared by the Reaction of Carbonyliron Compounds with the Alkylindium(I) Derivative In4[C(SiMe3)3]4
Werner Uhl, Sven Uwe Keimling, Michael Pohlmann, Siegfried Pohl, Wolfgang Saak, Wolfgang Hiller, and Markus Neumayer
pp 5478 - 5482; DOI:
10.1021/ic9704804
PDF
Copper(I) Halide Catalyzed Trans-Cis Isomerization of RuCl2(dppm)2 (dppm = Ph2PCH2PPh2)
Yongbao Zhu, Michael O. Wolf, and Glenn P. A. Yap
pp 5483 - 5487; DOI:
10.1021/ic9704187
PDF
Coordination, O-Methylation, and S-O Bond Cleavage of Sulfur Dioxide on Hexaruthenium Carbido Carbonyl Clusters
Teiji Chihara, Hideaki Kubota, Masashi Fukumoto, Haruo Ogawa, Yasuhiro Yamamoto, and Yasuo Wakatsuki
pp 5488 - 5497; DOI:
10.1021/ic9704290
PDF
Calixarene Metalloreceptors. Synthesis and Molecular Recognition Properties of Upper-Rim Functionalized Calix[4]arenes Containing an Organopalladium Binding Site
Beth R. Cameron, Stephen J. Loeb, and Glenn P. A. Yap
pp 5498 - 5504; DOI:
10.1021/ic9705913
PDF
Site Preference Energetics, Fluxionality, and Intramolecular M-H···H-N Hydrogen Bonding in a Dodecahedral Transition Metal Polyhydride
Ramon Bosque, Feliu Maseras, Odile Eisenstein, Ben P. Patel, Wenbin Yao, and Robert H. Crabtree
pp 5505 - 5511; DOI:
10.1021/ic970084l
PDF
Synthesis, Crystal Structure, High-Resolution Optical Spectroscopy, and Extended Hückel Calculations for [Re(CO)4(thpy)] (thpy- = 2-(2-Thienyl)pyridinate). Comparison with Related Cyclometalated Complexes
Frederik W. M. Vanhelmont , Hans U. Güdel , Marcel Förtsch, and Hans-Beat Bürgi
pp 5512 - 5517; DOI:
10.1021/ic970415u
PDF
14N Coupling Parameters in Oxovanadium(IV)-Amine, -Imine, and -Isothiocyanate Complexes Studied by Electron Spin Echo Envelope Modulation Spectroscopy
Kouichi Fukui, Hiroaki Ohya-Nishiguchi, and Hitoshi Kamada
pp 5518 - 5529; DOI:
10.1021/ic961462+
PDF
Molecular Structures and FT-Raman Spectroscopy of Luminescent Niobium and Tantalum Arylimido Compounds
Kurt S. Heinselman, Vincent M. Miskowski, Steven J. Geib, Louis C. Wang, and Michael D. Hopkins
pp 5530 - 5538; DOI:
10.1021/ic970494+
PDF
Unusual Luminescence Spectra and Decay Dynamics in Crystalline Supramolecular [(A18C6)4MBr4][TlBr4]2 (A = Rb, K; M = 3d Element) Complexes
Nicolette S. Fender, Frank R. Fronczek, Vijay John, Ishenkumba A. Kahwa, and Gary L. McPherson
pp 5539 - 5547; DOI:
10.1021/ic9601753
PDF
Creation of Metal-to-Ligand Charge Transfer Excited States with Two-Photon Excitation
Felix N. Castellano, Henryk Malak, Ignacy Gryczynski, and Joseph R. Lakowicz
pp 5548 - 5551; DOI:
10.1021/ic970334y
PDF
Efficient Substitutional Photochemistry of a Third-Row Transition Metal -Diketonate Complex
Richard J. Lavallee, Bentley J. Palmer, Roland Billing, Horst Hennig, Guillermo Ferraudi, and Charles Kutal
pp 5552 - 5558; DOI:
10.1021/ic9705150
PDF
Crystal Structures of Potassium Tetratellurite, K2Te4O9, and Potassium Ditellurite, K2Te2O5, and Structural Trends in Solid Alkali Tellurites
C. R. Becker, S. L. Tagg, J. C. Huffman, and J. W. Zwanziger
pp 5559 - 5564; DOI:
10.1021/ic970497m
PDF
Synthesis of Aluminum-Based Surfactant Mesophases Morphologically Controlled through a Layer to Hexagonal Transition
Mitsunori Yada, Hiroaki Hiyoshi, Kaoru Ohe, Masato Machida, and Tsuyoshi Kijima
pp 5565 - 5569; DOI:
10.1021/ic970292d
PDF
Vibrational Spectra and Structural Aspects of Fluorosulfites
Andreas Kornath and, Frank Neumann, and Ralf Ludwig
pp 5570 - 5573; DOI:
10.1021/ic970315o
PDF
Structure of Amorphous Platinum Uridine Green Sulfate by AWAXS and EXAFS
Ritva Serimaa, Veli Eteläniemi, Tarja Laitalainen, Arthur Bienenstock, Sakari Vahvaselkä, and Timo Paakkari
pp 5574 - 5579; DOI:
10.1021/ic9611756
PDF
X-ray Absorption Spectroscopic Study of the Temperature and Pressure Dependence of the Electronic Spin States in Several Iron(II) and Cobalt(II) Tris(pyrazolyl)borate Complexes
Cécile Hannay, Marie-Jeanne Hubin-Franskin, Fernande Grandjean, Valérie Briois, Jean-Paul Itié, Alain Polian, Swiatoslaw Trofimenko, and Gary J. Long
pp 5580 - 5588; DOI:
10.1021/ic970506r
PDF
Two New Pyridyl-Substituted Tris(pyrazolyl)borate Ligands and Their Potassium Salts
Karl Weis and Heinrich Vahrenkamp
pp 5589 - 5591; DOI:
10.1021/ic970627r
PDF
Simple Zinc Complexes of Pyridyl-Substituted Tris(pyrazolyl)borate Ligands
Karl Weis and Heinrich Vahrenkamp
pp 5592 - 5596; DOI:
10.1021/ic970628j
PDF
Cyclic Hydroborate Complexes of Metallocenes. 1. Organodiborate Ring Transformations Promoted by Zirconocene and Hafnocene Dichlorides. Syntheses and Structures of Zirconocene and Hafnocene Boracyclopentane Derivatives
Glenn T. Jordan IV, Fu-Chen Liu, and Sheldon G. Shore
pp 5597 - 5602; DOI:
10.1021/ic970758s
PDF
Zirconium(IV) Sandwich Complexes of Porphyrins and Tetraazaporphyrins: Synthesis, Structure, and Nonlinear Optical Properties
James P. Collman, Jonathan L. Kendall, Judy L. Chen, Todd A. Eberspacher, and Christopher R. Moylan
pp 5603 - 5608; DOI:
10.1021/ic970657u
PDF
A One-Dimensional Array of Clusters: Na2Mo6Cl8(O2CC5H4FeCp)6·CH3OH
Nicholas Prokopuk and Duward F. Shriver
pp 5609 - 5613; DOI:
10.1021/ic970816+
PDF
Ordered Supramolecular Porphyrin Arrays from a Building Block Approach Utilizing Pyridylporphyrins and Peripheral Ruthenium Complexes and Identification of a New Type of Mixed-Metal Building Block
Enzo Alessio, Michela Macchi, Sarah L. Heath, and Luigi G. Marzilli
pp 5614 - 5623; DOI:
10.1021/ic970340u
PDF
Absorption, Fluorescence, and Magnetic Circular Dichroism Spectra of and Molecular Orbital Calculations on Tetrabenzotriazaporphyrins and Tetranaphthotriazaporphyrins
John Mack, Nagao Kobayashi, Clifford C. Leznoff, and Martin J. Stillman
pp 5624 - 5634; DOI:
10.1021/ic961389n
PDF
Bidentate Sulfoxide Complexes of Ruthenium(II) and Their Preliminary Biological Assessment in Vitro
Donald T. T. Yapp, Steven J. Rettig, Brian R. James, and Kirsten A. Skov
pp 5635 - 5641; DOI:
10.1021/ic9606486
PDF
Intramolecular Electron-Transfer Assistance in the Redox Reaction of (-Cyano)pentaammineruthenium(III) Pentacyanoferrate(II). Role of the Electronic Isomer and of the Specific Donor-Acceptor Interactions
Paula Forlano, Alejandro R. Parise, Mariela Videla, and José A. Olabe
pp 5642 - 5644; DOI:
10.1021/ic9706414
PDF
Steric Control of the Coordination Mode of the Salicylaldehyde Thiosemicarbazone Ligand. Syntheses, Structures, and Redox Properties of Ruthenium and Osmium Complexes
Falguni Basuli, Shie-Ming Peng, and Samaresh Bhattacharya
pp 5645 - 5647; DOI:
10.1021/ic9705094
PDF
Reversible Depolymerization of Silver Pyrimidinolate into Cyclic Hexamers
Norberto Masciocchi, Eleonora Corradi, Massimo Moret, G. Attilio Ardizzoia, Angelo Maspero, Girolamo La Monica, and Angelo Sironi
pp 5648 - 5650; DOI:
10.1021/ic9708273
PDF
Template Synthesis, Properties, and Crystal Structure of a Trigonal Bipyramidal Cobalt(II) Octaazamacrobicyclic Complex
Myunghyun Paik Suh, Jaeho Lee, Mi Young Han, and Tea Sung Yoon
pp 5651 - 5654; DOI:
10.1021/ic970020a
PDF
Synthesis and Electrochemical Oxidation of Bridged Ruthenium/Platinum Complexes of 1,10-Phenanthroline-5,6-diolate
Pamela L. Hill, Lawrence Y. Lee, Todd R. Younkin, Stephen D. Orth, and Lisa McElwee-White
pp 5655 - 5657; DOI:
10.1021/ic9706055
PDF
A Cobalt(II) Cryptate of a Heteroditopic Cryptand L as an Efficient Oxygenation Catalyst of Organic Substrates Using Molecular Oxygen and 2-Methylpropanal
Dillip K. Chand and Parimal K. Bharadwaj
pp 5658 - 5660; DOI:
10.1021/ic970306f
PDF
Porphyrazine Binaries: Synthesis, Characterization, and Spectroscopy of a Metal-Linked Trinuclear Porphyrazine Dimer
Theodore F. Baumann, Anthony G. M. Barrett, and Brian M. Hoffman
pp 5661 - 5665; DOI:
10.1021/ic9701367
PDF
Synthesis and Structure of the Polyoxoanion [Si2W23O77(OH)]9-
André Tézé, Monique Michelon, and Gilbert Hervé
pp 5666 - 5669; DOI:
10.1021/ic970821d
PDF
Synthesis and Structure of [Au5(C6H4PPh2)4]+: A Cycloaurated Cation Containing a Pair of Ipso-Carbon-Digold Interactions
Martin A. Bennett, Lee L. Welling, and Anthony C. Willis
pp 5670 - 5672; DOI:
10.1021/ic9703686
PDF

Issue 25


A New Phthalocyanine Analogue Containing One 1,8-Naphthalene Unit
Nagao Kobayashi, Natsuko Sasaki, and Hideo Konami
pp 5674 - 5675; DOI:
10.1021/ic970286h
PDF
Photoinduced Electron Transfer in Covalently Linked Oxomolybdenum(V) Porphyrin Systems
Mark H. Wall Jr., Partha Basu, Tione Buranda, Bryan S. Wicks, Eric W. Findsen, Mark Ondrias, John H. Enemark, and Martin L. Kirk
pp 5676 - 5677; DOI:
10.1021/ic9705711
PDF
Localization in trans,trans-[(tpy)(Cl)2OsIII(N2)OsII(Cl)2(tpy)]+ (tpy = 2,2':6',2''-Terpyridine)
Konstantinos D. Demadis, Thomas J. Meyer, and Peter S. White
pp 5678 - 5679; DOI:
10.1021/ic970885o
PDF
Modeling the Catalytic Site of Liver Alcohol Dehydrogenase: Synthesis and Structural Characterization of a [Bis(thioimidazolyl)(pyrazolyl)hydroborato]zinc Complex, [HB(timMe)2pz]ZnI
Clare Kimblin, Tony Hascall, and Gerard Parkin
pp 5680 - 5681; DOI:
10.1021/ic9710871
PDF
Synthesis of cis-Bis(heteroaryl)nickel(II) Complexes and Reductive Elimination of Bis(heteroaryl) Products Induced by Protic Acid
Yasuharu Murakami and Takakazu Yamamoto
pp 5682 - 5683; DOI:
10.1021/ic971111a
PDF
A Magnetically Coupled Three-Dimensional (Terephthalato)manganese(II) Network
Chang Seop Hong and Youngkyu Do
pp 5684 - 5685; DOI:
10.1021/ic9711527
PDF
Structural Diversity in Monomeric Cadmium Phenoxides
Donald J. Darensbourg, Sharon A. Niezgoda, Joseph H. Reibenspies, and Jennifer D. Draper
pp 5686 - 5688; DOI:
10.1021/ic971002w
PDF
The OC2F5-, OCF(CF3)2-, and OCFCF2O- Anions: Preparation and Structure
X. Zhang and K. Seppelt
pp 5689 - 5693; DOI:
10.1021/ic970512n
PDF
Unusual Ring Systems Containing Indium. Synthesis and Structure of the First Mercuraindacycles
François P. Gabbaï, Annette Schier, Jürgen Riede, Alexander Sladek, and Hans W. Görlitzer
pp 5694 - 5698; DOI:
10.1021/ic970241g
PDF
A Novel Anionic Gold-Indium Cluster Compound: Synthesis and Molecular and Electronic Structure
François P. Gabbaï, Sai-Cheong Chung, Annette Schier, Sven Krüger, Notker Rösch, and Hubert Schmidbaur
pp 5699 - 5705; DOI:
10.1021/ic970725c
PDF
,'-m-Xylenediylbis(indium dichloride). A Novel Bifunctional Lewis Acid
Martin Tschinkl, Annette Schier, Jürgen Riede, and François P. Gabbaï
pp 5706 - 5711; DOI:
10.1021/ic970204p
PDF
Synthesis and Solution State Characterization by Gradient-Enhanced 2D Multinuclear NMR Spectroscopy of a Fluorine-Bridged Dimethyltin(IV) Salicylaldoximate Derivative
Abdelkrim Meddour, Frédéric Mercier, José C. Martins, Marcel Gielen, Monique Biesemans, and Rudolph Willem
pp 5712 - 5715; DOI:
10.1021/ic970866e
PDF
Alkoxide and Aryloxide Derivatives of a (Triamidoamine)uranium Complex
Paul Roussel, Peter B. Hitchcock, Nigel D. Tinker, and Peter Scott
pp 5716 - 5721; DOI:
10.1021/ic970856d
PDF
The Coordination Chemistry of Fluorocarbons: Difluoro-m-cyclophane-Based Fluorocryptands and Their Group I and II Metal Ion Complexes
Herbert Plenio, Jörg Hermann, and Ralph Diodone
pp 5722 - 5729; DOI:
10.1021/ic9708069
PDF
Hexacoordination via Sulfur Donor Action in Bicyclic Pentaoxyphosphoranes
Paul Sood, A. Chandrasekaran, T. K. Prakasha, Roberta O. Day, and Robert R. Holmes
pp 5730 - 5734; DOI:
10.1021/ic970724k
PDF
Complexes with S-Donor Ligands. 6. Synthesis of the First Family of (Trithiocarbonato)gold Complexes. Crystal Structure of [(PPh3)2N][AuCl2(CS3)]
José Vicente, María-Teresa Chicote, Pablo González-Herrero, and Peter G. Jones
pp 5735 - 5739; DOI:
10.1021/ic970478c
PDF
Electronic, Magnetic, and Redox Properties of [MFe3S4] Clusters (M = Cd, Cu, Cr) in Pyrococcus furiosus Ferredoxin
Christopher R. Staples, Ish K. Dhawan, Michael G. Finnegan, Derek A. Dwinell, Zhi Hao Zhou, Heshu Huang, Marc F. J. M. Verhagen, Michael W. W. Adams, and Michael K. Johnson
pp 5740 - 5749; DOI:
10.1021/ic970200k
PDF
Stability and Size-Discriminating Effects in Mononuclear Lanthanide Triple-Helical Building Blocks with Tridentate Aromatic Ligands
Stéphane Petoud, Jean-Claude G. Bünzli, Fabien Renaud, Claude Piguet, Kurt J. Schenk, and Gérard Hopfgartner
pp 5750 - 5760; DOI:
10.1021/ic970693t
PDF
Low-Spin Iron(III) Chiroporphyrins: 1H NMR Studies of Cyanide and Substituted Imidazole Coordination
Stanisaw Woowiec, Lechosaw Latos-Grayski, Marinella Mazzanti, and Jean-Claude Marchon
pp 5761 - 5771; DOI:
10.1021/ic970513f
PDF
Early- and Late-Lanthanide Pyridinethiolates: Synthesis, Redox Stability, and Structure
M. Berardini, Jongseong Lee, Deborah Freedman, Jae Lee, T. J. Emge, and J. G. Brennan
pp 5772 - 5776; DOI:
10.1021/ic9706865
PDF
Weak Interactions in Ternary Copper(II) Complexes with Iodotyrosinates. Biological Significance of the Iodines in Thyroid Hormones
Feng Zhang, Tatsuo Yajima, Hideki Masuda, Akira Odani, and Osamu Yamauchi
pp 5777 - 5784; DOI:
10.1021/ic9705397
PDF
Binuclear Copper Complexes Based on the 6,6'-Bis[[bis(2-pyridylmethyl)amino]methyl]-2,2'-bipyridine Ligand
Dong-Heon Lee, Narasimha N. Murthy, and Kenneth D. Karlin
pp 5785 - 5792; DOI:
10.1021/ic970639c
PDF
Structural and Spectroscopic Studies of Two Phases of the Organometallic Chain Polymer [Ru2{2:2:2-O2PMe2}2(CO)4]n
Christopher M. Barnes, D. Scott Bohle, Robert E. Dinnebier, Sara K. Madsen, and Peter W. Stephens
pp 5793 - 5798; DOI:
10.1021/ic970265n
PDF
Rhenium(V) and Technetium(V) Oxo Complexes of an N2N'S Peptidic Chelator: Evidence of Interconversion between the Syn and Anti Conformations
Ernest Wong, Theresa Fauconnier, Samantha Bennett, John Valliant, Tam Nguyen, Frank Lau, Linda F. L. Lu, Alfred Pollak, Russell A. Bell, and John R. Thornback
pp 5799 - 5808; DOI:
10.1021/ic9706562
PDF
Synthesis, Structure, and Reactivity of [RuCl(PP)L]PF6 (PP = (PPh3)2, Ph2P(CH2)4PPh2; L = P(py)3, PPh(py)2, py = 2-pyridyl). The "Missing" P,N,N'-Coordination Mode for 2-Pyridylphosphines
Richard P. Schutte, Steven J. Rettig, Ajey M. Joshi, and Brian R. James
pp 5809 - 5817; DOI:
10.1021/ic970835j
PDF
Synthesis and Reactivity of the Labile Dihydrogen Complex [{MeC(CH2PPh2)3}Ir(H2)(H)2]BPh4
Claudio Bianchini, Simonetta Moneti, Maurizio Peruzzini, and Francesco Vizza
pp 5818 - 5825; DOI:
10.1021/ic9705599
PDF
A New Binucleating Ligand Based on Anthracene and Its Cofacial Dirhodium(I) and Diiridium(I) Complexes
María del Rosario Benites, Frank R. Fronczek, Robert P. Hammer, and Andrew W. Maverick
pp 5826 - 5831; DOI:
10.1021/ic9706358
PDF
Thermodynamics of Inter- and Intramolecular Hydrogen Bonding in (Diphosphine)platinum(II) Diolate Complexes and Its Role in Carbohydrate Complexation Regioselectivity
Mark A. Andrews, Gerald K. Cook, and Zachary H. Shriver
pp 5832 - 5844; DOI:
10.1021/ic970860p
PDF
Steric and Electronic Effects in the First Homoleptic Imino Ether Complex: Synthesis and X-ray Crystallographic Determination of [Pt(NHC(OEt)Et)4](CF3SO3)2
Paul D. Prenzler, David C. R. Hockless, and Graham A. Heath
pp 5845 - 5849; DOI:
10.1021/ic970312b
PDF
Synthesis, Structure, and Photophysical Properties of Novel Ruthenium(II) Carboxypyridine Type Complexes
Thomas Norrby, Anna Börje, Björn Åkermark, Leif Hammarström, Jan Alsins, Kianosh Lashgari, Rolf Norrestam, Jerker Mårtensson, and Gunnar Stenhagen
pp 5850 - 5858; DOI:
10.1021/ic9705812
PDF
Palladium Chemistry in Molten Alkali Metal Polychalcophosphate Fluxes. Synthesis and Characterization of K4Pd(PS4)2, Cs4Pd(PSe4)2, Cs10Pd(PSe4)4, KPdPS4, K2PdP2S6, and Cs2PdP2Se6
Konstantinos Chondroudis, Mercouri G. Kanatzidis, Julien Sayettat, Stéphane Jobic, and Raymond Brec
pp 5859 - 5868; DOI:
10.1021/ic970593n
PDF
Polymorphism in Spin Transition Systems. Crystal Structure, Magnetic Properties, and Mössbauer Spectroscopy of Three Polymorphic Modifications of [Fe(DPPA)(NCS)2] [DPPA = (3-Aminopropyl)bis(2-pyridylmethyl)amine]
Galina S. Matouzenko, Azzedine Bousseksou, Sylvain Lecocq, Petra J. van Koningsbruggen, Monique Perrin, Olivier Kahn, and André Collet
pp 5869 - 5879; DOI:
10.1021/ic971174t
PDF
New Ionophoric Calix[4]diquinones: Coordination Chemistry, Electrochemistry, and X-ray Crystal Structures
Paul D. Beer, Philip A. Gale, Zheng Chen, Michael G. B. Drew, Jennifer A. Heath, Mark I. Ogden, and Harold R. Powell
pp 5880 - 5893; DOI:
10.1021/ic9704851
PDF
Kinetics of Formation of Molybdenum Selenides from Modulated Reactants and Structure of the New Compound Mo3Se
Robert Schneidmiller, Marc D. Hornbostel, and David C. Johnson
pp 5894 - 5899; DOI:
10.1021/ic9708125
PDF
Equilibrium Dynamics in the Thallium(III)-Cyanide System in Aqueous Solution
István Bányai, Julius Glaser, and Judit Losonczi
pp 5900 - 5908; DOI:
10.1021/ic970366l
PDF
Protonolysis of Dialkyl- and Alkylarylplatinum(II) Complexes and Geometrical Isomerization of the Derived Monoorgano-Solvento Complexes: Clear-Cut Examples of Associative and Dissociative Pathways in Platinum(II) Chemistry
Raffaello Romeo, Maria Rosaria Plutino, and Lars I. Elding
pp 5909 - 5916; DOI:
10.1021/ic9704905
PDF
Kinetics and Mechanism of Urea Hydrolysis Catalyzed by Palladium(II) Complexes
Natalia V. Kaminskaia and Nenad M. Kosti
pp 5917 - 5926; DOI:
10.1021/ic961500p
PDF
Aerobic Epoxidation of Olefins Catalyzed by Electronegative Vanadyl Salen Complexes
Christopher J. Chang, Jay A. Labinger, and Harry B. Gray
pp 5927 - 5930; DOI:
10.1021/ic970824q
PDF
Influence of the Nature of the Ligands on the Electronic Ground State of Organouranium(V) Compounds, Studied by Electron Paramagnetic Resonance
Didier Gourier and, Daniel Caurant, Jean Claude Berthet, Christophe Boisson, and Michel Ephritikhine
pp 5931 - 5936; DOI:
10.1021/ic961496h
PDF
Molecular Engineering of Photosensitizers for Nanocrystalline Solar Cells: Synthesis and Characterization of Ru Dyes Based on Phosphonated Terpyridines
S. M. Zakeeruddin, M. K. Nazeeruddin, P. Pechy, F. P. Rotzinger, R. Humphry-Baker, K. Kalyanasundaram, M. Grätzel, V. Shklover, and T. Haibach
pp 5937 - 5946; DOI:
10.1021/ic970008i
PDF
Luminescent and Redox-Active Iridium(III)-Cyclometalated Compounds with Terdentate Ligands
Antonino Mamo, Ivan Stefio, Melchiorre F. Parisi, Alberto Credi, Margherita Venturi, Cinzia Di Pietro, and Sebastiano Campagna
pp 5947 - 5950; DOI:
10.1021/ic970791e
PDF
Structural Characterization of Representative d7, d8, and d9 Transition Metal Complexes of Bis(o-carborane)
David E. Harwell, Jeffrey McMillan, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 5951 - 5955; DOI:
10.1021/ic9706313
PDF
Favoring the cis Isomer in d2 Octahedral Dioxo Complexes: Role of the Metal
Isabelle Demachy and Yves Jean
pp 5956 - 5958; DOI:
10.1021/ic9704997
PDF
Synthesis and Crystal Structure of the First Cluster Displaying PdI-AgI Interactions: [Ag2Pd2(SC6F5)2(SO3CF3)(dppm)3]SO3CF3·CH2Cl2
Rafael Usón, Miguel A. Usón, and Santiago Herrero
pp 5959 - 5961; DOI:
10.1021/ic970457i
PDF
(Fluoroalkyl)phosphine Coordination Chemistry: Synthesis and Structure of {[,1,6-(C6H5)P(C2F5)2]Cr(CO)2}2
R. Gregory Peters, Byron L. Bennett, R. Chris Schnabel, and Dean M. Roddick
pp 5962 - 5965; DOI:
10.1021/ic970672z
PDF
A Neutral Spirocyclic Hexacoordinated Germanium(IV) Complex: Hypervalent Germanium Compounds with Sulfur-Containing Eight-Membered Rings
Stephen D. Pastor, Victor Huang, David NabiRahni, Stephen A. Koch, and Hua-Fen Hsu
pp 5966 - 5968; DOI:
10.1021/ic9710263
PDF
Synthesis and Characterization of Novel Axial Dichloroplatinum(IV) Cisplatin Analogues: Crystal Structure of an Axial Dichloro Complex [Pt(cis-1,4-DACH)(trans-Cl2)(CBDCA)]·1/2MeOH
Shaikh Shamsuddin, Jaap W. van Hal, Joseph L. Stark, Kenton H. Whitmire, and Abdul R. Khokhar
pp 5969 - 5971; DOI:
10.1021/ic970416m
PDF
Formation of Ruthenium Nitrosyl Complexes: Reactions of Ru(bpy)(CO)2Cl2 and Its Methyl-Substituted Analogues Ru(4,4'-dmbpy)(CO)2Cl2 and Ru(6,6'-dmbpy)(CO)2Cl2 in Oxidizing Acidic Solutions
Pertti Homanen, Matti Haukka, Markku Ahlgrén, and Tapani A. Pakkanen
pp 5972 - 5972; DOI:
10.1021/ic971285s
PDF
Molecular Modeling of Vanadium Peroxides
Thomas R. Cundari, Laura L. Sisterhen, and Chryssanthi Stylianopoulos
pp 5972 - 5972; DOI:
10.1021/ic971287c
PDF

Issue 26


Synthesis and Characterization of the Platinum Cluster Complex Pt4(PF3)8
Cynthia L. Hammill, Ronald J. Clark, Charles W. Ross, III, Alan G. Marshall, and James Schmutz
pp 5973 - 5977; DOI:
10.1021/ic970590a
PDF
X-ray Crystallographic Studies of the Products of Oxidative Additions of Iodine to Cyclic Trinuclear Gold(I) Complexes: Directional Effects for Au-I···I-Au Interactions
Jess C. Vickery and Alan L. Balch
pp 5978 - 5983; DOI:
10.1021/ic970612t
PDF
Synthesis and Properties of Iron(II) Hydride Complexes Containing the Tripodal Tetraphosphine Ligand P(CH2CH2PMe2)3
Leslie D. Field, Barbara A. Messerle, and Ronald J. Smernik
pp 5984 - 5990; DOI:
10.1021/ic970143v
PDF
Hydrotris(pyrazolyl)borato Cycloocta-1,5-diene Complexes of Iridium(I): Synthetic Studies and Equilibria in Solution. X-ray Crystal Structures of a Four- and a Five-Coordinate Iridium(I) Hydrotris(pyrazolyl)borato Complex
Alberto Albinati, Mike Bovens, Heinz Rüegger, and Luigi M. Venanzi
pp 5991 - 5999; DOI:
10.1021/ic970361o
PDF
Cyclopentadienyl Ligand Effects on Enthalpies of Protonation of the Ru-Ru Bond in Cp'2Ru2(CO)4 Complexes
Chip Nataro, Leonard M. Thomas, and Robert J. Angelici
pp 6000 - 6008; DOI:
10.1021/ic970181e
PDF
Trans- and Cis-Water Reactivities in d6 Octahedral Ruthenium(II) Pentaaqua Complexes: Experimental and Density Functional Theory Studies
Nicolas Aebischer, Elena Sidorenkova, Mauro Ravera, Gábor Laurenczy, Domenico Osella, Jacques Weber, and André E. Merbach
pp 6009 - 6020; DOI:
10.1021/ic970783y
PDF
Oxidatively Induced Reductive Eliminations. A Mechanistic Study of the Oxidation Chemistry of CnRhMe3 (Cn = 1,4,7-Trimethyl-1,4,7-triazacyclononane)
Erik Fooladi and Mats Tilset
pp 6021 - 6027; DOI:
10.1021/ic970876f
PDF
Equilibria, Kinetics, and Mechanism for Rapid Substitution Reactions Trans to Triphenylsilyl in Platinum(II) Complexes
Ola F. Wendt and Lars I. Elding
pp 6028 - 6032; DOI:
10.1021/ic971008l
PDF
C-Hydroxydicarba-closo-dodecaboranes
Ilya Zharov, Anil Saxena, Josef Michl, and Robert D. Miller
pp 6033 - 6038; DOI:
10.1021/ic970796b
PDF
Structural Novelties in Anionic Cluster Halide Phases. Discrete Tetrahedral A4Br+ Ions in Two New Zirconium Bromide Structures (A = Na-Cs)
Ru-Yi Qi and John D. Corbett
pp 6039 - 6044; DOI:
10.1021/ic970818u
PDF
Cs8Ga11, a New Isolated Cluster in a Binary Gallium Compound. A Family of Valence Analogues A8Tr11X: A = Cs, Rb; Tr = Ga, In, Tl; X = Cl, Br, I
Robert W. Henning and John D. Corbett
pp 6045 - 6049; DOI:
10.1021/ic970904u
PDF
Low-Dimensional Sulfoantimonates with Metal Complexes as Counterions. Hydrothermal Synthesis and Properties of [M(en)3]Sb2S4 (M = Co, Ni) and [M(en)3]Sb4S7 (M = Fe, Ni)
Hans-Oscar Stephan and Mercouri G. Kanatzidis
pp 6050 - 6057; DOI:
10.1021/ic970609+
PDF
Electronic Band Structure Study of the Transport Properties of the Intermetallic Compounds ZrRuP and ZrRuSi
Dong-Kyun Seo, Jingqing Ren, Myung-Hwan Whangbo, and Enric Canadell
pp 6058 - 6063; DOI:
10.1021/ic970148s
PDF
The Chemistry of 1,3,5-Triazacyclohexane Complexes. 6.1 Synthesis and Characterization of the Cobalt(II) Methoxide Core {Co3(OMe)4}2+
Randolf D. Köhn, Matthias Haufe, Gabriele Kociok-Köhn, and Alexander C. Filippou
pp 6064 - 6069; DOI:
10.1021/ic9704593
PDF
Factors Influencing the Configuration and Conformation of Diamine Chelate Rings in Platinum(II) Compounds: 2,4-Bis(methylamino)pentane Complexes
Leonardo Cerasino, Kevin M. Williams, Francesco P. Intini, Renzo Cini, Luigi G. Marzilli, and Giovanni Natile
pp 6070 - 6079; DOI:
10.1021/ic970704i
PDF
Tsalen- and Tsalpn-Based Nickel Complexes with Two Aldehyde Functionalities as Potential Synthons for Thiophenolate-Containing Di- and Polynucleating Acyclic and Macrocyclic Ligands
Aase Christensen, Holger S. Jensen, Vickie McKee, Christine J. McKenzie, and Maria Munch
pp 6080 - 6085; DOI:
10.1021/ic970713r
PDF
Synthesis and Structure of a New Macrocyclic Polyhydroxylated Gadolinium Chelate Used as a Contrast Agent for Magnetic Resonance Imaging
J. Platzek, P. Blaszkiewicz, H. Gries, P. Luger, G. Michl, A. Müller-Fahrnow, B. Radüchel, and D. Sülzle
pp 6086 - 6093; DOI:
10.1021/ic970123t
PDF
Chiral Cyclometalated Platinum(II) and Palladium(II) Complexes with Derivatives of Thienylpyridine as Ligands: Helical Distortion of the Square Planar (SP-4) Geometry
Michel Gianini, Alex von Zelewsky, and Helen Stoeckli-Evans
pp 6094 - 6098; DOI:
10.1021/ic970228w
PDF
Peroxidation of Pyrogallol by Antibody-Metalloporphyrin Complexes
Akira Harada, Hiroyuki Fukushima, Keizou Shiotsuki, Hiroyasu Yamaguchi, Fukuyo Oka, and Mikiharu Kamachi
pp 6099 - 6102; DOI:
10.1021/ic9610849
PDF
Synthesis and Structural Characterization of Nonplanar Tetraphenylporphyrins and Their Metal Complexes with Graded Degrees of -Ethyl Substitution
Mathias O. Senge and and Werner W. Kalisch
pp 6103 - 6116; DOI:
10.1021/ic970765g
PDF
Stepwise Approach to Bimetalic Porphyrin Hosts: Spatially Enforced Coordination of a Nickel(II) Porphyrin
Anton Vidal-Ferran, Nick Bampos, and Jeremy K. M. Sanders
pp 6117 - 6126; DOI:
10.1021/ic971235n
PDF
Metallohosts Derived from the Assembly of Sugars around Transition Metals: The Complexation of Alkali Metal Cations
Umberto Piarulli, Andrew J. Rogers, Carlo Floriani, Giuliana Gervasio, and Davide Viterbo
pp 6127 - 6133; DOI:
10.1021/ic9706717
PDF
An Alkoxo-Hydroxo-Bridged Octanuclear Copper(II) Complex with a Hydrophobic Exterior and a Hydrophilic Metallamacrobicyclic Core Showing Selective Hydrogen-Bonding Interactions
Kannappan Geetha, Munirathinam Nethaji, and Akhil R. Chakravarty
pp 6134 - 6137; DOI:
10.1021/ic970487l
PDF
Novel 2-fold Interpenetrating Diamondoid Coordination Polymers: [Cu(3,3'-bipyridine)2]X (X= BF4-, PF6-)
Susan Lopez, Mehmet Kahraman, Michael Harmata, and Steven W. Keller
pp 6138 - 6140; DOI:
10.1021/ic970703q
PDF

Issue 27


Imidazole and p-Nitrophenolate Complexes of Oxoiron(IV) Porphyrin -Cation Radicals as Models for Compounds I of Peroxidase and Catalase
Hiroshi Fujii, Tetsuhiko Yoshimura, and Hitoshi Kamada
pp 6142 - 6143; DOI:
10.1021/ic970271j
PDF
A New Sulfur-Rich Rhenium(III) Complex, Re(S2CC6H5)(S3CC6H5)2, and Seven-Coordinate Complexes Formed by Reversible Sulfur Abstraction Reactions, Re(S2CC6H5)3(PPh3) and [Re(S2CC6H5)3(CN)]-
C. A. McConnachie and E. I. Stiefel
pp 6144 - 6145; DOI:
10.1021/ic970689h
PDF
Highly Branched Dendritic Macromolecules with Core Polyhedral Silsesquioxane Functionalities
Bo Hong, Travis P. S. Thoms, Hunter J. Murfee, and Michael J. Lebrun
pp 6146 - 6147; DOI:
10.1021/ic971034j
PDF
Structure of a (-Oxo)(dihydroxo)diiron(III) Complex and Its Reactivity toward Phosphodiesters
Carole Duboc-Toia, Stéphane Ménage, Jean-Marc Vincent, Marie Thérèse Averbuch-Pouchot, and Marc Fontecave
pp 6148 - 6149; DOI:
10.1021/ic9711877
PDF
Anisometric Cyclometalated Palladium(II) and Platinum(II) Complexes. Structural and Photophysical Studies
Francesco Neve and, Alessandra Crispini, and Sebastiano Campagna
pp 6150 - 6156; DOI:
10.1021/ic9703540
PDF
Hydrogen-Bonding Patterns in Oxime/Oximato Platinum(II) Species Providing the Formation of One-Dimensional Chains, Two-Dimensional Networks, and Cages
Vadim Yu. Kukushkin, Takanori Nishioka, David Tudela, Kiyoshi Isobe, and Isamu Kinoshita
pp 6157 - 6165; DOI:
10.1021/ic970501u
PDF
Reactivity of [M(CP)(S2C-R)] (M = Pd, Pt; CP = CH2-C6H4-P(o-tolyl)2-C,P; R = NMe2, OEt) toward HgX2 (X = Br, I). X-ray Crystal Structures of [Pt{CH2-C6H4P(o-tolyl)2-C,P}(S2CNMe2)HgI(-I)]2 and [PdBr(S2COEt){-P(o-tolyl)2-C6H4-CH2-}HgBr]·0.5HgBr2·C2H4Cl2
Larry R. Falvello, Juan Forniés, Antonio Martín, Rafael Navarro, Violeta Sicilia, and Pablo Villarroya
pp 6166 - 6171; DOI:
10.1021/ic970584e
PDF
Structures, Bonding, Infrared Spectroscopy, and Two-Electron Reduction Potentials of the Coordinated Metallopnictanes Fe3(CO)9(3-EMLn)2 (E = P, As, Sb; MLn = Cr(CO)5, MnCp(CO)2)
Boyce E. Collins, Yoshihiro Koide, Cynthia K. Schauer, and Peter S. White
pp 6172 - 6183; DOI:
10.1021/ic970786a
PDF
Valence Tautomerism within a Linear Polymer Consisting of Pyrazine-Bridged Manganese-Quinone Subunits. Synthesis and Characterization of [MnIII(-pyz)(3,6-DBSQ)(3,6-DBCat)]n
Attia S. Attia and Cortlandt G. Pierpont
pp 6184 - 6187; DOI:
10.1021/ic970781d
PDF
Nucleophilic Addition to Complexes of (Ph2P)2C=CH2 as a Route to Functionalized, Redox-Active Ruthenium(II)-Diphosphine Complexes
Jim V. Barkley, Simon J. Higgins, Mark K. McCart, and Thomas J. Pounds
pp 6188 - 6196; DOI:
10.1021/ic970799o
PDF
The Square Pyramidal Hydride Cation [RuH(dcpe)2]+, dcpe = Bis(dicyclohexylphosphino)ethane. Structures of [RuH(dcpe)2]+[BPh4]- and of the Zwitterionic {(6-C6H5)BPh3}RuH(dcpe)
Rainer F. Winter and and Fridmann M. Hornung
pp 6197 - 6204; DOI:
10.1021/ic970583m
PDF
Synthesis and Chemistry of [Hydrotris(3,5-bis(trifluoromethyl)pyrazolyl)borato]silver(I) Complexes
H. V. Rasika Dias, Ziyun Wang, and Wiechang Jin
pp 6205 - 6215; DOI:
10.1021/ic9712028
PDF
Ring Size, Substituent, and Anion Effects on the Kinetic and Equilibrium Properties of Copper(II) Complexes with Water-Soluble Macrocyclic Tetrathia Ethers
Ksenia Krylova, Kimberly D. Jackson, Jeffrey A. Vroman, Andrew J. Grall, Michael R. Snow, L. A. Ochrymowycz, and D. B. Rorabacher
pp 6216 - 6223; DOI:
10.1021/ic9707117
PDF
Outer Sphere Metal-to-Ligand Charge Transfer in Organometallic Ion Pairs
Lucian A. Lucia, Khalil Abboud, and Kirk S. Schanze
pp 6224 - 6234; DOI:
10.1021/ic970351n
PDF
Electron Self-Exchange of Re2X4(PMe2Ph)40/+ (X = Cl, Br) by 1H NMR Line Broadening in Methylene Chloride
John Coddington and Scot Wherland
pp 6235 - 6237; DOI:
10.1021/ic9709335
PDF
Solid State Structures and Dynamic Solution Equilibria of Bis(dibenzylamido)magnesium Complexes: Aggregation Dependence on Stoichiometry and Denticity of Donor Solvent
William Clegg, Fiona J. Craig, Kenneth W. Henderson, Alan R. Kennedy, Robert E. Mulvey, Paul A. O'Neil, and David Reed
pp 6238 - 6246; DOI:
10.1021/ic970912a
PDF
New Small-Ring Cyclogermanes: Syntheses and X-ray Crystal Structures
Siva P. Mallela, Sven Hill, and R. A. Geanangel
pp 6247 - 6250; DOI:
10.1021/ic970833z
PDF
Chemistry of the Tetraselenomolybdate Anion: Syntheses, Spectroscopic Results, and Structural Characterizations of Polynuclear Mo-Cu-Se Compounds Containing Thiolate Ligands
Maochun Hong, Qianfeng Zhang, Rong Cao, Daxu Wu, Jiutong Chen, Wenjian Zhang, Hanqin Liu, and Jiaxi Lu
pp 6251 - 6260; DOI:
10.1021/ic9706459
PDF
Coordination Chemistry of Homoscorpionate Ligands with 3-Cyclopropyl Substituents
Arnold L. Rheingold, Glenn P. A. Yap, Louise M. Liable-Sands, Ilia A. Guzei, and Swiatoslaw Trofimenko
pp 6261 - 6265; DOI:
10.1021/ic970880r
PDF
Stabilization of Lithium Borohydride with Nitrogen Donor, Chelating Ligands. Syntheses and Solid State Structures of [HC(3,5-Me2pz)3]Li(3-BH4), {[H2C(3,5-Me2pz)2]Li(-3-BH4)}2, and {[4,4'-Me2bipy]Li(-3-BH4)}2 (pz = pyrazolyl, bipy = bipyridyl)
Daniel L. Reger, James E. Collins, Michael A. Matthews, Arnold L. Rheingold, Louise M. Liable-Sands, and Ilia A. Guzei
pp 6266 - 6269; DOI:
10.1021/ic970815h
PDF
Synthesis, Characterization, Structure, Electrochemistry, and Spectroscopy of Porphyrins That Have a Conjugated Connection to Donor/Acceptor Groups
Edia E. Bonfantini, Anthony K. Burrell, David L. Officer, David C. W. Reid, Michael R. McDonald, Paul A. Cocks, and Keith C. Gordon
pp 6270 - 6278; DOI:
10.1021/ic9702330
PDF
Synthesis, Structure, and Magnetic and Redox Properties of Linear Bis-Dinuclear Complexes Afforded by Schiff Base Ligands Containing Catecholate and Pyridine or Imidazole Groups
Sylvie Theil, Ratnamala Yerande, Rajeev Chikate, Françoise Dahan, Azzedine Bousseksou, Subhash Padhye, and Jean-Pierre Tuchagues
pp 6279 - 6286; DOI:
10.1021/ic9703538
PDF
Structure and Stability of 2-Aza-21-carbaporphyrin Tautomers Prearranged for Coordination
Ludmia Szterenberg and and Lechosaw Latos-Grayski
pp 6287 - 6291; DOI:
10.1021/ic9705857
PDF
Electrooxidation of Cobalt(II) -Brominated-Pyrrole Tetraphenylporphyrins in CH2Cl2 under an N2 or a CO Atmosphere
Karl M. Kadish, Jun Li, Eric Van Caemelbecke, Zhongping Ou, Ning Guo, Marie Autret, Francis D'Souza, and Pietro Tagliatesta
pp 6292 - 6298; DOI:
10.1021/ic970789n
PDF
Characterization of High-Spin and Low-Spin Iron(III) Quinoxalinotetraphenylporphyrin
Jacek Wojaczyski, Lechosaw Latos-Grayski, and Tadeusz Gowiak
pp 6299 - 6306; DOI:
10.1021/ic970305n
PDF
Effect of Phosphorus Axial -Acceptors in Iron(III) Porphyrinates: Characterization of Low-Spin Complexes [(PPh(OMe)2)2Fe(T(p-Me)PP)]CF3SO3 and [(PPh(OEt)2)2Fe(T(p-Me)PP)]CF3SO3
Marie-Agnès Pilard, Maud Guillemot, Loïc Toupet, J. Jordanov, and Gérard Simonneaux
pp 6307 - 6314; DOI:
10.1021/ic9704849
PDF
Dioxotungsten(VI) Complexes of Hydrotris(3,5-dimethylpyrazol-1-yl)borate Including the X-ray Crystal Structure of the Tungsten Selenophenolate Complex cis-{HB(Me2C3N2H)3}WO2(SePh)
Aston A. Eagle, Edward R. T. Tiekink, and Charles G. Young
pp 6315 - 6322; DOI:
10.1021/ic970544a
PDF
Pyrazole Ligation to Cobalt(III) Centers: Syntheses, Structures, and Properties of Cobalt(III) Complexes of N,N'-Bis[2-(1-pyrazolyl)ethyl]pyridine-2,6-dicarboxamide
Ferman A. Chavez, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 6323 - 6327; DOI:
10.1021/ic970532p
PDF
Copper Ion Complexes with Derivatized Chelating Pterin Ligands
Dong-Heon Lee, Narasimha N. Murthy, Yin Lin, N. Sarwar Nasir, and Kenneth D. Karlin
pp 6328 - 6334; DOI:
10.1021/ic970810k
PDF
Orientation-Selective ESEEM Study and Crystal Structure of a CuII(thiochrome)Cl2 Complex
Maria Louloudi, Yiannis Deligiannakis, Jean-Pierre Tuchagues, Bruno Donnadieu, and Nick Hadjiliadis
pp 6335 - 6342; DOI:
10.1021/ic970638k
PDF
Binucleating Ligand Structural Effects on (-Peroxo)- and Bis(-oxo)dicopper Complex Formation and Decay: Competition between Arene Hydroxylation and Aliphatic C-H Bond Activation
Samiran Mahapatra, Susan Kaderli, Antoni Llobet, Yorck-Michael Neuhold, Tania Palanché, Jason A. Halfen, Victor G. Young, Jr., Thomas A. Kaden, Lawrence Que, Jr., Andreas D. Zuberbühler, and William B. Tolman
pp 6343 - 6356; DOI:
10.1021/ic970718o
PDF
Synthesis, Crystal Structure, EXAFS, and Magnetic Properties of catena-Poly[-tris(4-(2-hydroxyethyl)-1,2,4-triazole-N1,N2)copper(II)] Diperchlorate Trihydrate: Relevance with the Structure of the Iron(II) 1,2,4-Triazole Spin Transition Molecular Materials
Yann Garcia, Petra J. van Koningsbruggen, Georges Bravic, Philippe Guionneau, Daniel Chasseau, Giovanni Luca Cascarano, Jacques Moscovici, Katia Lambert, Alain Michalowicz, and Olivier Kahn
pp 6357 - 6365; DOI:
10.1021/ic970895p
PDF
Coordination Modes of a Series of Xylylene-Bridged Bis(1,4,7-triazacyclonon-1-yl) Ligands: Synthesis, Structure, and Properties of Nickel(II) and Copper(II) Complexes
Bim Graham, Gary D. Fallon, Milton T. W. Hearn, David C. R. Hockless, George Lazarev, and Leone Spiccia
pp 6366 - 6373; DOI:
10.1021/ic970642w
PDF
Dramatic Modifications of Magnetic Properties through Dehydration-Rehydration Processes of the Molecular Magnetic Sponges CoCu(obbz)(H2O)4·2H2O and CoCu(obze)(H2O)4·2H2O, with obbz = N,N'-Bis(2-carboxyphenyl)oxamido and obze = N-(2-Carboxyphenyl)-N'-(carboxymethyl)oxamido
Joulia Larionova, Suvarna A. Chavan, J. V. Yakhmi, Anne Gulbrandsen Frystein, Jorunn Sletten, Claude Sourisseau, and Olivier Kahn
pp 6374 - 6381; DOI:
10.1021/ic970719g
PDF
Structural Control of Copper(I) Coordination Polymers: Construction of One-, Two-, and Three-Dimensional Frameworks of Tetrahedral Copper(I) Ions Bridged by Dicyanobenzene Derivatives
Takayoshi Kuroda-Sowa, Takashi Horino, Mikiko Yamamoto, Yasuhiro Ohno, Masahiko Maekawa, and Megumu Munakata
pp 6382 - 6389; DOI:
10.1021/ic9707725
PDF
Supramolecular Architecture in Nickel(II) Polyamine Tetracyanoquinodimethanido Systems
Loreto Ballester, Angel Gutiérrez, M. Felisa Perpiñán, Ulises Amador, M. Teresa Azcondo, Ana E. Sánchez, and Carlo Bellitto
pp 6390 - 6396; DOI:
10.1021/ic970851g
PDF
Structural Investigations of Ruthenium Phthalocyanines with EXAFS Spectroscopy
Helmut Bertagnolli, Achim Weber, Wolfgang Hörner, Teja S. Ertel, Ulrich Reinöhl, Michael Hanack, Michael Hees, and Rainer Polley
pp 6397 - 6400; DOI:
10.1021/ic970653p
PDF
Structural and Electron Paramagnetic Resonance Studies of the Square Pyramidal to Trigonal Bipyramidal Distortion of Vanadyl Complexes Containing Sterically Crowded Schiff Base Ligands
Charles R. Cornman, Katherine M. Geiser-Bush, Stephen P. Rowley, and Paul D. Boyle
pp 6401 - 6408; DOI:
10.1021/ic970868z
PDF
A New Three-Dimensional Vanadium Selenite, (VO)2(SeO3)3, with Isolated and Edge-Shared VO6 Octahedra
P. Shiv Halasyamani and Dermot O'Hare
pp 6409 - 6412; DOI:
10.1021/ic9708881
PDF
Syntheses, Crystal Structures, and Magnetic Properties of Sc19Br28Z4 Compounds with Z = Mn, Fe, Ru, or Os. Structural and Bonding Trends in R16X20Z4-Type Oligomers
Sharon J. Steinwand, John D. Corbett, and James D. Martin
pp 6413 - 6422; DOI:
10.1021/ic970881j
PDF
Surface Complexation Description of the Dissolution of Chromium(III) Hydrous Oxides by Oxalic Acid
Luis A. García Rodenas, Alberto M. Iglesias, Ariel D. Weisz, Pedro J. Morando, and Miguel A. Blesa
pp 6423 - 6430; DOI:
10.1021/ic9709382
PDF
A 12-Membered Inorganic Heterocycle: Synthesis and Structural Characterization of a Bimetallic Chromium(VI) Siloxane Complex
Hendrikus C. L. Abbenhuis, Martinus L. W. Vorstenbosch, Rutger A. van Santen, Wilberth J. J. Smeets, and Anthony L. Spek
pp 6431 - 6433; DOI:
10.1021/ic961116s
PDF
The Dipotassium Salt of the 6,6'-commo-Bis(tridecahydro-nido-6-cadmadeca- borate) Dianion: A New Type of Metal-Centered commo-Bis(metallaborane)
Ralf Littger, Ulrich Englich, and James T. Spencer
pp 6434 - 6436; DOI:
10.1021/ic970190n
PDF
Rhenium(VI) Benzylidyne Complexes, Re(C-2,4,6-C6H2Me3)(PPh3)(H2O)X3 (X = Cl and Br): Crystal Structure and Spectroscopic Properties
Wen-Mei Xue, Michael C. W. Chan, Thomas C. W. Mak, and Chi-Ming Che
pp 6437 - 6439; DOI:
10.1021/ic970342e
PDF
Facile P-C Bond Cleavage of Trimethylphosphine at a Heterodimetallic (Ni-W) Center
Takayuki Nakajima, Isao Shimizu, Kimiko Kobayashi, Hiroyuki Koshino, and Yasuo Wakatsuki
pp 6440 - 6442; DOI:
10.1021/ic9705103
PDF
Modulated Magnetic Coupling in Alkoxoiron(III) Rings by Host-Guest Interactions with Alkali Metal Cations
Gian Luca Abbati, Andrea Cornia, Antonio C. Fabretti, Wanda Malavasi, Luisa Schenetti, Andrea Caneschi, and Dante Gatteschi
pp 6443 - 6446; DOI:
10.1021/ic970637s
PDF
Synthesis of a Heterobimetallic Ladder Polymer [(5-C5Me5)WS3Ag2Br]n
Jian-P. Lang, Hiroyuki Kawaguchi, and Kazuyuki Tatsumi
pp 6447 - 6449; DOI:
10.1021/ic970687x
PDF
Orbital Ordering in -Substituted Porphyrins: Resonance Raman Spectra of the Radical Cations
Sharon A. Sibilia, Roman S. Czernuszewicz, Maxwell J. Crossley, and Thomas G. Spiro
pp 6450 - 6453; DOI:
10.1021/ic970562s
PDF
Synthesis and Characterization of [Ag4(3-SC2B10H11)2(-O3SCF3)2(PPh3)4]: A Silver Complex with a 3-Thiolate Ligand
M. Mar Artigas, Olga Crespo, M. Concepción Gimeno, Peter G. Jones, Antonio Laguna, and M. Dolores Villacampa
pp 6454 - 6456; DOI:
10.1021/ic970665a
PDF
Synthesis and Characterization of [Cp3iM(CO)3]2 (M = Mo, W; Cp3i = 1,2,4-Triisopropylcyclopentadienyl Ligand). X-ray Crystal Structure of [Cp3iMo(CO)3]2
Pamela S. Tanner, Denis C. Barbini, and Wayne E. Jones, Jr.
pp 6457 - 6460; DOI:
10.1021/ic970547n
PDF
A Polymeric Platinum(II)-Thallium(I) Complex Stabilized by Alkynyl-Thallium and Platinum-Thallium Bonding Interactions
Irene Ara, Jesús R. Berenguer, Juan Forniés, Julio Gómez, Elena Lalinde, and Rosa I. Merino
pp 6461 - 6464; DOI:
10.1021/ic970546v
PDF
Nitrosoarene Complexes of Manganese Porphyrins
Shelia J. (Schultze) Fox, Li Chen, Masood A. Khan, and George B. Richter-Addo
pp 6465 - 6467; DOI:
10.1021/ic970836b
PDF
(Methylthio)methyl and (N,N-Dimethylcarbamoyl)methyl Upper-Rim-Substituted Calix[4]arenes as Potential Extractants for Ag(I), Hg(II), Ni(II), Pd(II), Pt(II), and Au(III)
Alexander T. Yordanov, Olusegun M. Falana, H. Fred Koch, and D. Max Roundhill
pp 6468 - 6471; DOI:
10.1021/ic970773x
PDF
Synthesis and X-ray Crystallographic Characterization of (-(Diphenylphosphino)phenyl-C2,P)palladium Bromide. A Novel Tetranuclear Metalated Compound
Atta M. Aarif, Francisco Estevan, Abel García-Bernabé, Pascual Lahuerta, Mercedes Sanaú, and M. Angeles Ubeda
pp 6472 - 6475; DOI:
10.1021/ic9702734
PDF
Phenylarsonates of Aluminum and Gallium: Synthesis and Structural Characterization of [tBuAl(3-O3AsPh)]4 and [tBu2Ga(2-O2AsPh)]2O
Mark R. Mason, R. Mark Matthews, Mark S. Mashuta, and John F. Richardson
pp 6476 - 6478; DOI:
10.1021/ic971168x
PDF
Titanium(IV) Neopentoxides. X-ray Structures of Ti3(3-O)(3-Cl)-(-OCH2CMe3)3(OCH2CMe3)6 and [Ti(-OCH2CMe3)-(OCH2CMe3)3]2
Timothy J. Boyle, Todd M. Alam, Eric R. Mechenbier, Brian L. Scott, and Joseph W. Ziller
pp 6479 - 6479; DOI:
10.1021/ic971335t
PDF